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十七烷基

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The extraction equilibrium constants of Nd , Eu , Am in the system of seven monoacidic organophosphorus compounds dodecane 1. 0mol/l NO〓are reported. The dependency of the extractability on the PO〓function group、bonding charactor、metallic ion species and the structure of substitute has been examined.

给出了七个烷基磷酸的正十二烷熔液从1.0mol/lNO〓水溶液中萃取Nd、Eu、Am的平衡分配常数Kex,考察了萃取剂PO〓官能团、萃合物成键特性、金属离子及取代基结构与萃取性能间的关系,发现了:(1)可运用取代基自由能加和模型预测辛基膦酸辛基酯对La、Eu、Nd、Am等三价离子的平衡分配数据。

The main components were myristic acid (19.37%), palmitic acid methyl ester(7.56%), lascorbic acid 2,6dihexadecanoate(6.27%), 8,11octadecadienoicacid methyl ester(5.22%), heptadecane(4.82%), lauryl ethoxylate(2.98%), 2isopropyl5methyl1heptanol (2.62%), tetracosanoic acid methyl ester(2.12%),2ethyl2methyltridecanol (2.08%), et al.

其化学成分主要为肉豆蔻酸(19.37%),棕榈酸甲酯(7.56%),2,6十六烷基1抗坏血酸酯(6.27%),8,11十八碳二烯酸甲酯(5.22%),十七烷(4.82%),十二烷基乙氧基醚(2.98%),2异丙基5甲基1庚醇(2.62%),二十四烷酸甲酯(2.12%),2乙基2甲基十三醇(2.08%)等。

The fatty acid in soybean oil had been determined with a main composition of hexadecanoic acid C(subscript 16:0, 8.6%, octadecenoic acid C(subscript 18.2, 52.1%, octadecenoic acid C(subscript 18:1, 33.1% and octadecanoic acid C

而加氢产物中检测到正构烷烃同系物,以正构十七烷烃和正构十八烷烃的含量最高,分别约为16.5%和18.5%,同时检测到少量烷基苯同系物等芳烃化合物。

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