化学方法

The most parts of thesis as follows:1. Five symmetrical intra-molecular charge transfer oligomeric phenylene vinylene light emitting materials were designed and synthesized using oligomeric phenylene vinylene as a framework.2. The structures of target molecule were characterized by ~1HNMR,~(13)CNMR, IR, MS and element analysis.3. In order to study the influence of the location and numbers of electron-donor and electron-acceptor on their photoelectric performance by changing length of OPV chain, the UV spectra and fluorescence spectra of target compounds has been compared. We have researched into main factors effecting on material emitting red-shift; organic electroluminescence device was prepared using the compound P4. The capability of eletroluminescence was researched.4. The photoelectric properties of P4 was explained by quantum chemical calculation (the Gaussian 98 quantum chemistry program). It is greatly contributed know the whole process of charge transfer to guide the design of red emitters.

本文研究的内容主要包括以下部分：(1)设计并合成5个对称的以齐聚苯乙烯类为骨架的分子内电荷转移型齐聚苯乙烯类发光材料；(2)通过IR，MS，~1H-NMR，~(13)C-NMR和元素分析对所合成的目标化合物进行表征；(3)通过对目标化合物的紫外光谱和荧光光谱比较分析，研究改变OPV的长度，电子给体和电子受体的位置及数量对其光电性能的影响，探讨材料发射红移的主要因素；选取性能良好的目标化合物P4制备成OELD器件，对其电致发光性能进行研究；(4)运用Gaussian98量子化学程序包，采用量子化学方法对目标化合物P4的光电性能从理论加以解释，进一步认识荷移跃迁的整个过程，为红光材料的设计加以指导。

Methods Leaves of 11 species of Aloe L. were studied by phytotomy, histochemistry and phytochemistry.

应用植物解剖学、组织化学和植物化学方法研究11种芦荟属植物叶。

Quantum chemistry methods and molecular modeling technology are the main branches of the computational chemistry.

量子化学方法和分子模拟是计算化学的主要分支。

The foreground of transforming biomass energy by boosting up lipid biosynthesis according to transgene and thermochemistry or biochemistry way is very considerable.

通过转基因方式增强油脂生物合成以及通过热化学和生物化学方法转化生物质能的前景是非常可观的。

Efficacious drugs were made of these species for treatment of cough, phlegm, breathe heavily, especially, to cure lung disease. We have investigated on the Chemical constituents of Adenophora stenanthina subspecies xifengsis collected from Gansu Qingyang, and twenty four compounds were isolated from ethanol extraction by chromatography technigues. Twenty compounds were identified by means of chemical and spectra methods（IR, FAB-MS, EI-MS,〓,〓, DEPT , among which three compounds were new as 3βvanilloyloxy-stigmast-5-ene-7β-one; 3β-Vanilloyloxy-stigmast-5-en-7 β-ol; 3β-vanilloyloxy-stigmast-5-en-7β, 15 〓-diol.

我们对采自甘肃庆阳的西峰沙参Adenophorastenanthina subsp.xifengensis）进行了化学成分的研究，利用现代层析手段从该植物的乙醇浸膏中分离出二十四个化合物，经化学方法和波谱技术（红外，质谱，核磁共振谱）鉴定了二十个化合物的结构，其中三个为新的化合物，它们分别是：豆甾-5-烯-7-酮-3β-香草酸酯；7β-羟基-豆甾-5-烯-3β-香草酸酯；7β，15ξ-二羟基-豆甾-5-烯-3β-香草酸酯。

With the rapid development of industries,more and more complicated chemical is used,which lead to creasing waste water,there are a lot kind of harmful chemical materials contained in waste water.

快速发展的工业越来越多地采用各种复杂的化学方法，从而使废水大量增多，而很多废水中含有种种有害的化学物质。

Use NADPH-d to organize chemistry and ABC immunity systematism to learn a method, observe leaf of different dosage ginkgo extracts content gawkish to hemal sex small rat pallium NOS and NNOS positive nerve yuan quantitative influence.

采用NADPH-d组织化学和ABC免疫组织化学方法，观察不同剂量银杏叶提取物对血管性痴呆小鼠大脑皮层NOS和nNOS阳性神经元数量的影响。

Anatise TiO2 nano-powder with high stability and high photocatalytic activity was prepared using precursor metatitanic acid raw material at mild reaction by chemical method.

使用简单的化学方法，以偏钛酸为原料，利用化学添加剂，通过酸碱作用，在较温和的反应条件下（常压、120℃之下），制备了具有高稳定性、高活性的锐钛矿型纳米TiO2粉体。

Characterize the chemical structure of these compounds using traditional wet chemistry techniques as well as Synchrotron-sourced Fourier transform infrared microspectroscopy

应用常规化学方法和同步红外显微光谱仪鉴定生物活性物的化学构成；杆菌O157：H7 效果和调节瘤胃代谢功能的关系

We have investigated on the chemical constituents of Nepeta partite collected from Gansu Zhuanglang, and twenty eight compounds were isolated from the methanol extraction of this species by chromatography techniques. Twenty five compounds were identified by means of chemical and spectra methods IR, FABMS, EI-MS,〓, DEPT, and 2D NMR）, among which four compounds were new as isopimar-15-en-3β, 8β, 20-triol; phenylethanal-3-O-（2'-glycerin）-5-O-β-D-glucopyranoside; 3-O-linolenoylglyceryl-6'-O-(α-D-galactopyranosyl）-β-D-galactopyranoside; ethyl rosemarinate.

我们对采自甘肃庄浪的康藏荆芥进行了化学成分的研究，利用层析手段从该植物的甲醇浸膏中分离出二十八个化合物，经化学方法和波谱技术（红外，质谱，一维和二维核磁共振谱）鉴定了二十五个化合物的结构，其中四个为新的化合物，它们分别是：异海松-15-烯-3β，8β，20-三醇；苯乙醇-3-O-（2'-甘油基）-5-O-β-D-吡喃葡萄糖甙；3-O-亚麻酰基甘油-6'-0--β-D-吡喃半乳糖甙；迷迭香酸乙酯。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。