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The pH value in soil was significantly increased in litter aqueous extract of four decomposition stages. The NH+4-N concentration was significantly decreased in soil amended with litter aqueous extract of 10-day decomposition which promoted the growth of Aerobic azotobacter and Ammonifier but inhibited the growth of Aerobic cellulose-decomposer. Available phosphorus concentration was significantly increased and phenolic acid content was significantly decreased in soil amended with litter aqueous extract of 60-day decomposition which inhibited the growth of Aerobic azotobacter but promoted the growth of Aerobic cellulose-decomposer.

不同分解时间的凋落物浸提液均造成了土壤pH值的显著升高;分解10d的凋落物浸提液对土壤铵态氮的含量具有显著的降低作用,对土壤好气性自生固氮菌和氨化细菌的生长均具有显著的促进作用,而对好气性纤维素分解菌的生长具有抑制作用;分解60d的凋落物浸提液显著地降低了土壤酚酸含量,对土壤有效磷含量具有显著的升高作用,对好气性自生固氮菌的生长具有抑制作用,而对好气性纤维素分解菌的生长具有促进作用。

The change of remaining litter weight was the largest in the earlier 30 days during 60-day litter decomposition, and there was no significant difference in subsequent 30 days. The phenolic acid content of litter was significantly reduced with the decomposition time prolonging, and the releasing quantity of phenolic acid was the highest at the tenth day. The amounts of soil Aerobic azotobacter, Ammonifier and Aerobic cellulose-decomposer and the soil chemical properties such as pH, phenolic acid content, NH+4-N and available phosphorus were significantly affected by the litter aqueous extract of four decomposition stages.

凋落物分解的60d中,凋落物残留量在前30d内变化最大,30d后无显著变化;凋落物中酚酸含量随分解时间的延长,呈显著降低的趋势,且在分解10d时,酚酸释放量最大。4个分解动态的凋落物浸提液显著地改变了土壤好气性自生固氮菌、氨化细菌、好气性纤维素分解菌的数量和土壤pH值、酚酸含量、铵态氮、有效磷等化学性质。

The phenolic acid content of litter was significantly reduced with the decomposition time prolonging, and the releasing quantity of phenolic acid was the highest at the tenth day. The amounts of soil Aerobic azotobacter, Ammonifier and Aerobic cellulose-decomposer and the soil chemical properties such as pH, phenolic acid content, NH+4-N and available phosphorus were significantly affected by the litter aqueous extract of four decomposition stages.

凋落物分解的60 d中,凋落物残留量在前30 d内变化最大,30 d后无显著变化;凋落物中酚酸含量随分解时间的延长,呈显著降低的趋势,且在分解10 d时,酚酸释放量最大。4个分解动态的凋落物浸提液显著地改变了土壤好气性自生固氮菌、氨化细菌、好气性纤维素分解菌的数量和土壤pH值、酚酸含量、铵态氮、有效磷等化学性质。

The mass loss patterns of four type litters fitted exponential model, and the decomposition rate could be well predicted by their lignin/N ratio.

结果表明:与对照相比,降水量减少条件下,蒙古栎叶凋落物的初始N、P、K浓度显著升高,初始木质素浓度显著降低,凋落物分解速率大,N、P、K矿化率高,N和P固持时间缩短;降水量增加情况下,其凋落物初始N浓度显著降低、木质素浓度显著升高,N、P、K矿化率低,N和P固持时间延长。4种类型叶片凋落物的质量损失过程均符合指数降解模型,分解速率可以由凋落物木质素/N来预测。

The biocatalyzed characters of the purified cellulases were investigated with the CMC-Na as substrate. The most appropriate catalyzed temprature for cellulase 1 is 60 "C,and 65 for cellulase 2. The two enzymes have the extreme stability at the temperatures no more than 50.The CMC-Na has the protective effect on the cellulase. The pH stability range of cellulase 1 is 4 ~ 8, and 6-9 for cellulase 2. Zn2+, Ca2+, Mg2+, K+, Li+can ativate cellulase 1. K+, Li"1 can ativate cellulase 2. Cellulase 1 can mainly decompose CMC and salicin. Cellulase 2 can decompose not only CMC and salicin, but other substrates feebly.

