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化学合成

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In this review, basically classified by the chemical construction of dendritic skeleton, mainly focusing on the polyamidoamine, polypropylene imine, polycarbosilane, polyether and polyester systems, the recent advances in the rationally designed syntheses and their self-organized superstructure of side-chain LC dendrimers have been summarized and commented.

本文按树枝状大分子骨架的化学结构分类,对侧链型树枝状大分子液晶的设计合成、液晶相行为及其自组织超结构的最新研究进展进行总结和评述,重点介绍了聚酰胺-胺、聚丙烯亚胺、聚碳硅烷、聚醚以及聚酯树枝状大分子液晶体系。

In addition to this,we discussed the stereochemistry in the synthesis of polyhydroxyα-amino acid based on chiral tert-butanesulfinyl amide.

除此之外,我们还系统讨论了基于叔丁基亚磺酰胺的多羟基取代α-氨基酸合成方法中的立体化学问题。

The effects of unsaturation, substituents and stereochemistry of molecular structure on the reaction mechanisms and the synthetic applications are studied.

探讨分子构造中不饱和基、取代基及立体化学对光、热反应机构之影响,并结合光和热反应开发新的合成方法。

For each group of compounds, their nomenclature, chemical physical properties, synthesis,reactions, and stereochemistry are taught.

针对每一类别的有机化合物,教导内容包含命名原则、合成方法、化学与物理特性、反应机制及立体结构。

The invention adopts a low temperature solid state reaction method, proceeds from europium oxide, molybdenum oxide and strontium carbonate, and can synthesize the UV-excited europium-doped strontium molybdate LED red phosphor having stable chemical performance without high temperature calcinations. The method is high in maneuverability and good in reproducibility. The obtained product is stable in quality and regular in appearance.

本发明采用低温固相反应法从氧化铕,氧化钼与碳酸锶出发可以不需要高温煅烧合成出化学性能稳定、紫外激发LED用铕掺杂钼酸锶红色荧光粉,本发明方法的可操作性强,重现性好,所得产品质量稳定,形貌规整。

The possible reason is that in shock waves a nonstoichiometric ferromagnetic zinc ferrite is formed, in which the distributions of the cations in the A and B sites of the sublattice are different from that formed in calcination, it has stronger exchange interaction and leads to the increase of the magnetization.

可能的原因是冲击波合成了非化学计量比的铁磁性铁酸锌,改变了尖晶石次晶格中A,B位阳离子的分布而使其具有更强的交换相互作用而导致其磁化强度的增加。

A series of cholesterol-bearing O-carboxylmethyl chitosan conjugates with different degrees of substitution of the cholesterol moieties and cholesterol-bearing chitosan were synthesized by the succinyl linkages and characterized by Fourier transform infrared, Proton Nuclear Magnetic Resonance (~1H NMR) and elemental analysis. These hydrophobized chitosan derivatives were amphiphilic in nature and their self-aggregation behavior in aqueous media was evaluated by the fluorescence probe technique.

课题的主要研究内容如下:采用化学的方法合成了不同分子结构、不同取代度的系列胆甾醇基壳聚糖衍生物—胆甾醇基壳聚糖和胆甾醇基-羧甲基壳聚糖,并应用先进的分析手段电位滴定、红外光谱法(IR、核磁共振波谱法等对原料、中间产物以及产物进行了结构表征,衍生物分子中的胆甾醇基取代度(3.2%~12.5%)采用元素分析的方法进行检测。

The main study of this dissertation is shown as follows.1.Two new amphiphilic steroid derivatives(N-cholesteryl succinyl glucosamine, CSG and N-deoxycholyl glucosamine,DCG) were designed and synthesized.Their chemical structures have been confirmed by means of Fourier Transform Infrared Spectrometry,Nuclear Magnetic Resonance Spectrometry and Mass Spectrometry.

设计、合成了新型的两亲性甾族衍生物—N-胆固醇琥珀酰基氨基葡萄糖(N-cholesteryl succinyl glucosamine,CSG)和N-脱氧胆酰基氨基葡萄糖(N-deoxycholyl glucosamine,DCG),并采用傅立叶红外波谱仪(Fourier TransformInfrared Spectrometry,FT-IR)、核磁共振波谱仪(Nuclear Magnetic ResonanceSpectrometry,NMR)和质谱等分析仪器对原料、中间产物和最终产物的化学结构进行表征。

"Sulfa drug: Common term for sulfonamide drug, any member of a class of synthetic antibacterial drugs with a particular chemical structure including Both sulfur and nitrogen atoms."

磺胺药:任何同时含有硫和氮原子的特殊化学结构的合成抗菌药物。

The preparation of a novel chiral sulfonamide alcohol derived from natural camphor and its application in the titanium tetraisopropoxide-promoted enantioselective addition of diethylzinc to benzaldehyde is described.

由天然樟脑合成了一个新手性磺酰胺醇,并对其在二乙基锌对苯甲醛的对映选择性加成中的催化性能进行了研究,获得了73%化学产率和

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This paper discusses design and realizable methods of remote test output interface from logical design angle.

本文从逻辑设计的角度讨论遥测输出接口的设计及实现方法。

This also 星体投射plies to buildings, structures and geological features.

这也适用于建筑物和地质特征。

We all hope for a better life.

我们都希望好的生活。