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化合物

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The chemical constituents have been isolated from Delphinium tatsienense Franch Var Chinghaiense by column chromatography and preparative thin layer chromatography.

用柱层析、制备薄层层析等对青海翠雀的化学成份进行了分离,并用IR ,EA ,MS ,1HNMR ,13 CNMR及DEPT等光谱确定了化合物的结构,共分得 5种二萜生物碱,其中一种为新化合物,还分得一种非生物碱β谷甾醇

The chemical constituent s have been isolated from Delphinium tatsienense Franch Var Chinghaiense by column chromatography and preparative thin layer chromatography.

用柱层析、制备薄层层析等对青海翠雀的化学成份进行了分离,并用IR ,EA ,MS ,1HNMR ,13 CNMR及DEPT等光谱确定了化合物的结构,共分得 5种二萜生物碱,其中一种为新化合物,还分得一种非生物碱β谷甾醇。

The interactions of the model compound (FL4) or diad composed of fluorescein and 2-methyl-anthraquinone and TiO_2 colloid have been examined by absorption, fluorescence spectroscopy and fluorescence lifetime.

测定了以荧光素为光敏剂的电子给体-受体二元化合物荧光素蒽醌甲酯及模型化合物荧光素丁酯(FL4)在溶液中和在二氧化钛(TiO_2)胶体中的吸收光谱、荧光光谱、荧光寿命等。

They had suppressed the cathodic process of carbon steel electrode. Their inhibition performance was also related with their molecule stereo conformation and electron configuration. Four of bis-(1, 1'-benzotriazoly)-α,β-diamide compounds linked via-CO 〓CO-chain were synthesized and certified by IR and 〓H-NMR. The minimum energy conformations of these compounds were obtained by MM2 forcefield program. The two benzotriazole moiety in BBT1 was more planar than in other compounds. This was beneficial in increasing the inhibition effects of BBT1. In 0.5M H〓SO〓 solution, BBT1 suppressed anodic corrosion reaction. In 3%NaCl solution, BBT1 suppressed both cathodic and anodic corrosion reactions. 1- [ (1'-imidazolly)-methyl] benzotriazole was synthesized by Mannich reaction.

合成了四个通过-CO〓CO-连接的双(1,1'-苯并三唑)-α,ω-二酰胺化合物,采用MM2分子力学程序优化了它们的分子结构,双(1,1'-苯并三唑)-α,ω-二酰胺化合物的缓蚀作用与其分子内两个苯并三唑单元的空间取向有关系,良好的平面性有利于苯并三唑二聚体的吸附和缓蚀作用,苯并三唑二聚体BBT1分子内两个苯并三唑单元近似平行,所以显示出较好的缓蚀效果。0.5M硫酸中BBT1主要抑制铜的阳极溶解的电化学反应;3%NaCl溶液中,BBT1对铜的阳极溶解和氧的阴极还原过程均有抑制作用,相比较而言对阴极过程的抑制作用更大一些。

Eleven novel 2-alkylthio-5-(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-5-yl)-1,3,4-oxadiazole derivatives (5) and six novel 2-alkylthio-5-(5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidine-5-yl)-1,3,4-thia- diazole derivatives (8) have been designed and synthesized by using 5-amino-3-ethoxycarbonyl-1H-1,2,4-triazole as a starting material.

以5-氨基-1H-1,2,4-三唑-3-羧酸乙酯为起始原料,设计合成了11个新型的2-取代硫醚-5-(5,7-二甲基-1,2,4-三唑并[1,5-a]嘧啶基)-1,3,4-恶二唑类化合物(5)和6个新型的2-取代硫醚-5-(5,7-二甲基-1,2,4-三唑并[1,5-a]嘧啶基)-1,3,4-噻二唑类化合物(8)。

Compound 102 was isomerized into 103 when treated with p-toluenesulfonic acid in dichloromethane.

化合物102利用对苯甲酸进行双键异构化,得到化合物103。

The characteristic of Circular dichroism on carbohydrates was introduced, and its application in structural analysis of carbohydrates was reviewed.

本文综述了糖类化合物的圆二色谱的特点以及CD在糖类化合物结构研究方面的应用状况。

Plating method test was used to examine its growth regulative activity on radishes of amphibrya and corns of dicotyledon.

将目标化合物用水配制成浓度分别为10ppm、50ppm和100ppm的溶液,采用平皿法测试目标化合物对单子叶植物玉米和双子叶植物萝卜的生长调节作用。

The concentration of the compound was prepared as 10, 50, 100 ppm using water. plating method test was used to examine its growth regulative activity on radishes of amphibrya and corns of dicotyledon.

将目标化合物用水配制成浓度分别为10 ppm、50 ppm和100 ppm的溶液,采用平皿法测试目标化合物对单子叶植物玉米和双子叶植物萝卜的生长调节作用。

The results show that there is excellent linear relationship between solute-related parameters and retention indexes for the saturated hydrocarbon, olefine and diene compounds on different polar chromatographic stationary phases.

结果表明:烷烃、烯烃、二烯烃类化合物在不同极性的色谱柱上的色谱保留与其分子结构描述参数之间具有较好的线性关系,烃类化合物在不同极性固定相上的保留主要与溶质分子的MR有关,即与溶质分子的色散力有关。

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