化合物

In order to improve the yield and the stablity of the carbyne complexes,thiophenol group was introduced to connect to the tantalum center of compound 1.And "one pot" ylide transylidation reactions were carried out and the carbyne complexes(12-19) were also obtained.

为了提高卡拜化合物的产率和稳定性，我们在金属钽配合物(1)上引入供电子基团，采用"一锅煮"法与叶立德发生转化反应，同样也可以得到金属钽的膦基卡拜化合物(12-19)。

Result The results showed that its components were quite complex, and 89 organic compounds were identified. There were 72 kinds of oxygen-containing organic compounds which included esters, phenols, aethers, ketones and alcohols in the depolymerization product, small amounts of alkanes, alkenes, arenes, thiophenol and nitrogen-containing organic compounds were also detected, which showed that characteristics of the product with high oxygen content, low nitrogen and sulphur content.

结果］超临界乙醇解聚产物成分十分复杂，GC/MS分析鉴定出89种有机化合物，其中72种为含氧化合物，主要有酯、酚、醚、酮和醇等，还检测出少量烷烃、烯烃、芳烃、苯硫酚和含氮化合物，反映了解聚产物的高含氧量和低含氮硫量的特性。

CH3OH could attack the phosphor atom in 1,3,2-dioxaphopholane of compiound (1) to give O-methyl O-hydroxyethyl-O-phthalimidoethyl thiophosphate in 85% yield; in the presence of potassium hydroxide aryl selenol could attack the carbon atom in 1,3,2-diox-aphopholane of the cyclic phospholipid conjugate of N^1-(2-furanidyl)-N^3--5-fluorouracil to give the corresponding product of ring-opening in high yields.

在室温下，以异丙醇作溶剂，苯硒酚与化合物2不反应。在氢氧化钾存在下，以异丙醇／水作溶剂（体积比20：1，在室温下，硒酚可以有效地进攻中化合物2中1，3，2-二氧磷杂环戊烷中的碳原子生成相应的开环产物。按照这一反应条件，顺利实现了硒酚对N^1-（2-呋喃基）-N^3-羟烷基-5-氟脲嘧啶硫代环甘油磷脂缀合物的亲核开环，生成甘油骨架的端碳原子上带有芳硒基新颖的磷脂核苷缀合物。

Chemical compounds and mixtures containing uranium and thorium are active in direct proportion to the amount of these metals contained in them.

含铀和钍的化合物和混合物活跃的程度与这些化合物和混合物中这两种金属的含量直接相关。

I found in this way that of the other elements known, only the cornpounds of thorium behave like the compounds of uranium.

于是我发现在其他所有已知元素中，只有针化合物才有像铀化合物一样的特性。

Methods After extracting the samples, the reaction between thymol and nitrate produced nitrothymol in the presence of sulphuric acid; then nitrothymol was made to react with sodium hydroxide; determination was made on the concentration of nitrate by spectrophotometry at 412 nm.

样品经提取，其中的硝酸盐在硫酸酸性条件下，与麝香草酚生成硝基化合物，再与氢氧化钠作用，生成黄色化合物，在波长412nm处用分光光度法测定食品中硝酸盐含量。

The invention relates to a process for producing polyethylene terephthalate 1, 3-propanediol, which comprises the following steps: using titanic acid ester as major catalyst, using germanium compounds and cobalt compounds as synergic catalyst, conducting esterification reaction for poly terephthalic acid and 1, 3-propanediol according to the molar 1:1.05-2.2 under the nitrogen pressure of 0.1-0.4MPa and 230-265 DEG C, or conducting ester exchanging reaction for poly terephthalic acid and 1, 3-propanediol according to the molar ratio 1:1.8-2.2 in 160-220 DEG C, decompressing reaction to high vacuum 10-150Pa, wherein the final temperature of reaction is 265-275 DEG C, recovering to normal pressure with nitrogen to obtain the PTT product.

本发明涉及一种生产聚对苯二甲酸1，3-丙二醇酯的方法，采用以钛酸酯为主催化剂，锗化合物和钴化合物为协同催化剂，对苯二甲酸二甲酯和1，3-丙二醇按摩尔1∶1.05-2.2，在0.1-0.4MPa氮气压力和230-265℃下进行酯化反应，或对苯二甲酸二甲酯和1，3-丙二醇按摩尔比1∶1.8-2.2，在160-220℃进行酯交换反应，将反应减压至高真空10-150Pa，反应终温在265-275℃，用氮气恢复到常压，得到本PTT产品；大大缩短了反应时间，直接聚合制备特性粘度在0.7-1.05dL/g的PTT切片，使反应产物色相良好，PTT产品可用于纤维加工及工程塑料领域。

The results showed that the phenolics in cranberry would reduced. The free quercetin showed the best stability. And the flavonoids and proanthocyanidins were the second. The total phenolics showed the worst stability.

结果显示，蔓越莓中的酚类化合物含量会随储存时间而下降，其中以游离态quercetin之安定性最佳，总类黄酮及前花青素则其次，在总酚类化合物之安定性最差。

In this paper, we designed a series of pyrrolo[2,1-f][1,2,4]triazine (Compound 51 and 52) as potential novel tyrosine kinase inhibitors.

本文中设计了一系列4，5，6三取代的新型吡咯并[2，1-f][1，2，4]三嗪化合物（化合物51，52）作为潜在的酪氨酸激酶抑制剂。

Objective: Design and synthesis of novel triazole antifungal derivatives based on the structure of fluconazole.

目的：以氟康唑为先导化合物，设计合成新的三唑醇类化合物，并研究其抗真菌活性。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。