化合物

objective effects of plant tannins,chebulinic acid and tellimagrandin i on chemically induced hemoglobin synthesis in k562 cells were investigated.methods the hemoglobin synthesis situation was assayed with benzidine staining.erythroid antigens glycophorin a expression on the surface of k562 cells was labeled by direct immunofluorescence using fluorescein isothiocyanate-conjugated anti-gpa antibodies.then flow cytometric analysis was performed to detect gpa expression levels on surface of the cells.results both chebulinic acid and tellimagrandin i could inhibit the hemoglobin synthesis of butyric acid and hemin-treated k562 cells in a concentration-dependant manner.however,the ba-induced k562 cells were more sensitive to two tannins than heroin-induced cells.conclusion chebulinic acid and tellimagrandin i have inhibitory effect on the erythroid differentiation.

目的 研究可水解单宁诃子酸和特里马素i对氯化高铁血红素和丁酸钠诱导k562细胞红系分化的影响。方法四甲基偶氮噻唑蓝法分析诃子酸和特里马素i对k562细胞生长的影响，联苯胺染色法检测血红蛋白合成情况，应用免疫荧光和流式细胞术检测血型糖蛋白a在细胞表面的表达。结果诃子酸和特里马素i在0.04～0.09？mmol／l浓度下均可显著抑制k562细胞的生长增殖。2种单宁化合物(0.002～0.01？mmol／l)可显著抑制丁酸钠诱导的k562细胞血红蛋白合成，2种单宁化合物(0.01～0.05？mmol／l)还可显著抑制氯化高铁血红素诱导的血红蛋白合成，特里马素i(0.01？mmol／l)还抑制丁酸钠诱导的gpa在细胞表面表达。结论诃子酸和特里马素i对红系分化有抑制作用。

Compounds 1-9 were obtained from this plant for the first time. Compounds 2, 5-9 were isolated from family Chloranthaceae for the first time.

化合物1～9均是首次从该植物中分离得到，化合物2，5～9为首次从该科中分离得到。

First, combined with the corrosion mechanism of carbon steel in chlorhydric acid, the relation between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles are developed in terms of Hansch Relation.

最后，运用灰色理论，通过建立苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀性能与分子结构关系的灰色缓蚀模型，研究了苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀性能与分子结构的关系。

ABSTRACT Inhibition mechanism and the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles whose inhibition is caused by chemical adsorption and quaternary ammonium salts whose inhibition is caused by physical adsorption are mainly studied from microscope through quantum chemistry calculation, and the relations between inhibition efficiency and molecular structure of inhibition of carbon steel in chlorhydric acid by benzene nitriles are studied by making use of model-constructing thought of grey theory in this paper.

本文主要通过量子化学计算，从微观角度研究了化学吸附型缓蚀剂苯腈类化合物和物理吸附型缓蚀剂季铵盐在盐酸溶液中对碳钢缓蚀的缓蚀机理和缓蚀性能与分子结构的关系；并运用灰色理论建模思想，研究了苯腈类化合物在盐酸溶液中对碳钢缓蚀的缓蚀性能与分子结构的关系。其中，通过量子化学计算，从微观角度研究物理吸附型缓蚀剂在盐酸溶液中对碳钢缓蚀的缓蚀机理和缓蚀性能与分子结构的关系，是在尝试着进行；而运用灰色理论建模思想，研究缓蚀剂缓蚀性能与分子结构的关系，是一项具有尝试性和开拓性的工作。

The biomarkers such as the n-Alkanes, the isoprenoids, the terpane, and cholestane were detected through GC-MS analysis. Based on the study of the biomarkers, the biological evolution during Permian and Triassic can be divided as three stages, namely, the mixing source stage of low biota such as thallose and advanced plant in late Permian (below bed 63), the stage of low biota such as thallose in the boundary transitional layer (bed 63-69) and the mixing source stage of advanced plant and low biota such as thallose in early Triassic (above bed 69). What's more, the second stage near the boundary transitional layer can be subdivided into 4 stages. The stages of biota evolution is close related with sedimentary environment changing and the boundary transitional layer.

利用GC—MS分析技术，在陆相地层中检测出正构烷烃、类异戊二烯烷烃、萜烷和甾烷类生物标志化合物并根据生物标志化合物和特征值研究，将二叠系—三叠系生物演化划分为三个大的阶段，即晚二叠世的菌藻类低等生物与高等植物混源阶段（63层以下），界线异常层的菌藻类低等生物阶段（63-69层）和早三叠世高等植物与菌藻类低等生物混源阶段（69层以上），界线附近异常层的第二阶段又进一步细分为4个次一级阶段，生物演化阶段与沉积环境变化及界线异常层具有非常密切关系。

The author found that the chromone ring could be cleaved at high temperature in PPA, and the change of the ratio of ring-opened product versus the target one with the change of reaction time and temperature was investigated in details.

