加成产物

It was found that the products are mixture of Michael-adduct and acetal.

发现在适量甲醇存在时，其超临界反应产物是Michael加成产物和缩醛。

I-BuMgBr was the best Grignard reagent and its enantioselection was up to 94%.

其中，异丁基格氏试剂加成产物ee值最高，为94%。

In the course of our research for the construction of epibatidine skeleton, we found that 1, 3-dipolar cycloaddition could be occurred in DCM and DMF respectively.

在探索骨架21形成的过程中，我们发现以〓及DMF为溶剂，均可得到环加成产物。

E. value of productions were detected by high performance liquid chromatography. Results The chiral aminoalcohol ligand compound Ⅰ can promote the asymmetric allylation of acylhydrazones and the yield was 57%; The highest values of e. e. obtained for this reaction was 22%.

结果 手性氨基醇配体化合物Ⅰ能够促进烯丙基三氯硅烷和酰腙的烯丙基化加成反应，在它的辅助作用下，烯丙基化加成产物的产率可达到57%，对映体过量值最高达到22%。

The speed of electrophilic addition reaction of Alkene is inferenced greatly by the electron-withdrawing group or electron-releasing group on C=C of Alkene And the main addition product is decided by stability of carbonium ion.

烯烃C=C上连有供电子基和吸电子基时，对于烯烃亲电加成反应速度的影响是很大的。加成产物是由碳正离子中间体的稳定性来决定。

Reaction of [60] fullerene with malononitrile and ethyl cyanoacetate with the aid of Mn 〓·2H〓O produced methanofullerenes.

在以上反应中，多加成都是可以避免的，高产率的得到一些易分离的C〓的加成产物。

1 Heptane, it was revealed that the Cr〓/ Catsan and ZnCl〓 could catalyze the Michael addition of pyrrole with conjugate olefine at α-position of pyrrole to get mono- or bi-Michael addition product selectively under mild condition in good yield. Totally, forty-six new compounds, including thirty target compounds, were prepared.

在探索7-氮杂桥环母体的构建方法过程中，发现了Cr〓／Clay和ZnCl〓可有效地催化吡咯的α-位与多种共轭烯烃发生Michael加成反应，可在温和的条件下，以良好的收率选择性地得到单或双Michael加成产物。

To explore new synthetic methods, we set out a careful investigation of the reaction of benzimidazolium salt with many nucleophilic agents, including the active aromatic compounds and heteratom nucleophilic agents, and found that the quaternary C=N is not so active; when benzimidazolium salt is reacted with big nitrogen nucleophilic agent? phthalimide, it does not give the expected addition product, instead, produces N-alkyl phthalimide through alkyl-transfermation from benzimidazolium salt to phthalimide.

为了开发新的合成方法，研究了苯并咪唑盐与各种亲核试剂（活泼芳环与杂原子亲核试剂）的反应，发现苯并咪唑盐不与活泼芳环及杂原子亲核试剂发生2位加成反应；在与体积较大的位阻型N亲核试剂邻苯二甲酚亚胺反应时，未得到亲核试剂与极化的C＝N的加成产物，而是得到N烷基化的邻苯二甲酰亚胺，进一步研究表明，苯并咪唑盐将1（3）位N上的烷基转移给了邻苯二甲酰亚胺，并讨论了其反应机理和取代基，溶剂效应。

First, when operating the DABCO-catalyzed Ireland-Claisen rearrangement of propargylic acrylates 18b-d, we added dienophiles 40a-f in the reaction system to capture the rearranged allenes products respectively. The Diels-Alder adducts 41a-i were obtained with complete regioselectivity. Thus a novel tandem Ireland-Claisen rearrangement /Diels-Alder reaction process with propargylic acrylates has been developed.

首先在进行DABCO-催化的丙烯酸炔丙酯类化合物18b-d的Ireland-Claisen重排反应的同时，于反应体系中分别加入亲二烯体40a-f捕获重排得到的连二烯中间体，一步反应获得了单一区域选择性的Diels-Alder环加成产物41a-i，从而创建了一条新颖的丙烯酸炔丙酯类化合物的Ireland-Claisen重排与Diels-Alder环加成的串联反应路线。

The electron-rich and sterically hindered ligand 9d provides the best enantioselectivities (up to 97.8 % ee) for various chalcones as the substrates.

其中富电子且空间位阻较大的配体gd对查耳酮类底物表现了最好的手性诱导能力，加成产物的ee值达到94.7一97.8%。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。