加成产物

The reaction of α-hydroxyketone with Michael acceptor nitroalkene.was studied. After many experiments, we then found that in the presence of Zn2 and cinchonine, the α-hydroxyketone could successfully react with nitroalkene. Under our optimized condition, we gained the 95% yield of product with the ratio of syn : anti of 3:1 and 72% ee value for syn-product.

有机碱作用下α－羟基酮对硝基烯烃的加成反应研究研究了α－羟基酮类化合物与Michael受体硝基烯烃类化合物的反应，通过分析和实验发现在Zn2和辛可宁的作用下α－羟基苯乙酮能够与硝基烯烃化合物顺利反应，在优化的条件下以95%产率和3：1的Dr主要得到顺式产物，其中顺式产物的ee值最高为72%。

In the reaction of a-stannyl radical addition to carbonyl to form six-membered ring, we constructed a sulfonyl group at the a position of the formyl group to inhibit 1,5-H shift in order to increase the cyclization product yield. We obtained 41 % yield of the cyclization product in this system.

在 a-锡基自由基加成到醛基形成六员环的系统中，我们在醛基的 a 位上加入碸基来抑制 1，5-氢转移并提升环合产物之产率，在这个系统中，我们得到了 41 %的环合产物。

The adducts of ethylene oxide and propylene oxide are possessed of the majority of nonionic deinking agents. They are the adducts of fatty acid and polyol and monoethanolamine.

在非离子脱墨剂中，环氧乙烷和环氧丙烷的加聚产物占了绝大部分，分别为硬脂肪酸、高碳醇和烷酰醇胺型的加成物。

Therelationship of the amount of catalyst and the ee% of product was seen to be negative nonlin-ear. Catalyst 3 was used in the enantioselective addition of diethylzinc to aromatic aldehydesand gave good results. The configuration of products was determined by the configuration ofthe catalysts' chiral carbon linked with hydroxy group. Using β- amino alcohols bearing only one chiral center as catalysts for the enantiose-lective addition were studied. D-N, N-dialkyl-2-amino butanol gave poor catalytic effect be-cause of their structure. The configuration of the product is the same as the catalyst. Anotherkind of β- amino alcohols - phenylglycine derivatives and valine derivatives have chiralcenter on the carbon linked with amino group. Catalyzed by-phenylglycine derivatives 6,7, 9, 10, the reactions gave satisfied results. The optical yields exceeded 80%.

在探讨了含有两个手性中心的β-氨基醇之后，选择了只有一个手性中心的β-氨基醇，一是手性中心为连羟基的手性碳原子：D-N，N-二烷基-2-氨基丁醇；二是手性中心为连氨基的手性碳原子：D-苯基甘氨酸衍生物和L-缬氨酸衍生物。D-2-氨基丁醇的催化效果不太好，这与其结构的空间位阻较小有关系，反应产物与连羟基手性碳构型一致；由苯基甘氨酸和缬氨酸出发合成五种β-氨基醇6-10，研究了不同ee％的-6作用下的二乙基锌-苯甲醛加成反应，发现该催化剂具有不对称放大效应；-7，9，lO的催化效果也比较令人满意，光学产率80％以上，所得产物构型与催化剂构型一致。

By using GC/MS, the process of oxidizing reaction of atractylone is studied, and five decomposition products are obtained, which is greatly different from the references-only two decomposition products, and the mechanism of oxidizing reaction of atractylone is investigated. The hypothesized mechanism of reaction is: atractylone is readily to additively react with water and to generate the semiacetalhydroxyl at 1, 4-site.

利用GC/Ms法跟踪分析了苍术酮纯品的分解过程，得到5种分解产物―与文献报道的苍术酮转变成2种产物存在较大的差异；研究了苍术酮的氧化反应机理：苍术酮与水易进行1，4加成反应，生成半羧醛羟基。

A compound 2-(3-hydroxyphenyl)[60] fullerene pyrrolidine was synthesized by the 1,3-dipolar cycloaddition reaction of the fullerene(C60) and azomethine ylide (prepared from glycine and 3-hydroxybenzaldehyde). The product was characterized by UV-Vis,1H-NMR ,FT-IR and MS. The reaction conditions affecting the yields of product were investigated and the optimum reaction conditions with product yield 75%(based on consumed C60) were:molar ratio of C60∶3-hydroxybenzaldehyde:glycine 1∶3∶6,reaction temperature 95℃,reaction time 18h.

利用甘氨酸和3-羟基苯甲醛与C60发生1， 3-偶极环加成反应，合成分离得到了2-(3-羟基苯基)[60]富勒烯吡咯烷，用UV-Vis、1H-NMR、FT-IR、MS等测试手段表征了产物的结构，并通过单因素方法，探讨了反应条件对产物产率的影响，得到最佳工艺条件：反应物摩尔比1∶3∶6，温度95 ℃，反应时间18 h，产物的产率可达75%（以消耗的C60计）。

Two kinds of products can be obtained in the addition reaction of benzaldoxime with propinol, in which 3-hydroxymethyl-dihydroisoxazol is the main product when reaction equilibrium is reached.

炔丙醇的两种取向对应着加成反应的两种产物，反应达到平衡后， 3-羟甲基二氢异噁唑为主要产物。

A simple and efficient method for the synthesis of N3-functionalized 3,4-dihydropyrimidinones by aza-Michael addition reactions of 3,4-dihydropyrimidinones toα,β-ethylenic compounds catalyzed by KF/Al_2O_3 is described.

研究结果表明：DHPMs类化合物可与α，β-不饱和羰基化合物发生Michael加成反应，产物只有N3位功能化的DHPMs，而没有N1位的产物。

A detailed analysis of the experimental results implied that the attractive forces play a main role in the collisional quenching processes of NCO by the quenchers studied in this work, and for some quenchers, the quenching of NCO is probably controlled by the entrance-channel and might be ascribed to the contribution of chemical reactions.

这一加成过程是一个入口势能面属于纯吸引型的无垒过程，故是NCO+O反应的主要通道。二是O原子攻击NCO分子的O原子得到中间物tran-NCOO，再通过C-O键的断裂生成产物CN+OO。该产物通道由于是吸热的，故很难发生。

This dissertation is concerned with the approaches to a new high density liquid fuel, tetrahydrotricyclopentadiene, which can be synthesized with dicyclopentadiene as raw materials by three steps: Diels-Alder reaction, separation and hydrogenation. The main points of the paper are listed as follows.

本文以双环戊二烯为原料，通过双烯加成、分离、加氢反应得到目的产物——新型高密度液体燃料四氢三环戊二烯，主要研究内容包括： 1。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了