加

These results were veryreasonable considering the fact that cyclohexene and 1-octene can not bepolymerized with Ziegler-Natta catalyst.

产物的FD-MS分析结果表明：〓和辛烯-l的加成物为加成数从1到16的混合物；〓和环己烯主要生成加成数为9的加成物。

Both catalytic activity and selectivity of Ru(PPh_3)_3Cl_2 were improved in ionic liquid BMImPF_6/DME medium.The conversion of hexene and selectivity ofβ-adduct for the hydrosilylation reaction of 1-hexene with triethoxysilane catalyzed by Ru(PPh_3)_3Cl_2 in ionic liquid BMImPF_6DME (V/V=1/4) medium at 90℃were 100% and 89.0%,respectively.

实验结果表明，在乙二醇二甲醚/离子液体1-丁基-3-甲基咪唑六氟磷酸盐(BMImBF_6)(V/V =1/4)介质中，于90℃下，己烯与三乙氧基硅烷反应的转化率为100%，β加成物的选择性可达89.0%，而用Rh(PPh_3)_3Cl作为反应的催化剂，在纯离子液体BMImPF_6中，就可以高效催化烯烃与三乙氧基氢硅烷的加成反应，过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化剂/离子液体BMImPF_6催化体系，不仅解决了产物与催化剂分离困难这一难题，同时，离子液体BMImPF_6的存在提高了过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化硅氢加成反应的活性，特别是β加成物的选择性。

Since inextensible reinforcements do not stretch under design loading, they are the preferred MSE reinforcement type for highway structures in general and for critical structures such as bridge abutments in particular, where deformation control is crucial to structural performance of both the superstructure and the abutment.5 Inextensible reinforcements have been used successfully in MSE bridge abutment structures for thirty-five years, while research is still underway trying to develop an extensible

由于不可拉伸的加筋体在设计承载下不能拉伸变形，因此它们一般是公路结构，尤其是桥肩等重要结构中的首选材料，因为在这些结构中，变形控制对上层建筑和桥肩中性能表现是很关键的因素。不可拉伸加筋体在加筋土桥肩结构中已经成功的使用了35年，与此同时，研究能够在桥肩应用中性能有保证的可拉伸加筋体的工作正在进行中。

The dissertation mainly consists of two parts:1. The Reaction Chemistry of Alkynes under Palladium Catalysis Part 1 studies the reaction α,β-unsaturated carbonyl compounds with alkenylpalladium intermediate generated by nucleopalladation, and discovered 1 the Pd-catalyzed tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls,2 the four-component tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls, 3 the tandem intramolecular oxypalladation-conjugate additionreaction of alkynoic acids with α,β-enals. These new reactions provide notonly efficient highly stereoselective methods for the synthesis of γ,δ-unsaturated,polyunsaturated carbonyl compounds and γ-lactonic aldehydes, but also thebasic transformations for a number of C-C bond formation reactions which can be usedto design synthesis of many acyclic, cyclic or polycyclic compounds.

本论文的主要工作分为两个部分：一、钯催化下炔烃的反应化学在本小组前人工作的基础上，我们详细研究了炔烃亲核钯化产生的烯基钯中间体与α，β-不饱和羰基化合物的反应，发现两价钯催化下卤离子-炔烃-α，β-不饱和醛酮的串联加成反应、卤离子-炔烃-α，β-不饱和醛酮的西组分串联加成及炔酸分子内氧钯化-串联Michael型加成反应；由此发展了γ，δ-不饱和醛酮、多不饱和羰基化合物和带有醛酮基侧链的γ-丁内酯衍生物的高立体选择性合成方法，这一过量卤离子存在下的烯基钯对α，β-不饱和羰基化合物共轭加成反应的发现，为大量碳-碳键形成反应的实现提供了基础，使我们能够从这一基本反应出发，设计和开发多种分子内、分子间的碳碳成键反应，以好的立体、区域选择性组建开链、环状及多环类型的化合物。

Friction coefficients and lubricative mechanics of Al-Fe-V-Si heat resistant aluminum under four conditions were researched by method of annulus compression, without lubricant, but in the presence of pure aluminum, graphite+oil, pure aluminum+graphite+oil.

