化学合成

The purpose of this thesis is just to search a novel synthesis of thiourea, and to use thiourea in dealing with the waste water from the production of phthalic anhydride, and the application of thiourea in solid-state reactions at low heating temperature was also studied.

本论文研究的目的就是寻找一种合成硫脲新的工艺过程，且尝试以合成得到的产物硫脲应用于工业苯酐废水的处理，同时对硫脲在低热固相化学中的应用进行了初步的探索。

The in-situ epoxidation and in-situ grafting of unstaturated rubber,in-situ synthetic poly-unstaturated carboxylate,surface in-situ chemical treating of rubber filler,montmorillonite in-situ plugging plyer/peeling,in-situ preparing SiO2 by sol-gel technology were presented.The modification method and effect of rubber were addressed,and the practic application possibility of modificated rubber to rubber goods was researched.

介绍了不饱和橡胶的原位环氧化和原位接枝、原位合成聚不饱和羧酸盐、橡胶填充剂表面原位化学处理、蒙脱土原位插层/剥离、溶胶-凝胶法原位生成SiO2等原位反应合成技术在橡胶加工和改性方面的应用研究工作，讨论了各种改性橡胶方法的特点以及改性效果，并探讨了改性橡胶材料在各种橡胶制品行业实际应用的可能性。

With the hierarchical structure and special assembly. Biomimetic synthesis in spired by the biomineralization involves the controlled formation of inorganic materials with organic assembly as template, and the production of inorganic materials with special microstructure and excellent physical and chemical properties.

仿生合成就是将生物矿化的机理引入无机材料合成，以有机物的组装体为模板，去控制无机物的形成，制备具有独特显微结构特点的无机材料，使材料具有优异的物理和化学性能。

The present dissertation reviews the total synthesis of biotin, particularly on Hoffmann-La Roche\'s Lactone-Thiolactone approach. The Lactone-Thiolactone approach is presently the most competitive commercial route, which gives an excellent illustration of the gradual construction of the functionalized skeleton with the simultaneous solution of the stereochemical issues in a minimal number of steps.In 1970, Gerecke etc. of Roche Corp.

论文对生物素全合成的文献进行了综述，重点讨论了目前工业上最有竞争力的内酯—硫代内酯路线，展示了生物素是如何以最少的步骤去逐步构建目标产物的官能团骨架并同时解决立体化学问题的。1970年，Roche公司的Gerecke等报道了一条通过手性内酯，以较高收率并保持构型得到手性硫代内酯，从而直接合成d-生物素的方法后，该中间体内酯(3aS，6aR)-1，3-二苄基。

This dissertation successfully fabricated cross-linked polysiloxanes under base catalysts such as potassium hydroxide siloxanolate or tetramethylammonium hydroxide (Me_4NOH) siloxanolate by anionic ring-opening copolymerization of cyclosiloxanes and Polyhedral Oligomeric Silsesquioxanes as multifunctional monomers.

本论文首次通过阴离子开环共聚，成功地将POSS大分子作为多官能团单体，与环硅氧烷在KOH硅醇盐或Me_4NOH硅醇盐等碱性催化剂的作用下，直接合成交联聚硅氧烷：通过调节POSS大分子和环硅氧烷单体的种类以及化学计量比，可合成出一系列不同种类和不同交联密度的交联聚硅氧烷；并对其阴离子开环共聚机理以及极性调节剂DMAc对凝胶时间的影响进行了详细讨论；同时借以凝胶含量和溶胀比、GPC、FT-IR、固体~(13)C和~(29)Si NMR、WAXD、DSC以及TG等手段对所得聚合物的微观结构以及热性能进行了详细考察。

A series of copper halides in one, two, or three dimensions have been successfully synthesized such as rhomboid dimers of stoichiometry [Cu2X2L2]n, the tetranuclear species on cubane or stepped cubane tetramers of stoichiometry [Cu4X4L4]n and hexagonal[Cu6X6] grid chains.2 The main strategy in crystal engineering is a secondary building block approach.3 For a given building block, there are two routes to construct frameworks.

在一维、二维或三维的一系列卤化铜已经成功地得到了合成，比如化学计量法[Cu2X2L2]n的长菱形二聚物、化学计量法[Cu4X4L4]n和六边形[Cu6X6]网格链的在立方烷上的四核类或阶梯式立方烷四聚物。[2] 在晶体工程上的主要策略是一种次级构件途径。[3] 对于一给定的构件来说，有两条构件骨架的路线。

Author had started the research on design and synthesis of heterocycles several years ago, mainly focused on the design and synthesis of imidazole, thiazole, tetrazole derivatives and their glucosides, in which most of them may have some particular bioactivities.

本论文主要是围绕具有生理活性含氮杂环化合物的设计与合成而展开的，在论文工作中我们应用液相&一锅法&和固相组合化学方法进行了咪唑环、噻唑环、四氮唑环等具有生理活性的杂环化合物及其糖苷的合成。

The further research will enrich the theory and practice of green C1 chemistry and performance of thermodynamically unfavo-rable reactions.

该工艺为乙酸合成和CH4与CO2的绿色化学利用开辟了新途径，其研究将会丰富C1化学化工的理论与实践，并为实现热力学不利反应提供实验方法和理论依据。

Ithas been demonstrated that coupling between anabolism and catabolism can beseriously dissociated by chemical uncoupler. Chemical uncoupler can restrain anabolicreaction, such can make the excess sludge minimization.

在活性污泥培养中，化学解偶联剂能够将合成代谢和分解代谢解离，抑制合成代谢，从而达到剩余污泥减量化的目的。

Particularly, the neutral anion fluorescence chemical sensor uses cholic acid molecules as the molecule frame, and introduces a neutral thiourea or ureido to the positions of a 3 bit carbon atom and a 24 bit carbon atom to be used as a bonding unit; a fluorescence chemical functional group is introduced to the positions of the 3 bit carbon atom and the 24 bit carbon atom or to other positions and used as a signal unit, and then a neutral anion fluorescence chemical sensor is synthesized.

具体而言是以胆酸分子为分子骨架，在其3位碳原子和24位碳原子上引入中性硫脲或脲基，作为键合单元；在3位碳原子和24位碳原子上或其他位置引入具有荧光化学官能团，作为信号单元，合成中性阴离子荧光化学传感器。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失