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The structural and photocatalytic properties of TiO〓 as well as surface acidity were greatly improved by sulfation. SO〓〓/TiO〓 solid superacid with Hammett constant Ho less than -12.14 was prepared by treating the TiO〓 with 1.0mol. L〓 sulfuric acid solution and then calcining at 450℃ for 3h. When compared to unmodified TiO〓, the SO〓〓/TiO〓 superacid catalyst exhibited higher anatase content, smaller crystal size, higher specific surface area, centralized pore size distribution, and the blue-shifted band edge of uv-vis adsorption spectra. Furthermore, the SO〓〓/TiO〓 superacid also showed excellent reaction activity and stability for CH〓Br photocatalytic decomposition even under the moist reaction conditions. The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明:SO〓〓与TiO〓表面的结合为螯合式双配位结构;TiO〓光催化剂表面经H〓SO〓浸渍处理后,提高了表面酸性,改善了催化剂结构和光催化性能,当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时,可制得SO〓〓/TiO〓超强酸催化剂(H〓<-12.14),其结构和光催化活性得到明显改善,与TiO〓相比,SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移,具有优异的光催化氧化活性、稳定性及抗湿性能,光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级,是一种有实际应用前景的高效光催化剂;由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型,认为在SO〓〓/TiO〓超强酸催化剂表面,由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心,其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移,具有可逆吸附水的性能,是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明:SO〓〓与TiO〓表面的结合为螯合式双配位结构;TiO〓光催化剂表面经H〓SO〓浸渍处理后,提高了表面酸性,改善了催化剂结构和光催化性能,当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时,可制得SO〓〓/TiO〓超强酸催化剂(H〓<-12.14),其结构和光催化活性得到明显改善,与TiO〓相比,SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移,具有优异的光催化氧化活性、稳定性及抗湿性能,光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级,是一种有实际应用前景的高效光催化剂;由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型,认为在SO〓〓/TiO〓超强酸催化剂表面,由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心,其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移,具有可逆吸附水的性能,是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

Gradually, the separate sine waves have become visible. The dominant signal, corresponding to a planet with about the same mass as Jupiter but which orbits 55 Cancri A more closely than Mercury orbits the sun, was detected in 1996. Two further sine waves emerged in 2002, corresponding to one planet that has the mass of Saturn and is also orbiting more closely than Mercury, and another with four times the mass of Jupiter that is located in what would be Jupiter's orbit.

逐渐地,&正弦波&曲线出现明显的分离。1996年,科学家探测到了起支配作用的讯号,这种讯号表明发出讯号的行星与木星有着相同的质量,但它围绕恒星&55 Cancri A&运行的距离比水星围绕太阳运行的距离还要小。2002年,另外两个&正弦波&曲线被发现,它们也分别代表两颗行星:一个行星有着土星的质量,围绕恒星的距离也比水星围绕太阳的距离要小;另一个行星有着木星质量的四倍,其位置将会预计在木星的运行轨迹上。

ABSTRACT This thesis is aimming at the synthetic study of Cephalotaxine, and consists of the following three parts: Charpter 1 reviews the isolation, chemical structure identification, biological activities, and synthetic studies of structurally unique antileukemia Cephalotaxus alkaloids.

本论文以三尖杉碱的全合成新方法为研究的核心,共分以下三部分内容:第一章简要地概述了天然三尖杉生物碱的分离、结构及生理活性,三尖杉碱的全合成研究。

With the coaction of gravity and repulsion,nanocrystallines can be separated effectively from liquid phase environment.

在重力和该斥力的共同作用下,纳米晶可以有效地从液相环境中分离出来。

The invention discloses a synthetic using method of smelting high-furnace dust, which comprises the following steps: grinding the high-furnace dust with 1.5-15% zinc; proceeding magnetic cobbing; reclassifying to obtain the refined ferric ore; disposing ore tail through waste acid of titanium dioxide with 15-30% sulphuric acid; transmitting the zinc oxide in the solution at zinc sulfate pattern; separating solid and liquid solution through lime; obtaining refined zinc ore through S2-, CO32-, HCO3- ion; floating the immersed slag through neutral oil.

一种炼铁高炉炉尘资源综合利用的方法,含锌1.5%~15%的高炉炉尘经磨矿、磁选、重选回收铁矿物获得铁精矿,选矿尾矿用含硫酸15%~30%的钛白废酸处理,使其中的氧化锌以硫酸锌的形式转入溶液中,固液分离得出的溶液用石灰中和除铁后,再用S2-、CO32-、HCO3-离子沉锌获得锌精矿,浸出渣用中性油浮选获得炭精矿。该方法将钛白废酸和高炉炉尘结合在一起,使之成为互为所需的原料和试剂,有效地将两种废弃物变成了有价资源,较好解决了环境污染问题,同时又能产生好的经济效益。

Forty-two Gram-positive coccal isolates were acquired from infection cases in Luoyang, Jiyuan, Xuchang and Nanyang of Henan Province, and were analysed by means of 16S rRNA gene sequencing and Vitek-32 automatic identification system respectively.

将从河南洛阳、济源、许昌、南阳等地送检病猪体内分离的42株革兰阳性球菌纯培养后,分别用16S rRNA基因序列比较和Vitek-32全自动细菌鉴定系统进行鉴定。

Because collophanite usually combines with dolomite, and their flotability is similar so that they can not be separated by the conventional flotation method.

由于胶磷矿多含有白云石且两者可浮性相近,因此运用浮选方法一直没能很好地解决胶磷矿中自云石的分离问题。

MobiliTools - MobiliTools aims at providing a Java toolbox of independent but combinable and flexible software modules to support mobility of Java objects/agents, with a clear separation between activity, transport and communication concerns.

MobiliTools旨在为移动Java对象/代理提供一个由独立的、兼容性好的、灵活的软件模块组成的Java工具箱。清晰地分离了活动、传输和通信功能。

A simple, selective and sensitive method was investigated for simultaneous determination of anions (SO2-4, Cl-, NO-3, F-) and cations (Na+, NH+4, K+, Mg2+, Ca2+) by single-column ion-exclusion-cation-exchange chromatography with conductometric detection. DL-malic acid-methanol-water was used as an eluent.

采用单柱离子色谱系统和电导检测的方法,首次以DL-苹果酸-甲醇水溶液为淋洗液,简便、有效地同时分离、检测了溶液中SO2-4、Cl-、NO-3、F-、Na+、NH+4、K+、Mg2+、Ca2+9种离子。

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Singer Leona Lewis and former Led Zeppelin guitarist Jimmy Page emerged as the bus transformed into a grass-covered carnival float, and the pair combined for a rendition of "Whole Lotta Love".

歌手leona刘易斯和前率领的飞艇的吉他手吉米页出现巴士转化为基层所涵盖的嘉年华花车,和一双合并为一移交&整个lotta爱&。

This is Kate, and that's Erin.

这是凯特,那个是爱朗。

Articulate the aims, objectives and key aspects of a strategic business plan.

明确的宗旨,目标和重点战略业务计划。