化合物

Experimental results show that the different substituted location and different substituted group on benzene cycle would result in the diversity of reduction properties of substituted aryl nitrobenzene. Substituted nitrobenzenes with withdrawing group will be reduced at more positive potential, while those with repelling group will be reduced at more negative potential. In addition, the reduction potential of nitro group of o-nitrobenzene shifts more negative due to the effect of space resistance.

结果表明，芳族硝基化合物在苯环上的取代基位置不同以及在相同位置上取代基的种类不同均可使各芳族硝基化合物的电还原性能发生较大差异：吸电子取代基在电还原过程中电位较正，推电子取代基的电还原电位较负：邻位取代基在反应过程中由于空间位阻效应，苯环上的硝基在电还原时电位往负方向移动。

Methane, oxygen and H_2O molecules are activated, ionized and dissociated into active particles such as CH_3~+, O~-, H_2O~+, CH_3, CH_2, CH, H,OH and O, by nonelastic collision with high energy electrons. The particles react with each other in the reactor to synthesize chemically products including gaseous oxy-hydrocarbons.We study the rule of reaction by changing electrical parameter, gas flow etc. Study the conversion of methane, selectivity of gaseous hydrocarbons and yield of methanol under different reaction condition.

针对常规甲烷催化转化和氧化偶联制备含氧化合物的问题，遵循国际化学科学研究前沿"绿色化学"原则，采用自然界存在丰富的CH_4、H_2O和O_2为原料，在绿色友好的常温大气压无任何催化剂的条件下，采用强电场电离放电加速电子及其激励气体分子的极端物理手段，在反应腔体内进行无任何环境污染的非平衡等离子体化学反应，将气体分子激发、电离、离解成CH_4~+、CH_3~+、CH_4~·、H_2O~+、H_2O~·、O_2~+、O(~1D)等活性粒子，生成气态烃及含氧碳氢化合物，整个反应过程实现零污染、零副产品。

The recent progresses in the study on the fluorescence of rare earth complexes and application for the determination of the rare earth elements and organic compounds, as fluorescent probes for bioactive materials analysis and as detection means in separation technology were reviewed in detail. In chapter two, the absorption spectra of the 4f electron transitions of the complexes of the neodymium, praseodymium, holmium and erbium with fleroxacin in the presence of CPC have been studies by normal and derivative spectrophotometry.

本文以稀土元素配位化学为基础，以导数吸收光谱技术和荧光光谱技术为研究手段，利用新一代喹诺酮类抗菌药物，抗凝血类杀鼠药物的化学结构特点和大环化合物冠醚与金属离子突出的配位能力，以分析应用为目标，系统研究了这些化合物同稀土元素形成的配合物的光吸收和荧光特性，通过对体系实验条件的优化，使体系的稳定性、选择性和灵敏度得到显著改善。

These odoriferous organic compounds contain numerous ingredients generally classified into four main groups which are characteristic of the majority of essential oils.

这些有味的有机物化合物含有大量的复杂的化合物，它们都是绝大多数植物油的主要成分，可以分成四大类。

Epoxides, episulphides and ethylene imines also polymerize via similar cyclic onium ion mechanisms.

环氧化合物，环硫化合物和乙烯亚胺也可以按类似于环氧？睦胱拥幕？理进行聚合。

Epoxides, episulphides and ethylene imines also polymerize via similar cyclic onium ion mechanisms

环氧化合物，环硫化合物和乙烯亚胺也可以按类似于环氧？

Several transient compounds were synthesized by the homo- and heterogeneous reactions of reactive halogen compounds, In-situ ultraviolet photoelectron spectroscopy and photoionization mass spectroscopy as well as theoretical calculations were used to study their molecular structures, stability and molecular orbital properties, their electronic structures and geometric structures were obtained for the first time; Simultaneously, the electronic structure and thermal dissociation of acetyl peroxynitrate and trifluoroacetyl peroxynitrate which have great importance in the atmospheric chemistry were studied; The substituent effects of series of halopyridines and halothiophenes were studied by the ultraviolet photoelectron spectroscopy method for the first time. The atmospheric chemical reaction between peroxyacetyl radicals with IO radicals as well as the dissociation of the most stable isomer of CH3COIO3 were calculated by density functional theory, it was found that the CH3COOIO2 isomer may be act as a new reservoir of inorganic iodine in the stratosphere.

通过活性卤素的系列均相与非均相化学反应合成了几种瞬态物种，采用原位紫外光电子能谱和光电离质谱结合量子化学理论计算对化合物的分子结构、稳定性以及分子轨道特性进行了研究，首次获得了这些物种的电子结构和几何结构的信息；同时研究了大气中有重要作用的乙酰过氧硝酸酯和三氟乙酰过氧硝酸酯的电子结构性质及热解过程；采用紫外光电子能谱手段首次研究了系列卤代吡啶和噻吩的取代基效应；通过量子化学理论计算研究了乙酰基过氧自由基与IO自由基的大气化学反应及其最稳定异构体CH3COOIO2的解离，发现该物种可能是无机碘化合物在平流层中的储库物种。

This is the first example of a double-recognition between functionalized-β-CD host and organometallic guest.

这是 第一个修饰β-环糊精主体分子与有机金属化合物客体发生双重识别而形成自包合化合物的例子。

Phosphorus compounds result from degradation of compounds such as nucleic acids and phospholipids and occur as inorganic phosphates,that is ,orthophosphate or polyphosphate,or organic phosphorus.

"含磷化合物是由象核酸及磷脂这样的化合物的降解而产生的，并以无机磷酸盐，也就是正磷酸盐或多磷酸盐的形式存在，或以有机磷的形式而存在"

Characteristics of pore structures and oil production potential of sandstone reservoir of Paleogene Xingouzui Formation in Jianghan Basin

性质：用示踪原子标记制备标记化合物时，示踪原子在所指定的标记化合物中的量与参加反应的示踪原子总量之比值。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。