化学合成

Transition metal borides and inorganic boron-containing compounds, such as TiB〓, BN, B〓C and BP, are one of the most important groups for application in high-temperature performance, electronics and catalysts. Traditionally, they were prepared by high-temperature reactions; however, the products were beyond nanometer scale.

中文题名溶剂热合成硼化物及非金属含硼化合物纳米材料副题名外文题名论文作者谷云乐导师钱逸泰学科专业无机化学研究领域\研究方向学位级别博士学位授予单位中国科学技术大学学位授予日期2003 论文页码总数70页关键词纳米材料硼化物溶剂热合成馆藏号BSLW /2003 /O613 /6 硼化物、非金属含硼化合物功能材料（如硼化钛、氮化硼、碳化硼和磷化硼等）通常具有高硬度、高熔点、机械强度大、高温化学稳定性好等一系列优良性能，有些还具有奇异的光、电、磁、热学性能和催化活性，是一类最富潜力的非氧化物高温结构材料、电子材料和催化材料。

Radical ring expansion is a new strategy to synthesize the medium-sized and even large rings, nowadays, it is one of the important research fields of organic chemistry.

而自由基扩环反应是合成中环乃至大环有机化合物的一种有效的新方法，已成为当今有机合成化学的前沿研究领域之一。

The photophysical property of the complex is investigated by means of IR spectra, Raman spectrum and laser excited, high-resolved luminescence spectra which indicates one kind of Eu site with local symmetry of C 2v in the complex.

合成了植物生长素对氯苯氧乙酸和 1，10 邻菲罗林与铕的三元配合物Eu 3·Phen 。对所合成化合物进行了元素分析和热谱分析。通过测定配合物的红外光谱、拉曼光谱和激光激发高分辨荧光光谱研究了配合物的光物理性质。荧光光谱表明配合物中Eu离子只具有一种化学环境，Eu格位的局部对称性是C2v

We have synthesized a series of 4,4′ perfluoro-alkylated bipyridine ligands[4,4′- bis(RfCH2OCH2)-2,2′-bipyridine , Rf=HC4F8(1a), HC8F16(1b), C3F7(1c) and C10F21 (1d)] by nucleophilic substitution reactions. The reaction of fluorinated alkoxide on 4,4′-bis-2,2′-bipyridine results in the systheses of these four fluorinated ligands. These reactions are high yieldings and purification is easy. The structures are analyzed by GC-MASS、NMR、FT-IR etc.

中文摘要我们已合成出一系列在联吡啶的4，4′位置有两个氟化烷基侧链的联吡啶配位基[4，4′-bis(RfCH2OCH2)-2，2′-bipyridine ， Rf=HC4F8(1a)， HC8F16(1b)， C3F7(1c)及C10F21(1d)]，经由亲核取代反应，由4，4′-bis-2，2′-bipyridine反应而得，并具有不错的产率，其纯化也简易可行，所合成之产物并可用GC-MASS、NMR、FT-IR鉴定其化学结构。

In both cases, when they grew the cells in the presence of a chemical that infiltrates newly synthesised DNA, they could see that the unlabelled template strands of DNA went into one daughter cell and the new strands went to the other.

他们在培养基中添加能渗入新合成DNA的化学试剂，结果，两种情况下都观察到未标记的模板DNA链进入了一个子细胞，而新合成的DNA链进入了另一个子细胞。

Particular emphasis is placed on evaluating the significance of the effects of such toxicants on human health.

涉及到与天然毒物相关的生物化学、生物合成、化学、流行病学、免疫学、新陈代谢、营养学、药理学和病理生理学。

Sasol, established in 1950 in South Africa, is one of biggest producer of synthetic fuels and the largest petrochemicals producer in the world. The business of Sasol covers 9 branches including mining, synfuels, chemicals, oil, technology, petroleum and financing etc.

沙索集团是世界上最大的合成燃料和石化产品生产商之一，成立于1950年，总部设于南非约翰内斯堡，下设9个主要大公司，业务领域涉及矿产、合成燃料、化学、油品、气体、科技、石油和金融。

Sasol, established in 1950 in South Africa, is one of biggest producer of synthetic fuels and the largest petrochemicals producer in the world. The business of Sasol covers 9 branches including mining, synfuels, chemicals, oil, technology, petroleum and financing etc, of which the headquarter sets in Johannesburg S.A.

沙索集团是世界上最大的合成燃料和石化产品生产商之一，成立于1950年，总部设于南非约翰内斯堡，下设9个主要大公司，业务领域涉及矿产、合成燃料、化学、油品、气体、科技、石油和金融。

Because of good selectivity to anions in solution of calix[4]pyrroles, the synthesis of calix[4]pyrrole-bonded stationary phase will also provide new means for separation to anions and neutral substances in chromatography and promote the development in supramolecular chemistry.

基于杯[4]吡咯化合物在溶液中对阴离子的选择性识别性能，利用其对色谱固定相进行改性以合成针对阴离子和中性小分子化合物的色谱柱将为色谱分离技术提供新的手段，推动超分子化学在分析化学中的应用并促进杯吡咯化学的发展。

In our research, through derivatization of stable calix[4]pyrroles, active substituting units were jointed on the calixpyrrolic skelecton. After acylamide and free radical transfer reaction, the preparation of new calix[4]pyrrole-bonded stationary phases were fulfilled. the separation abilities of them to inorganic and organic anions and medicines were exploited and new analytical methods were established. The separation mechanisms were discussed. At the same time, through using calix[4]pyrroles as additives in CZE to influence the electrophoresis of inorganic anions, the recognition mechanisms and influencing factors in supramolecular chemistry were also studied.

本项目以新型杯吡咯大环化合物分子识别化学研究为基础，设计合成了含活泼取代基的官能化杯[4]吡咯化合物，通过酰胺化反应和原位自由基链转移反应制备了新型的杯[4]吡咯色谱固定相，系统研究了具有阴离子识别功能的杯[4]吡咯大环化合物作为离子色谱的分离介质对无机、有机离子型化合物和药物分子的色谱分离性能，建立了新的分析方法，对分离机理进行了探索和验证；同时将杯[4]吡咯化合物用作毛细管电泳流动相添加剂，利用其对无机阴离子电泳行为的影响探讨超分子化学中分子识别的机理和影响因素。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失