制备

Major content of this work includes five aspects as follows:(1). Oxygen sensitive materials had been prepared by carrier covalence method, and the preparation mechanism of the materials had been investigated by FI-IR, SEM, and the detection experiment of oxygen. Then through the detection of oxygen, the sensitivity and stability had been estimated, and it was studied that the properties of materials would be affected by the various factors.(2). Oxygen sensitive materials had been prepared by carrier covalence-cross linking method, and the preparation mechanism of the materials had been investigated by FI-IR, SEM, and the detection experiment of oxygen. Then through the detection of oxygen and spectrophotometer, the sensitivity and stability had been estimated, and it was studied that the properties of materials would be affected by the various factors.(3). For the detection of gaseous oxygen, the fiber optical sensor on basis of oxygen sensitive materials had a respond time of 10s, detection limit of 5ppmand detection precision of 0.5%. The sensor had good repeatability and stability, a less delay and at least 1 year life-span.

本论文主要包括以下五个方面的内容：(1)载体共价法制备氧敏感材料：通过红外光谱、扫描电镜图谱和氧测试实验探讨该氧敏感材料的制备机理，通过氧测试实验评价该氧敏感材料的氧敏感性和稳定性，同时研究了各种因素对该氧敏感材料性能的影响(2)载体共价—交联法制备氧敏感材料：通过红外光谱、扫描电镜图谱和氧测试实验探讨该氧敏感材料的制备机理，通过氧测试实验和分光光度计评价该氧敏感材料的氧敏感性和稳定性，同时研究了各种因素对该氧敏感材料性能的影响(3)氧敏感材料在光纤气态氧传感器中的应用：该传感器的响应时间为10s，检测下限为5ppm，检测精度为0.5％，具有较好的重复性和稳定性，迟滞较小，使用寿命至少为1年，适合各种环境下气态氧浓度的检测。

In this paper, the Iron-oxide-coated sand absorption character prepared in different temperatures was studied, mainly tested its absorb hexad chromium, and the inherent reason that formed this differences was explained.

本文研究了不同温度下制备的铁覆膜砂吸附性能的差异，对铁覆膜砂吸附Cr的性能进行了综合的测试，说明了形成这些差异的内在原因制备温度对IOCS的吸附性能有显著影响，一般低温制备的IOCS要比高温制备的铁覆膜砂吸附性容量较大，去除效率较高；覆盖在石英砂表面的铁氧化物在不同的焙烧温度下形成了不同的物质，110℃的低温一般形成FeOOH，而600℃高温下形成的则为α-Fe2O3。

This paper studies depression in the hot cathode glow discharge PCVD method of diamond films influence in the process, mainly from two aspects of research: a study of the process of discharge pressure of the impact of that pressure on the technology, the impact of state discharge , as well as pressure and discharge voltage of the relationship between the two, and experiment with different pressure, relative to the preparation of samples, and using Raman instrument and SEM analysis of the quality of the film, by comparing the different types of gas pressure on the quality of diamond films, summed up the most good gas pressure parameters of a high-quality diamond films.

本文研究气压在热阴极辉光放电PCVD方法制备金刚石膜过程中的影响，主要是从两个方面进行研究：一，研究制备过程中气压对放电的影响，得出气压对工艺，放电状态的影响，以及气压和放电电压的关系；二，采用不同气压进行实验，制备出相对应的样品，并用Raman和SEM等仪器对膜进行质量分析，通过对比不同气体压强对金刚石膜质量的影响，总结最佳气体压强参数，制备出高品质金刚石膜。

Magnesium methylate can be prepared by reacting magnesium with dry methanol; Primary alcoholates can be prepared by alcoholysis; the sterically demanding substituted magnesium alcoholates can be prepared by ester exchange or from dialkylmagnesiums.

综上所述，几乎所有的醇镁化合物都可以通过这三种方法进行制备：甲醇镁通过直接合成法制备；伯醇镁通过醇解法制备；仲醇镁或叔醇镁通过酯交换或烷基镁法制备。

A series of molybdenum carbide catalysts were prepared using 20%CH4-H2 to carburize molybdenum trioxide at different temperatures. The catalysts were characterized using X-ray diffraction, X-ray photoelectron spectroscopy and N2-adsorption. Their catalytic performance was evaluated in the model reaction of the dry-methane reforming to synthesis gas. Here, the characteration of bulk and surface Mo2C catalysts and its influence on the catalytic performance were described.

以MoO3为前驱物，于20%CH4-80%H2的混合气体(100 mL/min)中，在不同设定终温下进行碳化，制备了一系列不同碳化终温的Mo2C，通过XRD和XPS等手段进行了表征，并对其甲烷二氧化碳重整制备合成气的催化性能进行评价，讨论了碳化终温作为Mo2C的制备参数，与所制备的Mo2C体相、表面特征和催化剂性能的关系。

First SnCl2·2H2O and SbCl3 were dissolved with ethyl alcohol respectively,then nesa coatings were prepared with different ratio of Sb/Sn sols by different methods as such dipping-coating,spraying and spinning .

