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十八烷酸

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By means of molecular designing, a series of sodium branched-alkyl benzene sulfonates weresynthesized through seven process, involving Frieded-Crafts reaction, Grignard reaction, sulfonationand neutralization. Those isomers have similar structure, carbons of same quantity, but the position ofalkylaryl dissimilarity. Liner fat acid, metaxylene and halogenated hydrocarbon of different carbonnumber were used as the starting materials. Optimum processing condition was confirmed consideringinfluence of a series of reaction factors such as feed proportioning, quantity of catalysts, quantitysolvent, reaction time, temperature and pressure. Eight kinds of isomers of sodium hexadecylxylolsulfonates were finally synthesized, and characterized by FT-IR.

本文通过分子设计,以不同碳数直链脂肪酸、间二甲苯以及不同碳数的卤代烷为原料,经酰基化、格氏反应、加氢还原、磺化及中和等反应,合成了结构相似、烷烃链碳数一定、芳基在烷烃链不同位置的烷基芳基磺酸盐同分异构体;并考察了原料配比、催化剂用量、反应时间、反应温度、溶剂用量、反应压力等一系列因素对各反应的影响,进而确定最佳工艺条件,最终合成出十六烷基二甲苯磺酸钠的八种同分异构体,利用 FT-IR 对产物结构进行了分析。

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