十二烷基

THE FIRST TOTAL SYNTHESIS OF TAXAMAIRIN B Taxamairin B, representive of rare naturally-occuring rearrang-ed 9(10→20)-abeo-8, 11, 13-triene diterpenoids, has been firstsynthesized by a eleven-step route in an overall yield of 8.19%,starting from commercially available catechol and 1,3-cyclohexan-dione. The improved Friedel-Crafts annulation, thermodynamicallycontrolled-geminal pairing methylation, the selective oxidation ofallyl group and the selective reduction of the less-hindrancecarbon-carbon double bond are the key steps.

二。美丽红豆杉素B的全合成研究 1，美丽红豆杉素B的首次全合成以价廉，易得的邻苯二酚和1，3-环己二酮为原料，经过改良的Friedel-Crafts烷基化反应，热力学控制的α，β-不饱和酮结构的α一位双烷基化，烯丙位的选择性氧化，以及选择性还原位阻较小的碳碳双键等十一步反应，以8.19％的总收率首次完成了美丽红豆杉素B的全合成。

The fuberidazole was prepared by reaction of O-phenylendiamine with furfural at the presence of CTMAB as catalyst.

以邻苯二胺和糠醛为原料，以十六甲基三烷基溴化铵为催化剂合成了麦穗宁。

In this thesis, investigations focused on heteropoly acids-catalyzed C-C and C-N bond formation reactions and the synthesis of xanthenediones and acridinediones under thermal conditions are described.1.12-Phosphotungstic acid has been used as an efficient,eco-friendly,and air- and moisture-stable catalyst to promote the direct dehydrative substitution of the hydroxy group of benzylic and allylic alcohols with variousβ-dicarbonyl compounds.

本篇论文主要描述了杂多酸催化下的C-C和C-N键的生成，以及无溶剂直接加热下合成十氢氧杂蒽二酮和9-芳基十氢吖啶二酮。主要内容如下：1。在磷钨酸催化下，1，3-二羰基化合物与醇能够顺利偶合，脱除一分子的水，生成烷基化的1，3-二羰基化合物。反应在甲苯中进行时，二芳基甲醇能与各类1，3-二羰基化合物反应，成率很高；但对于1-苯乙醇，只能得到很低的产率。

They were acetic acid, benzaldehyde, n caproic acid, methyl pentadecanoic methyl ester, glycerin, benzoic acid,,9 octadecadienoic methyl ester, squalane, stearic acid and oleic eicosyl ester.

它们是乙酸、苯甲醛、正葵酸、-甲基十五烷酸甲酯、丙三醇、苯甲酸、，9-十八碳二烯酸甲酯、角鲨烷、硬脂酸和二十烷基油酸酯。

Two kinds of high alcohol acrylates were prepared by octadecyl alcohol and hexadecyl branched alcohol,respectively.The polymers of depressants were prepared by maleic anhydride-styrene-higher alcohol acrylates.By using these depressants,the pour points of the Liaohe crude oils were lowered form 30℃ to 20℃.

分别采用碳十八直链醇、碳十六支链醇与丙烯酸合成烷基酯，将烷基酯再与顺丁烯二酸酐、苯乙烯聚合制备的三元共聚物，对辽河油田的高凝原油的降凝效果进行了评价，实验发现这两种聚合物对凝固点为30℃原油都具有较好的效果，降幅可达10℃左右，但对凝固点为41℃的原油较差分别为3℃和6℃。

And the morphologies of lead tungstate crystal were different when different surfactants of polygycol 200 and cetyltrimethyl ammonium bromide were added in the experiments.

以钨酸钠和醋酸铅为原料，分别加以表面活性剂聚乙二醇200和十六烷基三甲苯溴化铵，用沉淀法合成出钨酸铅纳米晶和菱形微晶。

Little literature on the aspect of surfactants containing boron with long-carbon chain alkyls had been found.Using diethanolamine, boric acid, hexadecanol as starting materials, after a series of reaction such as vapour phase process bromizating, esterifying, alkylating, a new type of surfactants with boron RNB had been obtained. The structures of the compounds had been identified by elemental analysis, IR and HNMR.

本论文采用二乙醇胺、硼酸、十六醇等为主要原料，经气相法溴化、酯化、烷基化等一系列反应合成了一种新型含硼表面活性剂RNB，并通过元素分析、红外、核磁对其结构进行了确认。

Surfactant p-octyl polyethylene glycol phenyl ether (Triton X-100) or cetyltrimethylammonium bromide was mixed with n-hexane, n-hexanol, and water for preparing reverse microemulsion.

分别以聚乙二醇辛基苯基醚(Triton X-100)或十六烷基三甲基溴化铵为表面活性剂，与正己烷、正己醇和水构成反相微乳液。

Mesoporous tin oxide was synthesized by using cetyltrimethyl ammonium bromide or CTAB and Tween-20 as the template or hydrothermal process. Hollow tin dioxide micospheres were synthesized by using resorcinol-formaldehyde gel as the template or hydrothermal process. Thermogravimetric analysis, X-ray diffraction and electron microscopy have been used to characterize the materials.

本文分别采用十六烷基三甲基溴化铵模板法、CTAB和吐温20复合模板法及水热法来合成介孔氧化锡；用间苯二酚和甲醛凝胶模板法及水热法合成空心球氧化锡，并用热分析、X射线衍射、电镜等对以上材料作了形貌及结构表征。

Plunder melds and run with this jewel!

掠夺melds和运行与此宝石！

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻，也许正是在通往天国的路上，我体验着这白色的晕旋。