化学合成

The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.

通过Diels-Alder环加成反应，用茚〓和1，1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物，发现可控制反应条件，使1，1'-联茚与〓反应，并高产率地得到具有新颖结构的单加成物，用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征，测得它的两个〓杂化的桥头碳的化学位移为〓ppm，证明生成的衍生物为6∶6闭式环加成，〓NMR谱中共给出38个信号，表明〓联茚衍生物分子具有〓对称性；在波长532nm，脉冲宽度8ns的激光下，〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近，由于〓联茚单加成衍生物熱稳定性好，在四氢呋喃，丙酮等极性溶剂中溶解性好，能分别均匀地掺入溶胶-凝胶中，已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能；使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究，通过等温压缩曲线测试，证明浓度为〓〓时，〓联茚衍生物能够形成单层膜。

The potential superiority of indium trihalide in organic synthesis will promote the development of "Green Chemistry".

三卤化铟在有机合成中潜在的优势将推动"绿色化学"的发展。

In this dissertation, we analyze the observations of CNO elements, and discuss the uncertainties of their abundances. In particular, we calculate the abundance evolution of carbon using different sets of nucleosynthesis yields according to the standard infall model.

我们分析了目前CNO元素的丰度观测结果，总结指出其中存在的一些问题，特别是，依据标准内落银河系化学演化模型，采用不同的核合成产率，详细计算了C元素的丰度演化，并分析了C元素的来源。

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

吉林大学无机合成与制备化学国家重点实验室，长春 130012

The preliminary plan and actualized blue prints were presented,which was to construct an interact teaching,interpenetrative and flexible polymer science experiment course combined polymer chemistry,polymer physics and polymer process.Students learn from molecular design to synthesize polymer compounds and character properties of the materials,them process them to an utilized produce in this course.

设想将高分子化学、高分子物理和高分子成型加工三门实验课程有机地串联起来，组建成一门包括从高分子材料设计(用计算机软件进行分子设计、性能模拟)、聚合物合成、性能测试到加工成型，能环环相扣、互动式的、柔性化的高分子科学实验课程；提出了初步的实践方案。

Ultra-high pressure vessels are widely applied in the fields and industries of chemical, petrochemical, artifical crystal, compound diamond, isometrical hydrostatics treatment, ultra-high hydrostatics extrusion, powder metallurgy, material moulding, physical geography, geologic mechanism etc.

超高压容器广泛运用在化学、石化、人造水晶、合成金刚石、等静压处理、超高静液压挤压、粉末冶金、金属成型、地球物理和地质力学等行业或领域。

The smaller fullerenes C2n (2n 60) violating IPR, inevitable suffer large strain energies and show high lability. Besides that, quasi-fullerenes violating the classical definition, contain rings of other size, for example 4 or 7, are expected to suffer extra local strain or/and further loss ofπdelocalization, and thus highly unstable.

碳原子数少于60的小富勒烯，和结构中含有除五元环、六元环之外的其他结构的准富勒烯，由于不满足IPR规则，结构中必然存在较大的张力，因此具有较高的化学活性，难以在实验中合成和分离。

Levorotatory and dextrorotatory enantiomers of cetirizine and other nine compounds were synthesized and were identified by MS, IR, 1H-NMR and elemental analysis .

通过化学拆分得到单一手性的4-氯-α-苯基苯甲胺，然后由它出发合成出左西替立嗪和其它九个化合物的单一对映体，并经元素分析、红外、质谱、核磁等鉴定。

The relative fluorescence intensity of the system gained the maximum value in phosphate buffer solution at pH 7.3,and the system was quite stable.

两亲高分子聚合物是由武汉大学化学与分子科学学院自行设计和合成[1]。

In the gas-liquid phase reaction of catalytic oxidation of mesitylene by air to synthesize trimesic acid and the related process,an analysis method of reaction components was proposed,which includes chromatographic analysis,mass spectral analysis,IR spectrum,atomic absorption spectrophotometer and chemical titration for the purpose of analyzing reaction groups.

针对均三甲苯气液相催化空气氧化合成均苯三甲酸的反应及相关的工艺过程中，反应产物均苯三甲酸的分析问题，提出以色谱分析、质谱分析、红外光谱分析、原子吸收光谱分析及化学滴定为主要分析手段对反应组分进行分析，重点研究并建立了相关的分析方法。

This paper discusses design and realizable methods of remote test output interface from logical design angle.

本文从逻辑设计的角度讨论遥测输出接口的设计及实现方法。

This also 星体投射plies to buildings, structures and geological features.

这也适用于建筑物和地质特征。