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S-1-phenylethanol was obtained in up to 19%ee in toluene at 0℃.(4)A series of C_2-symmetric chiralβ-amino alcoholsⅣ-5were synthesized in several steps from natural amino acid L-proline,and applied in the asymmetric borane reduction of prochiral ketones.

4以天然L-脯氨酸为起始原料,经过几步转化合成了以萘环为母体的C_2-对称的手性β-氨基醇Ⅳ-5,将其应用于硼烷对前手性酮的不对称还原反应中,同样,我们也观测到温度影(来源:Ac1BC论文网www.abclunwen.com)响产物构型的现象。

Asymmetric catalytic activity of chiral spiroborate esters,- or-1,1′-bi-2-naphthoxyboric acid-proline anhydride [-1 or-1], toward borane reduction of prochiral imine s has been ob- served.

手性螺硼酸酯-或-1,1'-联-2-萘酚硼酸--脯氨酸酐[-1或-1]对前手性亚胺硼烷还原的不对称催化活性被观察到。

Preparation of ultra fine MgNi2 powder via reduction of the oxide precursor was systematically studied.The precursor was prepared with nickel nitrate,magnesium nitrate and glycin as start materials by combustion method.

以Mg(NO3)2和Ni(NO3)2为原料,用甘氨酸作为氧化剂,采用燃烧法制备约50 nm的混合金属氧化物前躯体,再在H2气氛保护下的管式炉中用CaH2还原制备MgNi2合金。

This research take late-maturing variety adzuki bean Jihong-4 as the experiment material, After the photoperiod inducement at different leaf ages treatment, the result showed that the activity of NR under LF treatment is higher than CK treatment on the whole, and is lower than SD treatment; The content of the dissociation amino acid under these three treatments show a descend trend along with the leaf ages accretion, but the inducement increasing the content of dissociation amino acid, different leaf ages leaves show some difference, and alternating rise with SD treatment; Inducement can reduce the content of soluble sugar, and continuous inducement shows a accumulation effect; 2LF is the most sensitivity stage for soluble protein under photoperiodic inducement, From this stage, each leaf indumenta can reducing the content soluble protein, but continuous inducement reducing rising it.

本研究通过光周期诱导的方法,对中晚熟品种冀红4号红小豆进行不同叶龄进行处理,结果表明:所有叶龄处理下硝酸还原酶活性基本高于自然光处理而低于连续短日照处理下的;随着叶龄增大,各处理游离氨基酸总量均呈下降趋势,但光周期诱导可提高游离氨基酸含量,不同叶龄表现有所差异,与连续诱导交替上升;诱导可降低可溶性糖的含量,并连续诱导出现累积效应;2LF是光周期诱对可溶性蛋变化最敏感的时期,这个时期起单个叶龄诱导可降低可溶性蛋白含量,但连续诱导却可提高;LF处理下的类胡萝素总体含量高于另两个处理,而LF处理下的叶绿素含量在仅3叶龄前高于CK处理下的,随后出现下降趋势。

The asymmetric reduction of prochiral P-oxo ester, aromatic ketone and aliphatic ketone to its corresponding chiral alcohol by yeast cells were studied respectively in this work when ethyl 4-chloro-3-oxobutyrate, acetophenone and 2-octanone were as the model substrates.

本文以4-氯乙酰乙酸乙酯、苯乙酮和2-辛酮分别为β-羰基酯、芳香酮和脂肪酮的模型底物,研究了利用活性酵母细胞催化这三类前手性酮不对称还原合成相应手性醇的反应特性。

Three-dimensional models of knee joint bone structure were then reconstructed on computer with the experimental data.

目的 利用虚拟现实技术还原膝关节骨性结构在屈伸运动过程中的三维空间形态,为观测膝关节面交叉韧带附丽区的相对位置变化和进一步研究前、后交叉韧带等长承建最佳等长点提供计算机辅助设计新方法。

According to statistics, as of yesterday, in December the first 10 trading days there are 30 companies large and small non-reduction notice.

据统计,截至昨天,在12月前10个交易日内有30家公司大,小非还原通知。

Under his leadership, Russia has rewritten history to reinstate the Stalinist version, in which the Soviet Union bears no guilt for the war or for the enslavement of eastern Europe.

在他执政期间,俄罗斯改写了历史,将其还原成斯大林时期的版本----前苏联挑起战争和奴役东欧均被看作是无罪的。

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And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47:5 法老对约瑟说,你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法,同时,采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。

Hey Big Raven, The individual lies dont matter anymore - its ALL a tissue of lies in support of...

嘿大乌鸦,个别谎言的事不要再-其所有的组织的谎言,在支持。