化合物

We investigated constituent of triterpenoid saponins ofAlbizzia, two new compounds together with two known compounds were isolated from Albizzia julibrissin Durazz. by using column chromatography (macroreticular resin, silica gel, Sephadex gel, reverse phase silica gel),preparative HPLC methods et al.On the basis of spectroscopic analysis, including IR,ESI-MS,~1H-NMR,~(13)C-NMR,HMBC,HMQC,~1H-~1HCOSY and chemical methods, the structure of two new compounds were identified as 3 - O -[β-D-xylopyranosyl(1→2)-β-D-fucopyranosyl (1→6)-β- D -2- deoxy - 2 - acetoamidoglucopyranosyl] -21-O-[(6S)-2- trans- 2,6-dimethyl - 6 - O-β- D - quinovopyranosyl -2,7- octadienoyl] - acacic acid- 28 - O-β-D-glucopyranosyl(1→3)[α-L-arabinofuranosyl(1→4)]-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside acacic acid 3- O -β- D- glucopyranosy(1→3)-β- D- fucopyranosl(1→6) [β-D- xylopyranosyl (1→2)]-β-D-glucopyranoside ;two known compounds were acacic acid lactone 3- O -β-D- xylopyranosyl-(1→2)-β-D-fucopyranosl (1→6)- 2-deoxy -2 -acetoamido -β-D- glucopyranoside ; acacic acid lactone 3- O-β-D-xylopyranosyl(1→2)-α-L- arabinopyranosl (1→6)- 2- deoxy - 2- acetoamido -β-D-glucopyranoside . The study lays chemical foundation and chemical reference substance for enhancing quality standard of Albizzia julibrissin Durazz.

本研究论文在综述国内外对合欢属Albizzia三萜皂苷化学成分和药理作用研究进展的基础上，利用传统植化分离手段和现代分离技术，包括大孔树脂、硅胶、葡聚糖凝胶、反相硅胶等柱色谱，制备高效液相色谱法等技术从中药合欢皮中分离得到了4个化合物，其中，2个新化合物和2个己知化合物，并进一步通过现代分析技术IR，ESI-MS，~1H-NMR，~(13C-NMR，HMBC，HMQC，~1H-~1HCOSY等和化学方法鉴定了2个新化合物的结构分别是：3-O-[β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖基]-21-O-[(6S)-2-反式-2，6-二甲基-6-O-β-D-吡喃鸡纳糖基-2，7-辛二烯酸基]-金合欢酸-28-O-α-L-呋喃阿拉伯糖基(1→4)[β-D-吡喃葡萄糖基(1→3)]-α-L-吡喃鼠李糖基(1→2)-β-D-吡喃葡萄糖苷，金合欢酸3-O-β-D-吡喃葡萄糖基(1→3)-β-D-吡喃夫糖基(1→6)[β-D-吡喃木糖基(1→2)]-β-D-吡喃葡萄糖苷；2个已知化合物结构分别是：金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷，金和欢酸内酯3-O-β-D-吡喃木糖基(1→2)-α-L-吡喃阿拉伯糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷。

The filled skutterudite compound possesses bcc structure as evidenced by electron diffraction analysis. Powder X-ray diffraction data of filled skutterudite samples were characterized by Rietveld method for some crystallographic parameters such as lattice constant, atomic occupation, atomic position, etc.

另外，通过对化合物电子衍射的分析证实了〓化合物是一种具有bcc结构的化合物；运用Rietveld方法对填充skutterudite化合物X衍射谱线进行了分析，对化合物的晶格常数、原子位置的占有率以及原子位置坐标等晶体学参数进行了表征。

The new structure compounds (4, 54, 56) possessing vasodilatation were found. These compounds may be as lead compounds of developing antihypertension drugs. The synthesis method of peptidemimetics containing β-tetrahydro -carbolic acid was established for the first time.

在对上述化合物NO清除能力评价实验中，发现了一类具有舒血管活性新化合物（化合物4，54，56），这一类具有舒血管活性化合物的发现可以为研制高血压治疗药物提供先导化合物。

Furthermore, the antifungal effect of the two-part heartwoods nearby sapwood was better than that of the heartwood nearby the pith. 14 kinds of chemical components were identified from the heartwood extractives by GC/MS, most of which are terpenoids and their derivatives, and the content of thujopsene is the highest (25.564%), cedrol (19.743%) is second only to that of thujopsene, 24 kinds of chemical components were identified from the dichloromethane extractives, and the highest component is also thujopsene (15.429%).

气质联机技术对正己烷和二氯甲烷提取物分析鉴定表明：侧柏心材正己烷提取物中有14种化合物，大部分化合物属于萜烯类物质及其衍生物，最高含量化合物为罗汉柏烯(25.564%)和雪松醇(19.743%)；侧柏心材二氯甲烷提取物中鉴定出24种化合物，最高含量化合物也为罗汉柏烯(15.429%)。

In this paper we reported the results of 4 antimony cyclic-mercaptides and 2 corresponding tincompounds and 1 organomercury compounds,3 stibonic acids and related compounds,4 bis(p-aminophenoxy)- thiaalkanes,4 EDTA-chelates of antimony,tin,mercury and bismuth,"TWSb", hexachloroethane,tetrachloroethylene and some other antimony,tin and mercury compounds.