将SnCl2.2H2O和SbCl3分别溶解于乙醇中，搅拌至完全溶解，以不同的Sb/Sb混合制备得到溶胶后，分别采用浸渍提拉、喷涂、旋涂工艺制备透明导电膜，并考察了不同制备工艺及热处理温度对膜的厚度、薄膜方块电阻以及对薄膜透光率的影响，运用XRD、SEM、TEM对所制备的透明导电膜进行了分析表征。

The specific properties of materials, such as the palate adhesion, dynamic cruor, anti-bacterial and the degradability of lysozyme, were studied, which provide valuable data for further application. The main creative ideas are listed as follows:(1) The water-retention chitosan/poly vinyl alcohol blend fiber was obtained by coagulating in 10％ NaOH/ethanol solution, and the blend and crosslink due to GA can enhance the mechanical properties of fiber;(2) The controlled degradable chitosan/gelatin blend fiber was obtained by solution filature, and the mechanical properties were improved;(3) The N-acylchitosan with the different degree of substitution were successfully prepared, and the relationship between structure and properties was estabilished;(4) By a new solvent system of 6％ NaOH/4％ urea for cellulose, the blood anti-coagulant function films were prepared by blending cellulose with chitin;(5) In the same solvent system above mentioned, the anti-bacterial blend films based on cellulose and carboxymethyl-chitosan were prepared, and the relationship of DS and the anti-bacterial property was concluded;(6) The controlled degradable chitosan films was obtained by the chemical crosslink.

本论文的主要创新点：（1）以NaOH水溶液／无水乙醇为凝固液，采用溶液纺丝法制备出保水性壳聚糖／聚乙烯醇纤维，共混和戊二醛交联极大提高了壳聚糖纤维力学性能；（2）用壳聚糖和明胶共混，以溶液纺丝法制备出可控降解的壳聚糖／明胶纤维，并大幅度提高了壳聚糖共混纤维的干、湿态抗张强度；（3）确立了不同取代度N-酰基壳聚糖的合成方法及其膜的结构与性能的关系；（4）利用纤维素新溶剂6％NaOH／4％尿素制备出抗凝血性纤维素／甲壳素共混膜；（5）利用上述纤维素新溶剂制备出抗菌性纤维素／羧甲基壳聚糖共混膜，揭示了羧甲基壳聚糖取代度与抗菌性能的关系；（6）制备出可控降解壳聚糖交联膜。

Design the structure of high performance Low-E film including its material and thickness of every layer according to basic optical theory. Carry out an innovative work to calculate its optical performance by characteristic matrices and optical admittance. Compare the results with those we get by traditional measurement.3. Prepare Low-E films with RF magnetron controlled reactive sputtering. The result shows that in the visible region (380nm-780nm), the highest transmittance is 82.4% while the average value is 75%. In the NIR region (780nm-2500nm), the average transmittance is 16.2%. These characters can fit the demand of the glass used in architecture and cars, and also in other applications.4. We novelly use the material Titanium as protective layer to solve the problem that Ag layer would disappear when depositing the second TiO_2 layer. As the protective layer, Ti does not increase the number of targets so as to lower the costs. The thickness of the protective layer Titanium is adjusted by controlling of sputtering time. Results shows the Low-E films get the best optical character when the sputtering time of Titanium is 20 seconds5. We novelly proposed a new transmittance quality factor Q=_·(?_-__ to evaluate the performances of Low-E films, which makes it easier to judge the qualities of Low-E film.6. The photocatalysis of Titanium dioxides is researched and introduced into Low-E films. Sb-doped TiO_2 thin films are prepared. Its photocatalysis and hydrophilicity are measured.

论文的工作主要有：1、总结了低辐射薄膜的制备方法，性能，以及国内外最新研究进展和应用，并对两种类型的低辐射薄膜进行了比较。2、从光学基本理论开始，设计了离线低辐射薄膜的结构，包括每一层的材料和厚度，并创新性的用特性矩阵和光学导纳理论计算了该离线膜的光学性能，利用软件对其进行了仿真，与实际制备的薄膜所测量的性能相比较。3、完成在实验室仪器上制备低辐射薄膜，掌握其工艺条件，解决了超薄金属膜的制备问题，所制备的低辐射薄膜在可见光区(380hm-780hm)最高可达82.4%，平均透射率为75%；在近红外区(780nm-2500nm)的平均透射率为16.2%，其性能达到建筑物幕墙玻璃，汽车前挡玻璃等应用标准，并为进一步的大规模生产打下基础。4、针对中间银层在镀上层膜时易被氧化这一工艺难题，本研究创新性的提出用Ti膜作为保护膜，没有增加新的靶材，提高了生产效率，并节约了生产成本。

Nanocrystalline copper tellurides Cu〓Te〓 and Cu〓Te〓 have been successfully prepared in ethylenediamine and ethylenediamine with hydrazine hydrate system under high-intensity ultrasonic irradiation at room temperature respectively. Nanocrystalline silver tellurides Ag〓Te and Ag〓Te〓 have been successfully prepared in ethylenediamine and ethanol system under high-intensity ultrasonic irradiation at room temperature respectively.

在制备碲化铜时，在纯乙二胺体系超声辐射所制备的最终产物为Cu〓Te〓，而在加有水合肼的乙二胺中制得的产物为Cu〓Te〓；在制备碲化银时，在乙二胺体系制备的产物为Ag〓Te，而在乙醇体系制备的产物为Ag〓Te〓。

The author prepared bulk SmBaCuO single crystals with 5×5×5mm〓 by MTG method. The SmBaCuO crystals were proved by X-ray diffraction and X-ray back-reflection Laue technique. SmBaCuO crytal became 90K zero resistance superconductor by the study of the relation of transition temperatures and heat treatment conditions.

采用MTG法及其它类似的方法制备的YBCO超导体的小样品具有很好的超导电性能，但要使YBCO超导体获得实际应用，必须制备超导电性能优异的大块YBCO超导材料，采用籽晶诱导技术是制备高性能大块YBCO超导体的有效方法，因此，制备较大尺寸高质量的〓〓单晶是籽晶诱导技术成败的关键，作者用MTG工艺制备了尺寸达5×5×5mm〓的大块〓单晶，X-ray衍射及X-ray劳埃像法证明MTG法制备的〓晶体具有很好的单晶特性。

Plunder melds and run with this jewel!

掠夺melds和运行与此宝石！

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻，也许正是在通往天国的路上，我体验着这白色的晕旋。