加成产物

Dependent on the palladium role of hydrogenation and hydrogen spillover, the olefins effused from the zeolite capsule catalyst were hydrogenated effectively, mostly converted to isoparaffin.

得益于钯的催化加氢和氢溢流的功能，在基于该三分结构的费托合成反应中，烯烃产物被有效的催化加氢为烷烃，且大部分被转化成了异构烷烃。

The process includes the following steps: dissolving bromine in halogenated hydrocarbon, dropping the bromine solution into reactant system comprising pentabromo toluene, halogenated hydrocarbon, free radical initiator and hydrogen peroxide at 50-65 deg.c, and heating to 60-78 deg.c for reflux reaction until the reactant system becomes transparent; filtering the resultant to obtain solid product, washing with carbon tetrachloride and water separately and vacuum drying to obtain pentabromo benzyl bromide.

具体步骤为：将五溴甲苯、卤代烃、自由基引发剂和过氧化氢组成的反应体系加入到三颈瓶中，将0.07～0.1mol的溴溶于50ml卤代烃配成溶液，在50-65℃温度下滴加到反应体系中，滴加时间为50-70分钟，然后升温至60-78℃温度下回流反应，至反应体系逐渐变透明，且不再产生气泡时，将所得产物过滤，得到固体产物，分别用CCl 4 和水洗涤，真空干燥，即得到五溴苄基溴；其中，五溴甲苯与溴的摩尔比为1∶0.7-1∶1.0，溴与过氧化氢的摩尔比为1∶1.0-1∶1.4，自由基引发剂加入量为五溴甲苯重量的1-10％，卤代烃的加入量为反应体系体积的40％-100％，所用溶剂可以直接进行下一批反应，不需要更换溶剂或蒸馏提纯。

When we used ligand 3k-Zinc in the asymmetric addition of phenylacetylene to ketones at room temperature, the highest ee was up to 85%.

当我们用配体3k-Zinc作为催化剂在对苯乙炔对酮的不对称加成反应中，产物最高的ee可达85％。

The results show that the degradation effectiveness of PVA was optimum when potassium ferrate and sodium hypochlorite were jointly used as the oxidative agent. The removal rate of PVA and COD was more than 98% and 40% under the conditions that the concentration of PVA was 3.0 g/L and the pH value was 7.2, the dosage of potassium ferrate and sodium hypo chlorite were 0.32 g/L and 3.92 g/L, and the reaction time was 50 min. In the process of united oxidative degradation, the chain of PVA was cut off and many low molecular weight compounds were formed. The main degradation products were carboxyl compounds.

结果表明，用高铁酸钾与次氯酸钠联合氧化PVA时，降解效果最佳；在3.0 g/L，pH值为7.2的PVA溶液中，当高铁酸钾与次氯酸钠的投加量分别为0.32 g/L、3.92 g/L，反应时间为50 min时，PVA的去除率大于98%，COD去除率大于40%；在联合氧化降解过程中，PVA断链成小分子物质，最终降解产物主要为羧基化合物。

The result obtained was very promising. Meanwhile, [3+2]-cycloaddition of aziridines with nitriles was discovered by using Sc3 as catalyst.

与此同时，我们还发现了Sc3可以很好地催化腈与2-芳基氮杂环丙烷的[3+2]环加成反应，得到了二氢咪唑产物，产率中等到优秀。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。