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Research on thermodynamics and kinetics of pyrolysis reaction mechanism Kinetic and thermodynaimic research of the pyrolysis reaction mechanism of toluene was conducted at different temperature range 298-1223K. The result shows that the pyrolysis reaction firstly occurs at the methyl on the benzene ring, and produces benzyl.

裂解机理的热力学与动力学研究在298K-1223K的温度范围内对甲苯热解机理的热力学和动力学研究结果表明,热解首先发生在苯环甲基C-H键上并生成卞基自由基,主要产物为联二甲苯,反应的活化能ΔE〓=402.27kJ/mol。

Topics discussed include ultrafast spectroscopic techniques; aspects of electron transfer reactions ranging from solvent effects; intermolecular and intramolecular systems, to dynamics at semiconductor surfaces; the dynamics of chemical systems using Raman spectroscopy; pericyclic photochemical rearrangements and photodissociation reactions; solvent--solute interaction dynamics; and chemical dynamics in clusters.

讨论的议题包括超快光谱技术,电子转移反应的溶剂效应等方面;分子间和分子系统,动力在半导体表面,使用的化学拉曼光谱系统动力学;周环重排和光化学解离反应;溶剂-溶质相互作用的动态以及在化学动力学组。

In order to improve the dynamic quality of the whole system, the dynamic balance precision of the high speed rotor should be improved. Dynamic behavior of geared rotor system was analyzed using modal synthesis method

应用模态综合法分析齿轮传动转子系统的动力学特性,结果表明模态综合法能有效地降低系统的自由度,提高计算速度,对于复杂的多转子-轴承系统的动力学研究具有广泛的应用前景。

Using the Second Lagrangian kinetics,the dynamic features of the robot are analysed,the generated driving torque of the arms is derived,and its dynamical models are set up.The sliding-mode fuzzy control is adopted by of the MJR120 palletizer,and the numerical simulation shows that the control method is efficient.

本文经过对该机器人进行的详细动力学分析,确定了系统的广义驱动力,运用第二类拉格朗日方程建立了系统的动力学模型;对MJR120 码垛机器人在控制上采用了滑模模糊控制技术,通过仿真实验表明了该控制方法对MJR120码垛机器人进行控制的有效性。

Based on Wavelet Packet Analysis and Smoothed Pseudo Wigner-Ville Distribution, the experiment data is time-frequency analyzed. The experimental results indicate that the amplitude of the laser-induced acoustic waves increases with the laser energy; the frequency coverage is from 0 to 150 KHz, and in the meantime there is a peak located at about 25 KHz. In addition, the spectrum and the peak of frequency are basically stable in spite of the change of laser energy and target texture.

从基本的空泡动力学理论出发,推导了空泡各特征参量之间的关系,进而对空泡动力学模型进行了修正;采用有限差分法对空泡脉动进行数值模拟,得到了空泡脉动特性随液体粘性、空泡含气量、表面张力以及可压缩性的变化规律;实验上采用光偏转测试装置探测了激光空泡脉动以及空泡溃灭的细节过程,进而分析了液体粘性和作用激光能量对空泡脉动周期、泡半径及泡能等特征参数的影响。

The result will provide afundamental basis for industrial design.Firstly,based on the assumptions that the reaction generating mono-ester was controlled by the solution rate of pentaerythritol,that di-ester conversed to tri-ester rapidly and that all the reverse reactions and side reactions were omitted,the equations of reaction kinetics were obtained.

具体工作如下:(1)基于生成一酯的反应受季戊四醇溶解速率控制、二酯迅速转化为三酯和忽略所有逆反应及其它副反应的假设基础上,建立了酯交换反应的反应动力学方程,获得了不同温度下的动力学常数和速率常数的指前因子及活化能。

We proposed the time-changed dynamic models of radar signals based on dynamic theory, and can analyze quality and quantity of the deinterleaving pulse train;(2) We proposed the algorithm to computer selfsimilarity exponent and detect successfully the object echo buried in noise according to self-similarity of noise and nonsimilarity of sine wave;(3) We also proposed a nonlinear dynamic filtering detection model.

1根据动力学理论,提出了雷达信号的时变动力学模型,利用这个模型可以对已经分选出来的雷达信号进行定性和定量分析;(2)提出了快速计算自相似性指数的算法,并利用噪声和正弦波分别具有自相似性和不具有自相似性的特点,成功地检测到淹没在噪声中的目标回波;(3)提出了一种非线性动力学滤波检测模型。

It provides not only fundamental principle and analysis of Modern Applied Mechanics and Dynamics but also applications in research areas such as stability, rigid body and rigid-body systems, movements of celestial body and spacecraft, vibration, nonlinear dynamics, et al.

它的研究一方面提供了现代应用力学以及动力学一般理论最基本的原理和方法,另一方面,它本身也给出了在稳定性、刚体与刚体系、天体与宇航器的运动、振动、非线性动力学等领域中一系列有实用价值的成果。

The results show that the reactive characters of macro-kinetics are different from that of intrinsic kinetics under the same experimental conditions. The isobutene dimeric reaction follows 1.5 order reaction because of the effect of inner diffusion, and isooctane dimeric reaction follows zero order reaction.

结果表明,在相同的实验条件下,反应的宏观动力学行为与本征动力学行为有较大的不同,异丁烯的反应级数受内扩散影响由2级变为1.5级,异辛烯的反应级数则为0级。

The structure of the first generation of low floor tramcars in China is introduced with the comparison made on the similarities and differences between independent wheels and conventional wheelsets.

介绍国内第 1列低地板有轨电车的结构,比较了独立车轮与传统轮对的异同,对独立车轮转向架试运行情况进行了分析,通过试验证明其走行部具有较好的稳定性、平稳性和曲线通过等动力学性能,最后结合走行部的关键结构分析了该车的动力学特点及仿真结果。

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随着死亡的吉他手Schuldiner接受主唱的职务,乐队在现实中树立了重要的影响。

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不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐,因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。

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关闭眼睛,深呼吸,一切不再是梦想,犹如。。。。。。