以羧甲基纤维素为底物时,酶1的最适催化温度为60℃,酶2的最适催化温度为65℃,在50℃以下稳定性较好,底物对酶有较强的保护作用;酶1和酶2的最适pH分别为5.5和5.5~6.0,酶1的pH稳定性范围为4~8,酶2的稳定性范围为6~9;Zn~(2+),Ca~(2+),Mg~(2+),K~+,Li~+对酶1有激活作用,K~+,Li~+对酶2有激活作用;酶1主要对CMC和水杨素有分解作用,对其它底物几乎不分解;酶2除了可以分解CMC和水杨素外,对其它底物也有微弱的分解作用。

Precursors of sulfates and alkali halides prepared in co-deposition process were mixed homogenously, annealed at high temperature and then formed CoO and NiO fibers, XRD, XPS, Raman and SEM were used to characterized the samples, the growth of these fibers might be a special LS mechanism: soluble precursors in molten salt decomposed gradually to form initial crystal nucleus and succeeding particles adhered to these nucleus and grew anisotropically in the special high temperature fluent medium, the higher decomposition temperature and solubility of the precursor are two key factors in this method, which are in favor of a longer growth process and result in larger sizes of the final metal oxides crystals.

以共沉淀方法生成硫酸盐与碱金属卤化物融盐的均匀混合前驱物,在高温下退火制备出了CoO和NiO的晶须,以XRD和XPS等对成份进行了分析,SEM分析了形貌特征,研究了不同前驱物热分解特性,认为本方法是一种简单的LS生长机制:可溶性前驱物于融盐中热分解后逐渐析出成核,后续的粒子附着在核上,在融盐环境下沿一定方向作准一维生长,其产物形貌之不同源于硫酸盐的高分解温度和在融盐中的可溶性,导致晶体生长过程中成核过程与生长过程竞争的结果对一般前驱物结果的偏移。

The average depth of the 15 surveyed sample plots is(8.2 cm),and the maximum,13.7 cm,the minimum,1.5 cm,with 10 times differences between these two values.The undecomposed component in the withered litters of moss is relative more,accounting for 42.8%,and semi-decomposed and decomposed one is less,accounting for 23.8% and 33.4%,respectively.

结果表明,试验流域苔藓枯落物层分布与组成存在明显差异,15个样地平均厚度8.2 cm,厚度最大达13.7 cm,最薄仅1.5 cm,相差近10倍;苔藓枯落物中未分解成分较多,占总量的42.8%;半分解和已分解成分较少,分别占23.8%和33.4%。

In order to assess the change of triploid populus tomentoza pulp plantation long-term-site productivity, The paper studied on effects of aboveground litterfall, fine root turnover and wet dust precipitation in nutrient cycling of triploid populus tomentoza pulp plantations at different ages,namely 2a、4a、5a、6a.It studied influence of different factors on decomposition of leaf、tree bark and twig of triploid populus tomentoza to select the operations to accelerate the decomposition and nutrient release. Finally, it studied influence of different intercrops on plantation site productivity and the relationship of intercrops and triploid populus tomentoza to select suitable intercrops. The main results as follows:(1)The aboveground litterfall of triploid populus tomentoza increased along with age from 216.03±59.7gm~(-2) at 3a to 482.38±101.3gm~(-2) at 7a, The N returned by litterfall wasl8.38±2.46kg.hm~(-2)a~-121.63±2.25kg.hm~(-2a~-139.51±4.61kg.hm~(-2a~-138.89±4.89kg.hm~(-2a~(-1) at 3a、5a、6a、7a respectively. The P returned by litterfall was 5.80±0.62kg.hm~(-2)a~(-1)、8.16±0.94kg.hm~(-2)a~(-1), 11.31±1.33kg.hm~(-2)a~(-1)、11.76±1.37kg.hm~(-2)a~(-1) at 3a、5a、6a、7a respectively. The nutrient returned by fine root turnover increased along with age, too. The N returned by fine root turnover was 3.85±0.41kghm~(-2)a~(-1)、5.22±0.63kghm~(-2)a~(-1),7.62±0.89kghm~(-2)a~(-1),9.17±1.22kghm~(-2)a~(-1) at 3a、5a、6a、7a respectively. The P returned by fine root turnover was 0.73±0.07kghm~(-2)a~(-1)、1.69±0.09kghm~(-2) a~(-1)、1.92±0.31kghm~(-2)a~(-1)、1.96±0.21kghm~(-2)a~(-1) at 3a、5a、6a、7a respectively. The leaf was the principal pathway to return nutrient to soil among litterfall, fine root turnover and wet dust precipitation. The proportion of returned N by leaf was 74.84%、71.96%、78.58%、75.03% at 3a、5a、6a、7a respectively,The proportion of returned P by leaf was 85.93%、80.31%、83.04%、83.23% at 3a、5a、6a、7a respectively. Therefore, it is important to protect and utilize the leaf in order to maintenance and enhance the long-term-site productivity of triploid populus tomentoza pulp plantation.

