化学吸附

The less the oxygen content and the more content of N element in the form of pyrrole-N were observed under stronger microwave power radiation. It was affirmed that the desulfurization capability of activated carbon could be greatly increased by microwave modification. According to the analysis on surface physical and chemical characteristics, a mechanism was concluded: Modified by microwave, functional groups begin to dissociate, alkalescency is enhanced, and surface oxygen content is reduced; the amount of active sites produced by dissociation of oxygen-containing groups increased, so did the pyrrole-N groups. Apparently, the activated energy of SO〓 adsorption decreased.

通过比较微波改性活性炭前后的吸附脱硫能力，结合它们的表面物理和化学性质的变化分析，确认微波改性活性炭的脱硫性能有显著提高，其作用机理在于微波处理后，活性炭表面微观形貌发生了较大的变化，化学基团发生分解，碱性特征增强，表面含氧量减少，以CO形式释出的含氧官能团分解后产生的活性部位和吡咯氮官能团数量增加，吸附SO〓的表观活化能降低。

Solution chemistry and theoretical analysis indicated that the results of heavy metal ions adsorption upon brucite conformed with Langmuir and Freundlich isotherm. The conditional stability constants of surface complexation model of brucite adsorbing Cu〓 and Pb〓 were deduced.

通过水镁石吸附重金属离子的溶液化学和理论分析表明，其吸附结果符合Langmuir和Freundlich吸附等温式，并计算出水镁石吸附Cu〓和pb〓的表面络合条件稳定常数。

A surface-modified adsorbent is a support bearing at the surface of a chemically bonded "monomolecular" layer of adsorbing groups, which provides fast kinetics of the recovery and elution of the molecules and ions under study.5–9 SPE by use of alkyl-bonded silica gels has been widely applied in the environmental analysis of

表面改性吸附剂是一种在表面有一层化学键合单一分子层的吸附基团，吸附基团提供分子和离子的恢复和洗脱快速动力学。

The research analysed the current status and pollution treatment research review from municipal refuse output, waste physical component, hazards, heavy metal pollution. On the basis of overall understand of current treatment situation about main municipal refuse landfill site of Fujian province. By the simulated test, utilizing 7 kinds of physical adsorbents (zeolite, incineration ashes, slag, plant ash, charcoal, ochre, active carbon), 4 kinds of chemical flocculant FeSO_4, AlCl_3, FeCl_3, Al_2(SO_4_3, and 3 kinds of hyclrophytes, we carried through the pollution removing study of heavy metal in landfill leachate and discussed removing effect of different physical adsorbents, chemical flocculant and hyclrophytes.

并在对福建省主要城市生活垃圾的处理现状全面了解基础上，通过室内模拟试验，分别利用7种物理吸附剂(沸石、焚烧灰、炉灰、草木灰、木炭、赭石、活性炭)、4种化学絮凝剂FeSO_4、AlCl_3、FeCl_3、 Al_2(SO_4_3和3种水生植物进行垃圾渗滤液中重金属的污染去除研究，比较不同物理吸附剂、化学絮凝剂和水生植物对垃圾渗滤液重金属污染的去除效果，试图从中筛选出治理成本低和治理效果好的城市垃圾渗滤液重金属污染修复技术，供南方城市垃圾处理场推广应用。

IR analysis of Leersia Hexandra Swart biomass revealed the presence of carboxyl, amide, hydroxyl and carbonyl groups, which are responsible for biosorption of the metal ion.

结果表明，该吸附是单分子吸附的伪二级动力学过程，吸附过程包含两个步骤： Cr离子通过静电作用富集在干粉材料表面，随后干粉表面存在的功能配位官能团会与Cr发生化学作用。

The invention is characterized in that the molecule of the polymer adsorption material has a structure in formula I: in the formula, R is selected from the natural polysaccharides with amino groups and hydroxyls and the derivatives thereof or the chemosynthetic polymers, the molecular weight of which is from 6 KD to 500 KD; X is selected from a C0 to C6 paraffinic chain with O atoms, N atoms or OH groups; R1, R2 and R3 are selected from a C1 to C4 alkyl group.

