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动力学

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Some new results are obtained from the studies: 1 a novel thermokinetic research method, the characteristic reduced parameter method, has been proposed, and the kinetics of oxidation of benzoquinone by hydrogen peroxide has also been investigated with this method; 2 the kinetic mathematical models that the metallomicelles made from the mono-nuclear or dinuclear complexes and surfactants catalyze the phenolic derivant oxidation have been established respectively; 3 the feasibility and mechanism that the metallomicelle, a mimetic model of peroxidase, catalyzes the phenolic derivant oxidation has been discussed.

研究得到如下新的结果:(1)提出了一种新的热动力学研究法——特征对比参量法,用该法研究了过氧化氢氧化苯醌反应动力学;(2)分别建立了由单核和双核金属配合物与表面活性剂形成的金属胶束催化酚类氧化反应的动力学数学模型;(3)探讨了金属胶束模拟过氧化物酶催化酚类氧化反应的可行性及其机理。

Synthesis of cyclohexyl acetate with rare earth composite solid superacid catalyst of SO2-4/TiO2/Ce4+was investigated.

研究了以稀土复合固体超强酸SO42-/TiO2/Ce4+为催化剂合成乙酸环己酯的反应,在反应温度分别为100℃、110℃、120℃下,测出酯化反应的动力学参数,建立了动力学方程,并与无催化剂作用下合成乙酸环己酯反应的活化能及动力学方程进行了比较。

This paper is about the hydrodynamics of blood in flow channel on the principle of hydrodynamics, and the hydrodynamics equations of Newton-fluid and Casson-fluid in rectangle channel. It also includes the studies of the diphasic flow. The fluid model selection is discussed from the examples in the hemorheology studies using flow channel technique.

本文用流体动力学原理,研究了流动渠道中的血流动力学问题,分别推导了牛顿流体、Casson流体在矩形渠道中的流体动力学方程,文中还对流动渠道内的二相流问题进行研究,并就血液流变学研究中利用流动渠道技术的应用实例,讨论了流体模型选择问题

The formation of charge transfer complex was studied in the first part. The second part includes the synthesis and characterization of the acrylated unsaturated polyester and the kinetic studies on the Ar-UPE/ triethylene divinyl ether (DVE-3) photocuring system, the rheology and properties of film after photocuring. The third part includes the synthesis and characterization of the urethane modified unsaturated polyester and the kinetic studies on the PU-UPE/DVE-3 photocuring system, the rheology and properties of film after photocuring. The fourth part includes the synthesis and characterization of the vinyl ether end capped polyurethane and the kinetic studies on the VE-PU/DVE3 photocuring system, the rheology and properties of film after photocuring.

整个研究工作分为四个部分:一是电荷转移复合物的研究;二是丙烯酰氧基化不饱和聚酯的合成,表征,Ar-UPE/二缩乙二醇二乙烯基醚(DVE-3)体系光固化动力学研究以及Ar-UPE/DVE-3体系流变性能和光固化后涂膜综合性能的研究;三是氨酯改性的不饱和聚酯的合成,表征,PU-UPE/DVE-3体系光固化动力学研究以及该体系光固化后涂膜综合性能的研究;四是乙烯基醚封端的聚氨酯的合成,表征,VE-PU/马来酸二甲酯体系光固化动力学研究以及VE-PU/DMA体系流变性能和光固化后涂膜综合性能的研究。

The efficiency of an closed epicyclic gear train is analyzed by means of this formula, some of efficient curves are drawn, and an adequate selecting range of transmission ratio is found.

