化合物

In this study,diallyl sulfides in garlic powder were identified via the introduction of Ag induced-ionization.

烯丙基硫化物由于弱极性不电离，本实验利用Ag+柱后诱导电离对大蒜粉剂中的含硫化合物进行质谱定性，并以二烯丙基三硫醚为参比，对各种二烯丙基含硫化合物进行定量测定。

The complexation behavior of these compounds with linear or aromatic dicarboxylate was investigated by the means of absorption, emission spectra,〓H-NMR and molecular dynamics.

结果显示，二羧酸盐阴离子与双链萘基脲／硫脲哌嗪化合物发生络合形成新的物种导致双链萘基脲／硫脲哌嗪化合物的吸收和荧光光谱行为的变化。

Compound Ⅱ and Ⅳ were obtained from this alga for the first time.The others were isolated from the Dictyotaceae algae for the first time.

化合物Ⅱ和Ⅳ系首次从该海藻中发现；其余化合物均为首次从网地藻科海藻中分离得到。

From the pyrolyzed product at 200℃ of Gephyrocapsa oceanica a group of C〓 dicycle terpenoids were firstly identified. They were highly instable and sensitive to temperature because they can only generate at 200℃ and segregate or transform at higher temperature. Therefore they can not only be an indicator of special temperature of organic matter originated from G. oceanica, but can be used to distinguish organic matter from G. oceanica before the hydrocarbon generation peak.

在近海颗石藻Gephyrocapsa oceanica 200℃产出的饱和烃中首次检出了一组C〓二环萜类化合物，这一组特殊的C〓二环萜类化合物在颗石藻来源的有机质中是高度不稳定和温度敏感的，因为它们只在200℃时才形成，更高的温度条件下便解离或转化了，因此，它们既可以是近海颗石藻Gephyrocapsa oceanica来源有机质的特定温度条件的指示，又可以被用于判识该藻类在成烃高峰到来前所形成的有机质。

Our research focused on the synthesis of heterocyclic compounds through the reaction between the dihalogen compounds and amides or carbamates.

我们小组首次进行了二卤代化合物和酰胺或氨基酸酯之间偶联反应的研究，以期发展构筑氮杂环化合物的新方法。

A set of in situ infrared apparatus which can beoperated at liquid nitrogen temperature is established. The structuralstudies of polyhydride of Ruthenium is carried out from roomtemperature to liquid nitrogen temperature. The structural conversion of〓 between dihydrogen and dihydride is observed firstly. It issuggested that with temperature changing, a fluxional structureconversion between terminal and bridged hydrogen appears. NMR studyand DV-Xα calculation are performed in this paper.

建立了可至液氮温度的原位红外测试装置，进行了室温至液氮温度区间钌多氢化合物的结构研究，首次发现了〓在室温存在分子氢与原子氢的结构流变，发现了新化合物存在随温度变化而出现桥氢与端氢的结构转化；进行了NMR测试及DV—〓计算。

The method comprises: utilizing arctiin as the precursor compound, and converting arctiin into 4, 4'-dihydroxy enterolactone by intestinal bacteria in an anaerobic condition. 4, 4'-dihydroxy enterolactone is lignin compound, and can be converted into phytoestrogen in human intestinal canals.

本发明是以牛蒡苷为先导化合物，在厌氧条件下，以肠道细菌将牛蒡苷转化为4，4′-二羟基肠内酯。4，4′-二羟基肠内酯为木脂素类化合物，在人的肠道中能被转化为植物雌激素―肠内酯而发挥药理作用。

Studing on samarium diiodide promoted asymmetric intramolecular reducing coupling reactions, we have made the resolution of the racemic biaryl dials by using enantiomeric N-tert-butanesulfinamine as the resolving reagent successfully and thus obtained a series of axially chiral biaryl dials with high enantiomeric excess.

中文摘要在二碘化钐促进的分子内不对称还原偶联反应中，我们不仅对联芳基二醛底物的合成路线进行了优化，还发现N-叔丁基亚磺酰胺辅基可以作为手性试剂，成功地对联芳基骨架二醛化合物进行拆分，得到高对映体过量的轴手性二醛类化合物。

This reaction was further extended to the coupling reaction of amide with diiodo biphenyl; and the carbazole derivatives were synthesized in 53%-95% yield.

另外将该反应体系的底物进行了进一步的拓展，用酰胺和二碘代联苯化合物偶联，合成了9个咔唑衍生物，收率在53％—95％之间，并运用~1H NMR、~(13)C NMR、HRMS等分析测试手段对这些化合物进行了表征。

The research development of β-diketo in costabilizer field,luminescence field,catalyzer field and extraction field was reviewed.

对β-二酮类化合物在热稳定剂领域、发光领域、催化领域、萃取领域的研究进展进行了综述，并对β-二酮类化合物的发展方向和应用前景提出了自己的见解。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。