本文采取时序研究法,以3a、5a、6a、7a共4个不同年龄的三倍体毛白杨纸浆林为对象,研究了地上凋落物、细根周转、湿沉降在林分N、P营养元素循环中的作用及不同年龄林分N、P营养元素循环的特征,以评价三倍体毛白杨纸浆林长期立地生产力的变化;采取网袋法研究了不同因素对落叶、树皮、树枝分解的影响,以确定加快其分解、促进养分释放的措施:同时研究了不同间作物对林地影响、林木与间作物之间关系,以选择能维持立地生产力的合适的间作物种类等内容,得到以下结论:(1)随着年龄的增加,三倍体毛白杨地上凋落物的数量从3a的216.03±59.7gm~(-2)增加到7a的482.38±101.3gm~(-2),通过凋落物归还的N分别为:3a时为18.38±2.46kg.hm~(-2)a~(-1),5a时为21.63±2.25kg.hm~(-2)a~(-1),6a时为39.51±4.61kg.hm~(-2)a~(-1),7a时为38.89±4.89kg.hm~(-2)a~(-1),归还的P分别为:3a时为5.80±0.62kg.hm~(-2)a~(-1),5a时为8.16±0.94kg.hm~(-2)a~(-1),6a时为11.31±1.33kg.hm~(-2)a~(-1),7a时为11.76±1.37kg.hm~(-2)a~-1随着年龄的增加,通过细根周转归还的养分也在增加,归还的N分别为:3a时3.85±0.41kghm~(-2a~(-1),5a时5.22±0.63kghm~(-2)a~(-1),6a时7.62±0.89kghm~(-2)a~(-1),7a时9.17±1.22kghm~(-2)a~-1归还的P分别为:3a时0.73±0.07kghm~(-2a~(-1),5a时1.69±0.09kghm~(-2)a~(-1),6a时1.92±0.31kghm~(-2)a~(-1),7a时1.96±0.21kghm~(-2)a~-1从地上凋落物、细根周转、湿沉降三种不同途径归还林地养分所占的比例来看,地上凋落物中的落叶是归还养分主要途径,年龄在3a、5a、6a、7a时,通过落叶归还的N所占比例分别为74.84%、71.96%、78.58%和75.03%,归还的P所占比例分别为85.93%、80.31%、83.04%和83.23%。

Percents of N immobilization were positively correlated with the litter mass loss, indicating forest floor with easily decomposition litters may have greater potential of N sinks than that with hardly decomposition litters.

在本实验中易分解凋落物具有较高的氮固持百分比,可能说明具有较易分解凋落物的森林表层可能比具有较难分解的凋落物的森林表层具有较大的氮固持潜力。

Development of new analytical techniques using modern instrumentation and digital computers, and the applications of these techniques in areas such as environmental, clinical, and forensic chemistry.

本实验室研究的范围,主要是利用质谱术进行各项研究。即利用气相层析质谱仪,液相层析质谱仪,串联质谱仪(GC/MS/MS;LC/MS/MS)的特性发展应用於环境科学、临床科学、情治科学等微量分析,如环境科学样品泥土中微量残留农药之侦测,及农药分解物结构之鉴定和流布情形之探讨。

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