推导出了动力学模型中惯性元件、弹性元件和分支节点的动力学分析的数学模型,用传递矩阵法建立起封闭周转轮系动力学分析的数学模型。

In this project, we have deduced the joint inversion model of geodetic data, seismic data and geological data considering about their weight ratio; presented Bayes-iterative search inversion algorithm which improved on the traditional Bayes algorithm and strengthen the stability of inversion solutions; enriched and developed geodetic joint inversion theory and method of tectonic stress field; joint with geodetic, seismic, geological and geophysical data, we have inverted the temporal and spatial variation characteristics of crustal deformation of active tectonic blocks in North China and the present-day cruatal movement and strain-stress field by FEM, DDA and bi-cubic spline function fit method; especial for the crustal deformation result in some typical areas, we have presented geodynamical interpretation and done some seismic dangerous estimations.

大地测量联合反演构造应力场属于大地测量与地球动力学和地震学的交叉研究领域,主要内容是研究用大地测量地壳运动监测数据定量研究地壳运动和变形的动力学问题及分析预测地震,本项目推导了兼顾权比确定的大地测量、地震和地质三类数据的联合反演模型;提出贝叶斯-轮回搜索反演算法,改进传统的贝叶斯方法,改善反演解的稳定性;丰富、发展了大地测量反演构造应力场理论及方法;联合大地测量、地震、地质、地球物理数据采用有限单元法、块体不连续变形分析法和双三次样条函数拟合方法反演分析了华北地区活动地块运动时空变化特征以及中国大陆现今地壳运动与应变-应力场,对典型地区地表形变结果进行地球动力学解释并进行地震危险性估计。

With ADAMS,a kind of dynamics analysis software,a dynamics model of vehicle with leaf spring and another with hydropneumatic spring were set up.

利用动力学分析软件ADAMS,建立了钢板弹簧车辆和油气弹簧车辆的动力学模型,开展了整车在随机路面上的平顺性仿真,分析了两种悬架对车辆平顺性的影响,并通过仿真数据与试验数据的对比,验证了动力学模型的正确性

The principle of molecular dynamics, the progress in related finite difference technique and interatomic potentiak, the choice of initial and boundary conditions, the realization and control of equilibrium ensembles, the extraction of useful information, and the special use of molecular dynamics and its combination with other computational methods are summarized.

综述了分子动力学模拟技术的发展,介绍了分子动力学的基本原理、有关的有限差分技术、势函数的发展、初始条件和边界条件的选取、平衡态系综及其调控、感兴趣量的提取、分子动力学的特别用途以及与其他计算方法的结合。

The synthesis of isoamyl acetate with the solid super acidic catalyst of S2O827TiO2-Al203 is investigated. The kinetic parameters of reaction are measured at 94℃, 100℃ and 106℃ respectively and the kinetic equation is thus built, which are compared with those of the reaction without catalyst.

文章研究了以固体超强酸S2O82-/TiO2-Al2O3为催化剂合成乙酸异戊酯的反应,在反应温度分别为94℃、100℃及106℃下,测出合成乙酸异戊酯的动力学方程参数,建立了动力学方程式,并与无催化剂时酯化反应的活化能及动力学方程式进行了比较。

The synthesis of isoamyl acetate with the solid super acidic catalyst of S2O82-/TiO2-Al2O3 is investigated.The kinetic parameters of reaction are measured at 94℃,100℃ and 106℃ respectively and the kinetic equation is thus built,which are compared with those of the reaction without catalyst.

文章研究了以固体超强酸S2O82-/TiO2-Al2O3为催化剂合成乙酸异戊酯的反应,在反应温度分别为94℃﹑100℃及106℃下,测出合成乙酸异戊酯的动力学方程参数,建立了动力学方程式,并与无催化剂时酯化反应的活化能及动力学方程式进行了比较。

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The concept of equivalent rotationally rigidity is offered and the formula of rotationally rigidity is obtained.

主要做了如下几个方面的工作:对伸臂位于顶部的单层框架—筒体模型进行分析,提出了等效转动约束的概念和转动约束刚度的表达式。

Male cats normally do not need aftercare with the exception of the night after the anesthetic.

男猫通常不需要善后除了晚上的麻醉。

Its advantage is that it can be used in smaller units.

其优点在于可以在较小的单位中应用。