化合物

Hitherto mankind has relied on fossil fuel for a major part of its energy supply. Obviously the reserve of fossil fuel is by no means unlimited and will eventually be exhausted after decades. Hence, so far as long-term viewpoint is concerned, it is of importance to utilize the abundant and elean solar energy as an alternative energy source. Stimulated by this objective, studies on the preparation of suitable thin semiconductor films of larger size using simpler methods have attracted increasing interests.

从应用角度看，目前人类利用的矿物燃料其储量终究有限，而太阳能广泛存在，作为一种新型的能源，就长远的现点而言，具有巨大的潜力和广阔的前景，近些年来，研究用简单的方法制备大面积的化合物半导体薄膜材料，越来越受到重视，我们采用电沉积的方法在Ni、Ti以及导电玻璃等基底上沉积了多种硫属化合物半导体材料。

The chelating ability of its enolate anion (TTF-ph-tfac) has been investigated with [MIICl_2·xH_2O] (M = Zn and Co) leading to complexes Zn(TTF-ph-tfac)_2(CH_3OH)_2 (7) and Co(TTF-ph-tfac)_2(CH_3OH)_2 (8), where the metal center is coordinated by two TTF-ph-tfac ligands. This redox active ligand shows promising features for the elaboration of hybrid organic-inorganic building blocks.

具有反铁磁行为的化合物5在110-120K观察到了相转变的发生，是目前已报道的该类化合物中最高的相变温度。3、TTF-ph-tfac烯醇阴离子具有很强的配位能力，与金属氯化物螯合配位分别生成了配合物Zn(TTF-ph-tfac)_2(CH_3OH)_2 (7)和Co(TTF-ph-tfac)_2(CH_3OH)_2 (8)，每个中心金属都桥连两个TTF-ph-tfac配体。

The method can be applied in the determination of the estrogenic compounds in wastewater samples successfully.

目标化合物的加标回收率为（94.0±2.9）%～（101±3.8）%，说明该方法能较好地应用于污水中雌激素化合物的定量检测。

The reaction proceeds by ethene chemical adsorption to form the surface ethoxide and the C-C bond formation between the ethoxide and the second ethene molecule to form the butoxide product.

乙烯化学吸附生成的烷氧化合物与物理吸附的乙烯分子发生二聚反应生成新的C-C键同时生成新的烷氧化合物。

A process for preparingp-fluo-2-(2-methyl-3-propionyl)-4-oxy-N,3-diphenyl-phenylbutylamide includes such steps as Friedle-Craft acylating of newly prepared phenylacetyl chloride and fluorobenzene under catalysis of AlCl3 to obtain 4-fluoro-phenylbenzyl ketone, brominating at carbonyl alpha position under catalysis of less AlCl3 to obtain alpha-bromo-4-fluo-phenylbenzyl ketone, and condensing with isobutyryl acetanilide under action of sodium ethoxide.

本发明涉及一种制备对氟－2－(2－甲基－3－氧丙基)－4－氧－N，3－二苯基－苯丁酰胺(1)的方法，其包括以下步骤：新制的苯乙酰氯与氟苯在AlCl3催化下进行Friedle－Craft酰化反应，得到对4－氟－苯基苄基酮(4)；化合物(4)在少量AlCl3催化下进行羰基α位溴化，得到α－溴－4－氟－苯基苄基酮(5)；然后(3)异丁酰乙酰苯胺在乙醇钠作用下与化合物(5)进行缩合。

A simple and efficient method for the synthesis of N3-functionalized 3,4-dihydropyrimidinones by aza-Michael addition reactions of 3,4-dihydropyrimidinones toα,β-ethylenic compounds catalyzed by KF/Al_2O_3 is described.

研究结果表明：DHPMs类化合物可与α，β-不饱和羰基化合物发生Michael加成反应，产物只有N3位功能化的DHPMs，而没有N1位的产物。

A review on the researches about co-enzyme NADH model compounds was given in the first part of this thesis. In the second part, some new synthetically useful reactions employing Hantzsch ester were discussed which are summarized as following (Scheme 1):Scheme 11 The selective reduction of the exocyclic double bond of the 4-arylmethylene- and 4-alkylidene-4H-isoxazol-5-ones and 4-arylmethylene-4H- pyrazol- 5-ones was achieved by using Hantzsch 1, 4-dihydropyridine as the reducing agent in ethanol.

论文包括两个部分：我们在第一部分对辅酶NADH模型化合物的研究作了综述，第二部分是反应研究，分为四章，我们发现和发展了辅酶NADH模型化合物—汉斯酯参与的几个具有合成价值的新反应和体系。

Combinatorial chemistry is a type of synthetic strategy which systematically connects a set of"building blocks"such as amino acids, nucleotide and small organic molecules to yield a large array of diverse molecular entities described as a combinatorial library. It also refers to the process of screening the compounds with the expective activity from the library.

组合化学是将诸如氨基酸、核苷酸、有机小分子等构建单元按某种组合方式连接起来，合成出包含大量化合物的化学库，并从中筛选出具有某种物理、化学或药理活性化合物的一套合成策略和筛选方案。

Compound 2 is isolated from Fagopyrum genus for the first time; compounds 1 and 5 are isolated from Fagopyrum tataricum Gaertn for the first time.

化合物2为首次从荞麦属植物中分离得到，化合物1、5为首次从苦荞麦中分离得到。

compound Ⅱ is isolated from Fagopyrum genus for the first time; compound 1 and 5 are isolated from Fagopyrum tataricum L.

化合物2为首次从荞麦属植物中分离得到，化合物1、5为首次从苦荞麦中分离得到。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。