化学发光

It has been demonstrated that this kind of materials are applicable in a wide range fields, such as nonlinear optics, two-photon absorption and emission materials, electron-transporting and emissive materials in organic light-emitting devices as well as chemisensors.

这类材料已经显示出非常广阔的潜在应用前景，可以用作非线性光学材料、双光子吸收和发光材料、有机电致发光器件中的电子传输材料和发光材料以及化学传感器等。

It has been demonstrated that this kind of materials are applicable in a wide range fields, such as nonlinear optics, two-photon absorption and emission materials, electron-transporting and emissive materials in organic light-emitting devices as well as chemosensors.

这类材料已经显示出非常广阔的潜在应用前景，可以用作非线性光学材料、双光子吸收和发光材料、有机电致发光器件中的电子传输材料和发光材料以及化学传感器等。

They can be classificated to two kinds. One kind is build by photomultiplier; another kind is build by MCP. The mechanism of delayed luminescence is discussed with subradiation. A photon count system is built. To proof the biophoton is a kind of ultra weak photon stream originate from exothermic reaction, and primarily discuss the relationship between the delayed luminescence and proteins activity, we chose microphyllous banyan leave , ficus elastica leave, gingkgo leave, Chinese fan palm leave, and cinnamomum camphora leave as biological samples. The ultra weak photon emission from normal biosamples, and proteins inactivated biosample were measured separately with photon count system. The results showed that the delayed luminescence of biosamples have

在研究过程中，作者从辐射陷获的角度讨论了延迟发光的产生机制，对生物光子的生物化学起源与相干场起源的统一性进行了探索；自行搭建了单光子探测系统；测量了小叶榕树、印度橡树，银杏树，蒲葵树香和樟树等多种植物叶片样品的延迟发光，获得了大量实验数据；为了证明生物光子是一种起源于放热化学反应能量释放的微弱光子流，并初步探讨生物蛋白活性与延迟发光衰减之间的关系，测量了正常生物样品、生物蛋白灭活样品的延迟发光，同时测量了多种不含蛋白质的无机化学体系作为比对，实验结果和实验数据的回归分析表明：弱光子发射来源于放热的化学反应，延迟发光的强度与衰减时间与生物蛋白活性密切相关。

Owing to the good stability in light, heat and chemical characteristics, the rare earth-doped molybdate is a good kind of luminescent material, but there are few reports on it.

稀土钼酸盐发光材料由于具有良好的光热稳定性和化学稳定性，是一种很好的发光基质材料，但关于稀土钼酸盐发光材料的研究却少有报道。

The most parts of thesis as follows:1. Five symmetrical intra-molecular charge transfer oligomeric phenylene vinylene light emitting materials were designed and synthesized using oligomeric phenylene vinylene as a framework.2. The structures of target molecule were characterized by ~1HNMR,~(13)CNMR, IR, MS and element analysis.3. In order to study the influence of the location and numbers of electron-donor and electron-acceptor on their photoelectric performance by changing length of OPV chain, the UV spectra and fluorescence spectra of target compounds has been compared. We have researched into main factors effecting on material emitting red-shift; organic electroluminescence device was prepared using the compound P4. The capability of eletroluminescence was researched.4. The photoelectric properties of P4 was explained by quantum chemical calculation (the Gaussian 98 quantum chemistry program). It is greatly contributed know the whole process of charge transfer to guide the design of red emitters.

本文研究的内容主要包括以下部分：(1)设计并合成5个对称的以齐聚苯乙烯类为骨架的分子内电荷转移型齐聚苯乙烯类发光材料；(2)通过IR，MS，~1H-NMR，~(13)C-NMR和元素分析对所合成的目标化合物进行表征；(3)通过对目标化合物的紫外光谱和荧光光谱比较分析，研究改变OPV的长度，电子给体和电子受体的位置及数量对其光电性能的影响，探讨材料发射红移的主要因素；选取性能良好的目标化合物P4制备成OELD器件，对其电致发光性能进行研究；(4)运用Gaussian98量子化学程序包，采用量子化学方法对目标化合物P4的光电性能从理论加以解释，进一步认识荷移跃迁的整个过程，为红光材料的设计加以指导。

Bioluminescent creatures use chemicals to make their ownlight.

具有发光能力的生物是利用化学物质发光的。

In order to study novel polyquinolines for their applications in the fields of electroluminescent devices and chemosensors, we synthesize polyquinolines containing phenylamine moiety for single-layer LEDs; moreover, we synthesize polyquinolines with different molecular structures to investigate their properties as fluorescent chemosensors.

中文题名聚喹啉的合成与表征副题名外文题名 Synthesis and characterization of novel polyquinolines 论文作者童辉导师王利祥学科专业高分子化学与物理研究领域\研究方向学位级别博士学位授予单位中国科学院长春应用化学研究所学位授予日期2002 论文页码总数152页关键词发光材料共轭聚合物荧光传感器电致发光聚合物聚喹啉馆藏号BSLW /2003 /O633 /17 本论文是以研究新型聚喹啉材料在电致发光和荧光传感器方面的应用为目的，将芳胺基元引入到聚喹啉主链上，以期使聚喹啉可用于单层电致发光器件中；同时通过合成不同分子结构的聚喹啉来考察其作为荧光传感器的性能和规律。

Quantum chemical CNDO/2 method has been performed to study 20 chloranlines on the electronic structure in order to analyze their toxicities to Photobacterium Phosphoreum. The correlation analysis and the step regression analysis are put in use in this paper.

研究氯苯胺类化合物的电子结构与发光菌毒性的关系，应用CNDO/2量子化学方法计算了20个氯苯胺类化合物的电子结构，探讨了发光菌在5、15、30 min时间内的半抑制浓度的负对数P(5-EC50)、P(15-EC50)、P(30-EC50)与化合物的电子结构的关系。

The chemical composition, crystal morphology, fluid inclusions and thermoluminescent characteristics of non-metallic mineral s such as quartz and carbonate from the Jindoushan gold deposit were studied in detail.

对产于烟台金斗山金矿内的贯通性非金属矿物石英及碳酸盐类的化学成分、晶体习性、流体包裹体和天然热发光特征做了研究，结果表明，矿床的主成矿阶段的环境介质为酸性偏中性，富矿和贫矿石英的热发光曲线均为双峰型，但峰点温度、总积分强度有显著差异。

The mechanism of CL reaction was also studied.

本文还对可能的化学发光机理进行了探讨。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。