我们采用了两条不同的合成路线合成了第Ⅳ类化合物，对部分反应条件进行了优化，在研究过程中发现了色酮化合物在高温下的开环反应及多聚磷酸的水解作用，并对前者进行了详细研究了，获得了不同反应温度和时间下未开环产物和开环产物的比例，得到了制备相应的未开环产物和开环产物的最佳反应条件。

To study the bioactive components from water soluble extract of the Chinese eaglewood, various column chromatography of Chinese eaglewood led to the isolation of ten compounds. Their structures were elucidated as 2,3-bis(3-hydroxyphenyl)- propan-1-ol (1), [(2R,3R)-3-(4-amino-3,5-dimethoxyphenyl)oxiran-2-yl]methanol (2), 8-chloro-4'- methoxy-5,6,7,3'-tetrahydroxy-2-(2-phenethyl)-5,6,7,8-tetrahydrochromone (3), 4'-methoxy-5,6,7,3'-tetrahydroxy-2--5,6,7,8-tetrahydrochromone (4), the isomer of 4 (5), 4'-methoxy-5,6,7,8-tetrahydroxy-2-(3'-hydroxyphenethyl)-5,6,7,8- tetrahydrochromenone (6), 4'-methoxyisoagarotetrol (7), 6-hydroxy-2-(2-hydroxy-2- phenethyl)-chromone (8), 6-hydroxy-2-(2-phenethyl)-chromone (9), 6-hydroxy-2-(4'- hydroxy-2-phenethyl)-chromone (10), and Guaiacylacetone (11) by means of spectral analysis and comparison with references.

为了进一步发现沉香中具有生理活性的化学成分，本文对国产沉香的水溶性成分进行了研究，从中分离得到11个化合物，通过红外、紫外、质谱、核磁共振(1H-NMR， 13C-NMR， COSY， HSQC， HMBC， ROESY)波谱解析，分别鉴定为：2，3-二(3-羟基苯基)-丙-1-醇(1)，[(2R，3R)-3-(4-氨基-3，5-二甲氧苯基)-2-氧化烯基]甲醇(2)，8-氯-4'-甲氧基-5，6，7，3'-四羟基-2-(2-苯乙基)-5，6，7，8-四氢色原酮(3)，4'-甲氧基-5，6，7，3'-四羟基-2-(2-苯乙基)-5，6，7，8-四氢色原酮(4)，化合物3的差向异构体(5)，4'-甲氧基-5，6，7，8-四羟基-2-(3'-羟基-2-苯乙基)-5，6，7，8-四氢色原酮(6)，4'-甲氧基异沉香四醇(7)，6-羟基-2-(2-羟基-2-苯乙基)色原酮(8)，6-羟基-2-(2-苯乙基)色原酮(9)，6-羟基-2-(4'-羟基-2-苯乙基)色原酮(10)和Guaiacylacetone (11)。

Flavonoids, derivatives of chromone or chromane, are built upon a C6-C3-C6 flavone skeleton in which the three-carbon bridge between the phenyl groups is commonly cyclized with oxygen. There are diverse group of plants containing flavone, isoflavone, flavonol, chalcone, ect.

黄酮类化合物系色原烷或色原酮的衍生物，其基本骨架具有C_6—C_3—C_6的特点，即指两个苯环通过中央三碳链相互连接而成的一系列化合物。

The fact that wastewater has higher chromaticity removal efficiency in acid medium than in basic medium indicates that H+ ions play an important role in chromaticity removal ,possibly by a mechanism of deoxidation in which H+ ionsreact with the organic compound of pollutants in wastewater and cause the chain rupture of chromophoric or anxochromic groups from the organic compound molecules.

事实已经废水色度去除效率高，比在酸性介质中显示基本氢离子色度去除起到了重要作用，可能的机制脱氧其中氢离子的反应有机化合物废水和污染物链条断裂造成anxochromic色或团体从有机化合物分子。

As a result of aromatization of organic matter during the thermal cracking of original bitumen into gas,the aromatic hydrocarbons in the bitumen are characterized by abnormally abundant tetra-and penta-cyclic compounds,and predominated by parent aromatic compounds without alkyl chain,such as fluoranthene,pyrene,chrysene, benzofluoranthene etc.

沥青的芳烃组成独特，富含四、五环芳烃化合物，且以萤蒽、芘、和苯并萤蒽等无烷基取代的母体芳烃化合物为主，反映出沥青裂解成气过程中的有机质芳构化作用。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。