化合物

In the paper, the research evolvement of electrocarboxylation from carbon dioxide with olefin, alkyne, and ketones in near decades was summarized, these reactions were convenient ways to synthesize some valuable pharmaceutical precursor and intermediates in organic synthesis.

文章综述了近几十年来二氧化碳与烯烃化合物、炔烃化合物以及酮类化合物的电羰基化反应的研究进展，这些反应是合成一些有价值的药物前驱体或是有机合成中间体的简便方法。

To avoid the influence of ammonolysis, alcoholysis and hydrolysis on molecular structure identification, in this paper, derivational estimation is utilized to confirm molecular structures ofβ-naphthol-containing sulfonyl chloride intermediates. Then the structures of corresponding sulfonamide dyes are also confirmed by FTIR,~1H NMR and mass spectrometry.

为了避免磺酰氯化合物发生水解、醇解和胺解等衍生化反应影响磺酰氯化合物分子结构表征，本文采用衍生化反推法证明了β-萘酚结构磺酰氯化合物的分子结构，并利用红外光谱、核磁共振氢谱、质谱表征了含β-萘酚结构磺酰胺染料的分子结构。

The annulation of stilbene compounds were studied. Phenanthrene derivates-interme diates of tylophorine were synthesized by annulation from-2,3-bis(3,4-dimethoxyphen yl)acrylic acid and-2,3-bis(3,4-dimethoxyphenyl) acrylonitrile with phenyliodine diace tate as a friendly and high efficient catalyzer.The route was first reported, whose application foreground would be promising.The catalyzer will be used to study of synthesi- zing a series of new phenanthrenes.

本文还探索了简单类化合物关环反应，并研究出用廉价高效对环境友好的催化剂-二乙酸碘苯成功地将类化合物－3，4-二甲氧基-α-(3，4-二甲氧苯基)-肉桂酸和-2-(3，4-二甲氧苯基)-3-(3，4-二甲氧苯基)-丙烯关环形成相应的菲环衍生物－娃儿藤碱重要中间体，此方法在国内尚属首次，具有重要的应用价值，此外可用此催化剂研究一系列类化合物的关环反应。

They are all anticancer active constituents. The last one is a new compound.

这三个化合物都有较强的抗癌活性，其中化合物3为新化合物。

The discovery of superconductivity with a critical temperature higher than 40 K in the iron arsenide LnFeAs has drawn much interest in condensed matter physics.

最近，由于在铁基LnFeAs化合物及其相关化合物中发现具有高于40K的超导电性，层状的铁基化合物引起了凝聚态物理学界很大的兴趣和关注。在随后的研究中发现，在该类材料中最高超导临界温度可达到55K。

Since the atomic radius of cerium or yttrium is at the border between the Th〓Ni〓-type and the rhombohedral Th〓Zn〓type structure, the influence of different annealing temperatures on the crystal structure of Ce〓Co〓 and Y〓Co〓 compound was clarified.

测量并获得了这些化合物的晶体结构类型、点阵常数、晶胞体积、居里温度、在5K和300K时化合物的饱和磁化强度和每个Co原子的平均磁矩、各向异性场、各向异性常数、自旋重取向温度以及补偿温度等，并获得了相应化合物的磁相图。

Summarizing the results from this analysis, it was revealed that the analytic contained abundant components of neolignans , having dimeric phenyl propanoid structure with unsymmetrically condensed benzofuran skeleton attached with different sugar moieties.

结果显示此部分为富含木质素类化合物，所分析出的化合物多为首次在该植物发现，其中有massonianoside D(1)、7、8和C-veratroylglycol (9)为已知化合物，而2~6、10~14是新颖天然物成分。

Benzene nitriles studied included parent benzene nitriles(cinnamonitrile,benzo nitrile,benzeneacetonitrile,isopropyl benzeneacetonitrile) and para-chloro ben zene nitriles(para-chloro cinnamonitrile,para-chloro benzonitrile,para-chloro be nzeneacetonitrile,para-chloroisopropyl benzeneacetonitrile).

所研究的苯腈类化合物包括苯腈类母体化合物(苯丙烯腈、苯甲腈、苯乙腈、异丙基苯乙腈)和对氯苯腈类化合物(对氯苯丙烯腈、对氯苯甲腈、对氯苯乙腈、对氯异丙基苯乙腈)。

The works in the project just done can be summarized as five respects.(1) A device was designed to fabricate the asymmetrical resonant cavities by a pendant drop. A series ARCs with variable parameters provides a valuable experimental method for investigating the characteristics of ARCs.(2) The relationship between the number of active modes and the shape parameters in an ARC was investigated. The experimental lasing threshold was compared with theoretical result, the good agreement between two shown that it was the decrease of the number of active modes in an ARC that decreased lasing threshold.(3) Dye lasing gain was used to enhance the signals of stimulated Raman scattering of the weak gain Raman modes in a circular cavity made by a pendant drop, the instantaneous SRS spectra of weak gain Raman modes in ethanol was obtained by this new method.(4) The SRS signals of minority compound in a binary chemical complex was obtained by using dye lasing gain method. The detection concentration of minority compound was reduced to an order compared with normal SRS method.(5) A cylindrical circular cavity was formed by a liquid jet, which was used to reduce the pump intensity required for laser induced plasma spectroscopy. The limit of detection of trace element in aqueous sample was greatly decreased by this new method.

我们设计并成功制作了使悬垂液滴连续变形的装置，用此装置可以方便地改变非圆对称谐振腔的几何参数，为ARCs的研究提供了一种有效的实验方法；研究了ARCs中活性模式数和变形参数间的变化规律，激光阈值的数值计算结果和激光辐射的实验结果作了比较，二者吻合的曲线说明ARCs中活性模式数量的减少是受激辐射放大阈值降低的原因；在由单元化合物构成的微型圆对称谐振腔中，首次尝试用"激光增益"增强弱增益拉曼模式的受激拉曼散射信号，获得了乙醇分子中弱增益拉曼模式的瞬态SRS光谱；在由二元混合物构成的微型圆对称谐振腔中，用染料的激光增益增强了少量化合物的SRS信号，把少量化合物的SRS信号探测浓度降低了近一个数量级，在SRS应用于瞬态过程的组份分析方面做了卓有成效的探索；用石英毛细管形成的稳定液拄构成拄形谐振腔，降低了激光诱导等离子体光谱需要的激励能量，有效地降低了水相样品的痕量元素分析极限，为LIPS应用于微量元素的化学分析开拓了一条新的技术路线。

This paper reviews advances in organotin complexes with their antitumor activity in recent years,especially two kinds of new organotin,ionic organotin compound and organotin carboxylate compound,and we also look forward their future development.

介绍了近年来国内外有机锡化合物在抗癌活性方面的研究进展，尤其是离子型有机锡化合物和含有N原子的有机锡羧酸酯类化合物，并对其发展前景进行了展望

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。