摘 要：采用圆环压缩法检测Al-Fe-V-Si系合金在喷射沉积高温时变形的摩擦因数，研究未加润滑剂、加石墨+机油润滑、加纯铝润滑、加纯铝+石墨+机油润滑4种条件下的摩擦因数随变形温度变化的情况，并探讨其润滑机理。

Arroyo's government saw the "correct" positioning of the Philippines on the "war on terror" as a once-in-a-lifetime opportunity to get rid of Muslim separatism, especially in strategic Mindanao - located close to Indonesia and critical checkpoints in the Strait of Malacca, Sunda, Lombok and Makassar, areas through which at least 40% of Japanese and ASEAN (Association of Southeast Asian Nations) trade transits.

至于阿罗约沾沾自喜的&美菲特殊关系&，德高望重的政治社会学家贝罗提醒菲律宾人，&20世纪50年代末，为促进国家工业化和减少奢侈品进口，加西亚总统推行'菲律宾第一'政策并控制外汇，但美国外交官帮助阿罗约的父亲马卡帕加尔在总统大选中击败了加西亚，因为马卡帕加尔许诺放松对外汇的控制。&

The combined Fatliquor LWF, modified reap oil -based fatliquor, phosphated fatliquor and acrylic fatliquoring retanning .

可进一步合成LWF结合型加脂剂、改性菜油加脂剂、磷酸酯加脂剂、丙烯酸加脂复鞣剂。

Results EROD activities in liver of wild crucian from Zhangtan, Jiangjunyan, Fuyang and Wenyan (23.51±4.17, 16.79±7.39, 18.74±5.16, 18.65±8.86 nmol/) were significantly higher than that of Jiekou (7.84±2.42 nmol/g promin), and no difference was observed between the other sites and Jiekou. Three dose groups (0.25, 0.50, 1.00L/dish water sample extracts) were used in Ames test. Reversional mutation rate of TA98 colony exposed to extracts from Zhangtan was 2.21, 3.39, 6.95 without S9, and 2.70, 4.07, 6.23 with S9, respectively. The revesional mutation of TA100 colony was 2.55, 2.81, 5.36 without S9, and 1.73, 2.86, 4.14 with S9, respectively. Reversional mutation rate of TA98 colony exposed to 1.00L/dish extracts from Jiangjunyan with S9 was 2.22, and there was a dose-response relationship in reversional colony count. Ames tests of the other extracts were negative.

结果 樟潭、将军岩、富阳、闻堰点位野生鲫鱼肝EROD酶活性分别为(23.51±4.17)，(16.79±7.39)，(18.74±5.16)，(18.65±8.86)nmol/，明显高于街口[(7.84±2.42)nmol/]，其他点位与对照比较差异无统计学意义；樟潭水样浓集物在浓度为0.25，0.50，1.00 L/皿时在不加与加S9条件下，TA98回变菌落突变率MR值分别为2.21，3.39，6.95，2.70，4.07，6.23；TA100回变菌落MR值分别为2.55，2.81，5.36，1.73，2.86，4.14；Ames试验结果为明显阳性；将军岩水样浓集物在浓度为1.00 L/皿且加S9条件下TA98MR值为2.22，且在浓度为0.25，0.50，1.00 L/皿加S9条件下TA98回变菌落数呈剂量－反应关系，MR值分别为0.88，1.98，2.22；Ames试验结果为弱阳性；其他点位均为阴性。

This novel catalyst was successfully used in the selective hydrogenation of halogenated aromatic nitro compounds.

作为加氢催化剂，Pd/CNTs对卤代硝基物的催化加氢表现出较高的催化性能，其加氢活性比P出C加氢催化剂高。

The genetic analysis was carried out for 8 characters on 9 energy cane parents and their 20 combination crosses with the NCII mating design. The results showed that the inheritance of stalk biomass, brix weight, available stalk numbers and weight per stalk was subject to both additive gene effect and non-additive genes effect, but mainly controlled by non-additive genes. The inheritance of plant height, stalk diameter and brix was subject to both additive gene effect. The broad sense heritability (HB2) of stalk biomass and brix was over 50%, and those of brix weight were 33.7% at the seedling stage 54.4% at its ratooning stage, respectively , which means that the selection would be done better at the early stage in the sugarcane breeding program.

利用遗传交配设计对能源甘蔗9个亲本组配的20个组合、8个性状进行遗传分析，结果表明：地上部鲜重、锤重、丛有效茎数和丛重的遗传既受基因的加性效应也受基因的非加性效应所控制，但以非加性效应为主；株高、茎径和锤度的遗传主要是受基因的加性效应控制，地上部鲜重和锤度实生苗新植和宿根的H_B~2都在50％以上，而锤重的H_B~2分别为33.7％和54.4％，而且锤重和地上部鲜重母本gca方差都大于父本gca方差，说明能源甘蔗育种中母本选择的重要性。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。