分子膜

Self-assembled monolayers are thin organic ordered films, which form through spontaneous chemisorption on solid surface.

自组装膜是活性分子通过化学键自发在异相界面上形成的取向、紧密排列的有序单分子膜。

By measuring the equilibrium and cyclic π～A isotherms and dynamic elasticities of octadecylamine monolayers on the subphases of water and CdCl 2 solution, it is showed that Cd 2+ added into the subphase can enhance the condensability of liquid-like monolayer but decrease that of the solid-like monolayer.

通过测定在纯水和CdCl2 溶液亚相上十八胺单分子膜的平衡、循环π～A等温线及其动态弹性，发现在亚相中加入Cd2 +可以使膜的液态相凝聚性增强，固态相凝聚性减弱。

However, by taking advantage of the steric restriction offered by the three ethoxyl groups on the heads of the C8TES molecules, as well as the difference of the chemical activities between the OTS and C8TES molecules, it was possible to construct both the homogeneously and phase-separated mixed C8TES/OTS SAMs by means of the stepwise method.

但是利用C8TES分子头部三个乙氧基所形成的空间位阻以及C8TES和OTS分子之间反应活性的差异，采用分步法可以制备出混合均匀的均相和相分离(Phase-separated)的C8TES／OTS混合自组装单分子膜。

In this paper, the characterization meth-ods on SAMs in recent years by the means of electrochemistry, spectroscopy, micrology and surface wettibility are re-viewed .

本文综述了自组装单分子膜体系的类型和基底表面的处理方法，着重从电化学、谱学、显微学以及表面润湿性等方面综述了近几年来自组装单分子膜的表征方法研究进展，并对其发展前景作了展望。

Membrane affinity quantified by IAM and liposome/buffer systems was a more efficient predicator of α values than hydrophobicity from n-octanol/buffer system. Consequently, not only hydrophobic force but also attractive polar extra-interactions involved in the binding to IAM and liposomal membranes but not in an n-octanol phase, ascribed to the binding process within AM. The binding to ordered lipid membrane in the larger part determined drugs'binding to AM intracellular compositions, and the ordered phospholipid plasma membrane was a potential site for drugs'binding in AM.

脂质体／水系统和磷脂膜色谱所测定的膜亲和性比正辛醇／水系统的疏水性更好的预测巨噬细胞内药物的α值，因此包含在磷脂膜色谱中但并不体现在正辛醇／水系统中药物与磷脂膜之间的额外吸引性极性作用力对药物在细胞内结合有着重要贡献；药物与有序磷脂膜的结合在很大程度上决定着药物与巨噬细胞内成分的结合，有序磷脂分子膜可能是巨噬细胞内部潜在的结合部位。

Monolayers and multilayers of copper tetrakis (12-alkyloxycarbonyl)phthalocyanine (CuC12Pc), CuC12Pc mixed with octadecylammonium and CuC12Pc mixed with arachic acid were prepared by Langmuir-Blodgett technique and their configurations were also studied.

利用LB技术研究了带有4个长碳氢链的酞菁铜化合物(CuC12Pc)的单分子膜及它与十八胺、二十酸的混合LB膜的聚集结构形态。

The research indicated that, the structure inside the pure C8TES SAM was indeed loose and unassembled completely, the molecule density inside the SAM was very low, which would result in an ultra-low surface contact angle, only 20～21°, on the C8TES SAM surface.

我们的研究表明，由于C8TES分子头部三个乙氧基形成的空间(来源：b5e5ABe3C论文网www.abclunwen.com)位阻的影响，C8TESSAM的内部处于一种不完全组装的松散状态，所形成的自组装单分子膜内分子密度偏低，造成C8TES SAM的表面接触角偏低，只有20～21°。

In this research, mixed SAM of HS-(CH2)15-CH3 and HS-(CH2)15-COOH was immobilized on gold substrate through chemical bond, and PEG and PMB were in sequence linked to the –COOH terminal groups on the SAM sureface by EDC/NHS amide coupling. The PMB immobilized surface was applied to study its specific and nonspecific interactions with LPS by ellipsometry and by SPR spectroscopy. The modified surface is characterized by FTIR, XPS, ellipsometry and contact angle measurements.

本研究系利用HS-(CH2)15-CH3及HS-(CH2)15-COOH混合溶液，在金表面形成稳定共价键结之混合自组单分子膜(Self-Assembly Monlayer，SAM)，再将PEG及Polymyxin B分子依序接至SAM表面之-COOH官能基上，利用表面电浆共振(Surface Plasmon Resornance，SPR)仪或椭圆仪，侦测其与LPS分子之特异与非特异性吸附行为。

Two types of SAM coatings, such as FDTS and OTS were applied to the micromachining, the results have revealed that the SAM coatings not only prevent released stiction but also in use stiction.

并对典型的FDTS和OTS分子膜进行了详细的讨论，研究表明，自组装分子膜不仅能有效防止释放粘附，更能防止工作粘附。

Tribological characteristics of OTS self-assembled molecular film were studied by LFM. The effects of sliding velocity and load on frictional force were analyzed.

应用横向力显微镜研究了OTS自组装分子膜的摩擦学性能，主要考察了滑动速率及载荷对OTS自组装分子膜摩擦力的影响。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。