化合物

Generally the catalysts have high activity and good selectivity. At present the coupling reactions of organoborahes with terminal olefins s acid chlorides and aryl halides play an important synthetic approaches in organoborane chemical. The catalysts can be used by many kinds of organometal compounds such as: irons cobalt nickel ruthenium rhodium palladiums titaniums zirconiums tins indium and lithium organic compounds; The achievement has been amazed in preparing of unsaturated or saturated compounds and in synthesizing of natural products bioactive molecules and chiral compounds.

目前，卤代烃与不饱和烃的偶联反应和有机硼试剂与酰卤和卤代烃的偶联反应已成为有机合成的研究热点，此类反应可用铁、钴、镍、钌、铑、钛、锆、锡、铟、锂等多种有机金属化合物来催化，用于形成含饱和或不饱和C-C键的化合物，并已在天然产物、液晶、具有生理活性物质和手性化合物的合成中应用。

The recent progresses in these fields were summarized in this paper. It focuses on the activation and oxidation on a series of hydrocarbons (from CH4 to these hydrocarbons with six carbons). The catalysts and oxidants reported here include organic metal compounds and inorganic compounds (such as molecular sieves, metal clusters, metal oxidates and so on).

本文总结了近几年在碳氢化合物的活化及氧化领域的一些新进展，涉及的底物包括从甲烷到碳原子数等于6的烃类，而催化剂及氧化剂包括有机金属化合物和无机化合物（如分子筛催化剂、金属团簇和金属氧化物等）。

Forming mechanisms of the spin glass state and re-entrance phenomenon of B2 type FeAl compound were analyzed, and it was thought that different mechanisms existed in FeAl compounds with various ranges of compositions such as indirect exchange interaction, short-range ordering of partial atoms, and finite and infinite radical coexistence.

研究了不同成分的B2型FeAl化合物磁化强度与外场的关系、磁化强度与温度的关系、磁滞回线的特点，分析了B2型FeAl化合物自旋玻璃态、再进入现象的形成机制，认为FeAl化合物不同成分范围内应存在不同机制如间接交换作用、部分原子短程有序、有限、无限原子集团作用并存。

Goal: To obtains the compound quantum chemistry parameter using chemistry software computation, carries on the structure analysis to this kind of weed killer member, theoretically explained that this kind of compound biology characteristic and the structure relations, for this kind of compound's activeness, the toxicity predict that action mechanism's research provides the rationale.

目的：通过利用化学软件计算得到化合物的量子化学参数，对该类除草剂分子进行结构分析，从理论上解释该类化合物生物特性与结构的关系，为该类化合物的活性、毒性预测，作用机理的研究提供理论基础。

Monophenyltin trichloride reacts withdicarbonyl dicyclopentadienyl titanium immediately at room temperature, but no ti-tanium-tin complex produced, and the products were diphenyltin dichloride〓 and tin or stannous Chloride. When diaryltin dihalides were used, only the chlorides and bromides reacted with 〓form the complexes containing titaninm-tin bond,〓. but the corresponding iodide complex was not found. This reaction is Sensitive totemperature,when the temperature is belw 10℃,the reaction hardly takes place,but as the temperature is above 25℃,more 〓 will be found and the reactionbecome more complex.

Ph-SnC〓室温下即可与Cp〓迅速反应，但不生成含钛一锡链的化合物，而是生成Ph〓和Sn或Sn〓二芳基二卤化锡化物中，只有氯化物和溴化物才能和〓反应生成含钛〓锡键的化合物〓相应的碘化物则不行，而且反应对温度比较敏感，低于10℃，反应几乎不能进行，而高于25〓，则会生成更多的〓，在回流条件下得不到含钛〓锡键的化合物，只能得到分解产物，〓和Sn或〓。

Second,we set the database of morphological characteristics of intercepted and captured bark beetle during quarantine,and the last,we studied the molecular identification of 15 species.The results were showed as below.1.Application of bark beetle semiochemicals in timber quarantine1.1 EAG and walking responses of bark beetle to different semiochemicalsSemiochemicals which can induce the olfactory response and aggregation behavior of bark beetle include host volatile components,pheromones secreted by bark beetles itself or synthesized with host compounds by bark beetles,and the compounds released by tissue of decaying wood under the pressure of microorganism after bark beetle colonization.

信息化合物在小蠹虫检疫中的应用1.1小蠹虫对各种信息化合物的触角电位及嗅觉反应能诱发小蠹虫产生嗅觉反应，进而使之产生聚集行为的信息化合物有很多种，主要包括：树木的挥发性组分；小蠹虫自身产生的信息素和寄生后转化寄主化学物质合成的信息素统称虫体信息素以及树木被小蠹虫寄生后，其组织在微生物作用下释放的物质。

In this dissertation, a kind of MPc and five metallonaphthalocyanine were synthesized. The molecular structure of the compounds were characterized by means of the elemental analysis, the infrared spectrum and the nuclear magnetic resonance spectrum, which proved that the topical compounds were successfully synthesized.

本文设计并合成了五种叔丁基取代的金属萘酞菁化合物和一种金属酞菁化合物，通过元素分析、红外光谱分析、核磁共振氢谱分析等对目标产物进行了结构表征，验证了所合成化合物的结构。

The flame-retardant/smoke-suppressant of PVC may be divided into three kinds. The first is FRs , includes the compounds lying in IVB～VIB, such as TiO〓, V〓O〓, Cr〓O〓 and MoO〓; The second is FRs , includes the compounds lying in VⅡB～IB, such as MnO〓, Fe〓O〓, Co〓O〓, CuO and ZnO. The third is FRs , includes the compounds of subgroup A, for example Mg 〓, Al 〓, Sb〓O〓, carbonate and phosphate.

PVC的阻燃抑烟剂可分为三大类，第一类阻燃抑烟剂为元素周期表中IVB～VIB族的化合物，以TiO〓，V〓O〓，Cr〓O〓和MoO〓为代表，第二类阻燃抑烟剂为元素周期表中VⅡB～ⅡB族的化合物，以MnO〓，Fe〓O〓，Co〓O〓，CuO和ZnO为代表，第三类阻燃抑烟剂为三氧化二锑，氢氧化镁，氢氧化铝等主族元素的化合物。

Cocoa contains flavanols, plant-based compounds that also are credited with giving red wine its heart-healthy benefits.

可可含有黄烷醇化合物，以植物为主的化合物，这种化合物同样是红酒能给人们的心脏健康带来益处的原因。

During the study, an unreported Pd-catalyzed cross coupling substitution reaction was observed, and the relative theoretic discussion was made. The mesmorphic properties of all these compounds were observed and measured by polarizing optical microscopy and differential scanning calorimeters.

论文通过钯催化偶联反应合成了十一个系列74个全新的环己基炔类液晶化合物，利用元素分析、气相色谱、液相色谱等方法分析了化合物的纯度，利用红外光谱、核磁共振和质谱等分析手段对化合物的结构进行了鉴定。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。