本文报告32种有机化合物对于日本血吸虫病的动物实验治疗的结果，包括：二硫锑环状化合物4种及其相应的 Sn 化合物2种及 Hg 化合物1种、酸类3种、双硫间烷类化合物4种、EDTA 与 Sb，Sn，Hg 及 Bi4种螯合盐、"TWSb"、CCl_3—CCl_3、CCl_2=CCl_2以及一些其他 Sb，Sn 及 Hg 的衍生物。

The contents of mineral elements, like Fe, in LMTCMs were higher than that of nor-LMTCM. The result of analysis of mineral element of 14 LMTCMs by ICP-MS method also showed the content of Fe have something to do with lung meridian tropism effects. The result of the study of platycodon radix approved the laws too. These laws were used to predict if the marine medicines have the lung meridian tropism effects.2. The Compatibility laws of Medicines and their chemical composition in LSP were studied by mining the data of the constituent herbs and their chemical composition. The results showed that the most constituent medicines of lung system prescriptions have lung meridian tropism. Radix glycyrrhizae, herba ephedrae, semen armeniacae amarum, fructus schisandrae Chinese and their compatibility are common in lung system prescriptions. Terpene, alkaloid, steroid, and flavanoid compounds and their compatibility are common in lung system prescriptions.3. The marine phycophyta medicines of LSP were studied by the same method.

对比归肺经中药及肺系方剂主要化学成分构成，萜类、生物碱、甾体类成分可能是归肺经中药及肺系方剂的主要药效成分；结合君臣佐使药的化学成分构成特点及肺系方剂组成中药的归经构成情况，肺系方剂组方设计应该考虑以下几个方面：一、优先考虑归肺经中药，在应用不归肺经中药时要配伍归肺经中药；二、组方时应考虑含萜类、甾体及生物碱类化合物的中药；治疗肺咳病及咳嗽症状时可以考虑含萜类化合物的中药，治疗气喘症状时可以考虑含生物碱类化合物的中药；三、在确定组方中药或化学成分配伍关系时，君药多考虑含生物碱、黄酮类化合物的中药；臣药、佐药可以考虑含萜类及甾体类化合物中药；使药可以考虑含萜类、甾体类及黄酮类化合物的中药。

The catalytic activity of the mono- and bi-nuclear complexes, and unsymetric complex 〓〓 MeNTB =tris ( N-methylbenzimidazol-2-ylmethyl amine and tetranuclear complex 〓L = N, N, N', N'-tetrakis (N-methylbenzimidazol-2-ylmethyl-1,4-diaminobutane for oxidation of hexane was examined. Thedi-iron complexes with one exchangeable monodentate ligand and unsym-metric(μ-carboxylato) diiron complex exhibit high catalytic ac-tivity, while mononuclear Fe complex are inactive.

这些单核、双核化合物、不对称化合物〓-三氨和四核化合物〓四-1，4-丁二胺催化氧化环己烷的催化活性被测试，结果表明含有可交换配体氧桥联双核Fe化合物和不对称双核Fe化合物表现很高的催化活性，而单核的Fe化合物是非催化活性的。

The compositions of complexes were determined as, by chemical and elemental analyses, Mn2CI2, Mn2Cl2, Cu2Cl2-2H2O, Cu(NO3)2-H2O, Cu(CH3COO)2, Zn2Cl2, Zn2(NO3)2-4H2O,ZnSO4 and Zn4(NO3)2, respectively. These complexes were characterized by IR,'H NMR and XPS. The crystal structures of these complexes were determined by single crystal X-ray diffraction techniques. The thermstability of the complexes was investigated by TG-DTG and the processes of their thermal decomposition were speculated. The constant-volume combustion energies of complexes, cU, were determined by a precision rotating bomb calorimeter at 298.15 K. Their standard enthalpies of formation, Hm, were calculated respectively. Finally, their biological activity was researched after the bactericidal activity was determined by selection of 1-2 bacteria.

通过化学分析、元素分析确定化合物分子组成分别为Mn_2Cl_2，Mn_2Cl_2，Cu_2Cl_2·2H_2O，Cu(NO_3)_2·H_2O，Cu(CH_3COO)_2，Zn_2Cl_2，Zn_2(NO_3)_2·4H_2O，ZnSO_4和Zn_4(NO_3)_2；借助IR、~1H NMR和XPS对化合物的键型特征进行了表征，运用X-射线单晶衍射分析法测定了个别化合物的晶体结构；以TG-DTG技术研究了化合物的热稳定性，阐明了它们的热分解机理；用精密转动弹热量计测定了化合物在298.15 K的恒容燃烧能，并计算了它们的标准燃烧焓和标准生成焓；选取1～2种病菌，初步测定了化合物的杀菌活性，进而研究了它们的生物活性。

Phytochemical investigation on the acetone extract of the stems of K.oblongifolia led to the isolation of 49 compounds and 31 of them were identified.They were 20 lignans,(including 11 dibenzocyclooctadienes,8 spirobenzofuranoid dibenzocycloocta -dienes,1 other lignan),9 flavones,and 1 nortriterpenoid.Among them,4 were new compounds,1 was new natural products,and 8 compounds were isolated from this family for the first time.

通过对冷饭藤的藤茎化学成分的研究，从丙酮提取物中分离得到49个化合物，鉴定了31个化合物，包括木脂素类化合物20个(联苯环辛烯类木脂素11个，螺苯骈联苯环辛烯类木脂素8个，其他类型木脂素1个)，黄酮类化合物9个，降三萜类化合物1个，其中。4个为新化合物，1个新的天然产物，8个为本科首次报道。

Compounds 1, 14, 20-24 were isolated from the roots and rhizomes of N.

化合物1，14，20～24为首次从裂叶羌活根和根茎中分离得到；化合物1为倍半萜类化合物，化合物14为6，7-呋喃型香豆素，化合物20～24为苯丙素类化合物。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。