化合物

This paper compared two kinds of rose families sorbus of different effective spots of total flavonids content. We get a better process of total flavonoids abstraction from the branch of Sorbus tianschanica,.Under the best process of total flavnoids ,two flavnoids were isolated from them. Preliminary affirmed two kinds of compounds belong to flavanone, two kinds of structure just substituent had a dissimilarity separately. This thesis was a part of a national natural science fund to subsidize.

除此，本论文还对新疆天山花楸的枝干总黄酮的提取工艺进行了研究，得到了最佳提取工艺，在最佳提取工艺的条件下对新疆天山花楸的枝干进行了系统的提取和硅胶柱层析，得到两种化合物，初步认定两种化合物属于二氢黄酮类，两种化合物的结构相似，只是个别取代基有所不同，本论文是国家自然科学基金资助项目。

It demonstrated that the molecular size matching and the sterically arrangement of groups of studied compounds with nucleoside phosphates are very important for the interaction of them. And the quenching ability depends on the interaction of these species strongly. Evidently, this phenomenon can be used as a method for the molecular recognition of nucleoside phosphate by the changing of fluorescence intensity of these compounds.

实验结果表明，分子尺寸的匹配和化合物中基团的空间合理排布是化合物和核苷磷酸盐间能发生相互作用的重要根据，而猝灭则强烈地依赖于这类物种间的相互作用，因此可利用化合物荧光强度的改变来识别各种不同的核苷磷酸盐。

This could be a fascinating method for the practical syntheses of chiral synthons as valuable building blocks and important medicinal intermediates.3.Series of novel optical pureγ-aryl-1H-1,2,4-triazole derivatives were designed and synthesized by using the chiral auxiliary(Oppolzer\'s sultam),and all these target compounds were structurally characterized by ~1H NMR,~(13)C NMR,MS and elemental analysis,at the same time,some representative compounds have been elucidated by X-ray diffraction analysis.

应用手性辅剂樟脑磺内酰胺的手性诱导作用，设计合成了一系列光学纯的γ-芳基-1H-1，2，4-三唑类衍生物，所有目标化合物都采用了~1H NMR、~(13)C NMR、MS和元素分析进行了结构表征，同时也获得了部分代表性化合物的晶体结构，进一步确证了化合物的结构。

Tagal collected in the mangrove forest in Hainan Island.Twenty-three compounds were isolated from the petroleum ether portion of the 95% ethanolic extract of the C. tagal.

从角果木的95%乙醇提取物石油醚萃取液中分离得到23个化合物，通过理化常数，1D NMR、2D NMR、IR、MS方法鉴定了19个化合物的结构，其中新化合物11个。

But the electrochemical results show that complexes exhibitcompletely irreversible redox behaviour which is different from thatfound in diiron proteins. 1.3 To obtain the diiron species which are stable to elec-trochemical reduction, a series of new tetranuclear cage ironspecies containing two 〓 cores, with using hexadentatepolybenzimidazole ligands, were synthesized and characterized by vari-ous spectroscopic methods. Their physical properties have been investi-gated. The crystal structures of 〓〓tetrakis (benzimidazol-2-ylmethyl)-1, 4-diaminobutane and 〓,〓-tetrakis ( N-ethylbenzimidazol-2-ylmethyl )-1, 4-diaminobutane were determined. They contain two 〓 cores which arelinked to each other by -〓-chain in the ligands.

1.3为了获得电化学还原稳定双核氧桥联Fe化合物，使用六齿配体合成了一系列含有两个〓单元四核笼状化合物，并用各种谱学手段表征了它们，还研究了它们的物理化学性质确定了〓L=N，N，N'，N'-四(苯骈咪唑基-1，4-丁二胺和〓，〓四-1，4-丁二胺化合物的晶体结构，它们含有两个〓单元，其中两个〓单元是通过配体的〓链桥联成四核笼状结构。

The preliminary bioassay showed that all compounds had certain fungicidal and insecticidal activities. The inhibition rates of compounds 5f and 5h were above 95% against Colle-totrichum gossypii at 100 mg/L, and the mortality rates of compounds 5g and 7d were above 85% against Tetranychus urticae at 250 mg/L.

初步生物活性测定结果表明，在试验浓度下，目标化合物均具有一定的杀虫和抑菌活性，其中化合物5f和5h在100 mg/L浓度下对炭疽病菌的抑制率达95%；化合物5g和7d在250 mg/L浓度下对棉红蜘蛛的致死率达85%。

The ligand of HL3 differs from HL1 and HL2 in having an ethyl group not methyl group on the triazole ring and having a thienyl group on the substituted amino group, meanwhile there are two kinds of 3 molecules in the crystal structure.

在化合物3中配体与化合物1和化合物2的不同，同时其一个结构单元中还存在两个结构几乎相同的分子，这两个分子只在键长、键角上有轻微差别。

It was found that the titled amine in which although dimethyl aniline and triethyl amine both were contained, possesses less efficiency of photoinitiation while it was composed with ketone as an initiated system.

苯基派嗦类化合物是一类特殊的胺类化物，如苯基乙基呱嗦就可看作为一种三级芳胺和另一种三级脂胺组合而成的化合物，然而对这类化合物和酮组合构成的光引发体系的研究，过去报道较少。

In chapter 4, we have described an improved method for the preparation of ethynylferrocene. Ethynylferrocene was prepared in satisfactory yield by reaction of formylferrocene with triphenylphosphine and carbon tetrachloride followed by dehydrohalogenation in the presence of n-BuLi.

第三章中，我们研究了钯催化下碘杂环化合物的羰基化—酰胺化反应、羰基化—酯化反应和与末端炔烃的羰基化交叉偶联反应，为一步合成多官能团化合物开辟了新的途径，同时，得到的这些产物经过进一步官能团转化后，可以成为一些天然产物合成中的重要中间体化合物。

Methods 2-(piperazin-1-yl)-1-(pyrrolidin-1-yl)ethanone (2) was synthesized from pyrrolidine via amidation and substitution, followed by treating with chloroacetyl chloride and triphenylphosphine in a "one pot" manner to give the corresponding phosphonium chloride 3 in a stable and pure form after crystallization from isopropanol.

以四氢吡咯为原料，先与氯乙酰氯成酰胺，再与哌嗪发生取代反应制得中间体［（1-四氢吡咯基）甲基］哌嗪(2)；化合物2与氯乙酰氯和三苯基膦反应，经异丙醇重结晶得到稳定的有机鏻盐(3)；化合物3与3，4，5-三甲氧基苯甲醛发生Wittig反应，再与马来酸成盐得目标化合物马来酸桂哌齐特(1)。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。