化合物

A Michael addition of dimethyl malonate and 2-pentyl-cyclopentenone could conduct a precursor which used for preparing aim compound by a selective decarboxylation.

中间体化合物2-戊基环戊烯酮在一定条件下经Michael加成和选择性脱羧反应合成目标化合物。

In natural drug, isoflavone compounds have specific medicative effects. The reaction between metal ions and isoflavone has not known too much now.

天然药物中的异黄酮类化合物是有明确药效但其与金属离子之间的作用却研究甚少的一类化合物。

By using two-stage separations indicates that, the content of total ketones compound by one stage separation is 12.14%, far lower than 54.95% by two-stage separations, and the content of pulegone and menthone increases from 3.37% and 3.46% by one-stage separation to 19.34% and 22.95% by two-stage separations respectively. But the content of the long chain unsaturated fatty acid and its ester ingredient reduces from 41.58% and 18.88% by one stage separation method to 29.06% and 9.86% by two-stage separations method respectively, also the phenol compound by two-stage separations method can been separated completely.

对荆芥挥发油采用两级分离的研究表明：酮类化合物的总含量由二级分离的54.95%远高于一级分离的12.14%，其中胡薄荷酮和薄荷酮的含量分别由一级分离的3.37%和3.46%增加到二级分离的19.34%和22.95%，而长链不饱和脂肪酸及其酯类成分含量分别从一级分离法的41.58%和18.88%降低到二级分离法的29.06%和9.86%，且二级分离法已完全除去酚类化合物。

The compound can simply and rapidly get into living cells, which has a reaction with free active mercapto group in cells, and fluorescence intensity of the compound is led to be obviously enhancing, thereby the fluorescent probe can be used in fluorescent measurement or fluorescent image of fluactive mercapto group (such as glutathione and the like) in living cells.

该化合物可简单迅速地进入活细胞，与细胞内游离的活性巯基基团发生反应，导致化合物的荧光强度显著增强，进而可以用于活细胞中活性巯基的荧光测定和荧光成像。

During preparation, mercapto ethanol isooctanoate, alkyl or ester tin chloride and organic solvent are first heated and refluxed while adding catalyst; organic layer is then obtained through separating liquid and decompression distilled; and through further steps, the compound is obtained. The synthesis process of the present invention is simple, and has conversion rate higher than 95 %, normal pressure and low reaction temperature, low power consumption and less pollution, and the prepared compound has high reaction activity and low toxicity.

制备时，将异辛酸巯基乙醇酯、烷基或酯基氯化锡和有机溶剂加热回流，同时加入催化剂，然后通过分液，保留有机层，再对有机层进行减压蒸等步骤制得所述化合物；本发明合成工艺简单，转化率大于95％，反应在常压条件下，反应温度低，从而降低了能耗，减少了污染，所制备的化合物具有反应活性高和毒性小的特点，使用安全。

In recognition of its important value in ion-selective electrode study, this thesis aims to develop new types of carriers. Metallorganic compounds, Metal-Schiff base complexes, heterocyclic nitrogen compounds, derivatives of calixarene,Sudan Ⅰ and dialkyldithio phosphate have been tested as carriers for all kinds of ions.

鉴于新型载体的开发在离子电极研究中所具有的重要价值，本文主要开展了这方面的一些研究工作，重点考察了金属有机化合物、金属希夫碱配合物、含氮杂环化合物、杯芳烃、苏丹Ⅰ以及双硫代磷酸脂衍生物等各类物质用作离子载体的可能性。

In the paper, a series of metallorganic compounds have been studied by the quantum-chemical calculation with proper basis sets, including:1. a series of carbonyl complexes.2. dibenzene chromium and its derivatives3. ferrocene and its derivatives4. a series of metallic complexes with acetylacetoneWe optimized the geometric configurations of a series carbonyl complexes including Ni4 Fe5, Cr6 with density functional theory B3LYP method at the different levels and confirmed the stable geometry by vibrational analyses. Then we calculated the nuclear magnetic resonance spectra with GIAO method provided by GAUSSION98 program at the different levels.

本文用量子化学计算程序，用密度泛函B3LYP方法，在恰当基组水平上，用GAUSSIAN98程序提供的GIAO方法研究了系列金属有机化合物的核磁共振谱：一、羰基配合物系列：二、二苯铬及其衍生物系列：三、二茂铁及其衍生物系列：四、乙酰丙酮的配合物系列：我们用密度泛函B3LYP方法，在不同基组水平上对第一过渡系羰基化合物的系列配合物进行了结构优化，通过振动分析确定其稳定构型，然后再用密度泛函B3LYP方法在不同基组水平上，用GAUSSIAN98程序提供的GIAO方法计算其核磁共振谱。

For example,the addition reaction with small molecular,the metathetical reaction with alkynes and Wittig reaction to prepare high-valent transtion-metal allenylidene complexes.

对于化合物11，详细研究了其与小分子加成反应、炔烃复分解反应以及通过Wittig反应制备高价态过渡金属丙二烯基卡宾化合物。

The structures of the target molecula and intermediate compounds were characterized by IR, 1H NMR, 13C NMR and MS.

新化合物及中间体化合物的结构利用IR、1H NMR、13C NMR和HRMS进行了结构表征。

The structures of the target molecula were characterized by IR, 1H NMR, 13C NMR, 2D NMR and elemental analysis.

为合成这些新化合物还合成了10个相关的中间体化合物。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。