生物医学材料领域中的水溶性阳离子多聚物吸附材料及其应用，包括采用带有氨基或羟基的天然多糖及其衍生物或者化学合成多聚物季铵化反应合成，其特征在于该多聚物吸附材料分子具有式的结构：式中，R选自粘均分子量范围为6KD～500KD的带有氨基或羟基的天然多糖及其衍生物或者化学合成多聚物；X选自含有O原子、N原子或者OH基团的C 0 ～C 6 烷链；R 1 、R 2 、R 3 选自C 1 ～C 4 的烷基。

In the sixth chapter, according to our nations situations, a probing study on the development and application of natural mordenite was carried out at the aim to develop a new adsorbent carrier and reduce the cost of adsorbent preparation. The characters of natural mordenite were chemically changed by an acid. The effects of the acid solution concentration, temperature, mordenite size and treatment times on the physico-chemical characters of mordenite were undertaken. The adsorption equilibrium of CO on the character-changed natural mordenite was measured.

在第六章中，结合我国的实际情况，对天然丝光沸石的开发利用进行了探索性的研究，期望开发一种新的吸附剂载体，以降低吸附剂的制备成本，为此，对天然丝光沸石进行了酸化学改性，研究了酸溶液和浓度、温度和沸石粒度以及处理次数对丝光沸石物理化学性质的影响，测定了CO在改性丝光沸石上的吸附平衡。

Because of this property, water is preferentially adsorbed by these surfaces, and large organic compounds cannot compete with strongly held water for adsorption sites on the clay surfaces. Thus, Na-clays are ine_ective sorbents for small organic molecules. However, it is possible to modify the surface properties of clays greatly by neutralizing the anionic framework of layer silicates by using positively charged organic species such as alkylammonim ions. In the modi_ed form (HDTMA-bentonite), the clay surface may become organophilic and interact strongly with organic compounds. Textile dyes represent a relatively large group of organic chemicals. In an HDTMA-bentonite-dye system it is possible that adsorption may be enhanced by the hydrophobic interaction between the adsorbed dye molecule and HDTMA-bentonite.

O组给予亲水的性质到矿物表面，因为这水是吸附在这些表面，和大的有机化合物不能比有坚强的为了吸附位置在泥土表面，因而，Na—泥土是ine_ective吸附剂为了小的分子，希，它是可能的到更改的表面属性，泥土非常在抵销anionic层硅酸盐在用的结构 Positively负荷的物种例如alkylammonim离子，在mod i_ed形状，泥土表面可能变成organophilic和互相作用坚强地有机化合物，织物染料表现相关的大的组化学的，在HDTMA—斑脱土—染料系统它是可能的那吸附可能是提高在交互作用在中间吸附染料分子和HDTMA—斑脱土，interlamellarHDTMA的间隔—斑脱土是获得在substracting泥土层从的厚度实验上坚决的基础的间隔（d001）。

In the initial stage of the bioleaching, when the bacteria are not active, the chemical oxidation of ferric irons to the solid sulfide minerals is primary; While in the whole course of the bioleaching, it is very limited; ferric irons inhibit the bacterial activity, lower the oxidational ability of the bacteria to ferrous irons in the liquid phase; ferric irons and their precipitations reduce the quantities of the attached bacteria and their activity, and have bad influence on the direct bioleaching action.

结果表明，在浸出的初始阶段，Fe3+的化学氧化作用是主要的；但在整个金属浸出过程中，Fe3+的化学氧化作用是很有限的；Fe3+对T.f菌有一定的抑制作用，降低了它们对液相中Fe2+的氧化能力；Fe3+及其沉淀使细菌在固体矿物颗粒表面的吸附量减少，降低了吸附细菌的活性，从而影响了细菌的直接氧化浸出作用。

The depressing ability of the macromolecule organic depressants can be improved by the increase of their D.S.. The high D.S. CPVA and CPEG show strong depressing ability to calcite, while CPEG indicates strong depressing ability to diaspore, and HPAM to pyrite.The depressing mechanism of organic depressants was confirmed by the measurements of zeta potential, contact angles, adsorption capacity and IR spectrum.

利用动电位、接触角、吸附量和红外光谱等测试方法和手段，探讨了抑制剂的作用机理：苯氧乙酸类小分子抑制剂与方解石之间可发生较强的化学作用，可以选择性地吸附在方解石表面，使捕收剂发生解吸或阻止捕收剂在矿物表面的吸附而使矿物受到抑制；大分子抑制剂则主要是依靠亲固基吸附在矿物表面，再利用其长链的强亲水性而使矿物受到抑制。

The reasons of iron ions content overproof in grade Ⅱ desalting water system,such as variation water quality,contamination of regenerant , operation adjustment of pretreatment system and switching operation of bed were discussed.

对二级脱盐水系统中铁离子含量超标的原因，如来水水质发生波动、再生剂受到污染、预处理系统操作调整、床体运行切换等进行了论述。

You were hired to drum up new business, so go and do it.

公司雇你招徕新业务，你就做你的事好了。