分子层

Two of these protein bands, with a molecular weight of 12 000 Mr and 14 000 Mr, showed immunoreactivity with IgE in the sera from patients with allergy to pollen of Caryota ochlandra. For the pollen extract of Carvota mitis, 30 protein bands were detected in SDS-PAGE, and three of these protein bands, with a molecular weight of 12000, 14000, and 26000 Mr, showed immunoreactivity with IgE in the sera from patients with pollen allergy of Carvota mitis. The 14000 Mr protein was the major allergen. Result from the ion-exchange chromatography indicated that the two pollen allergens (12 000、14000 Mr) from Caryota ochlandra were eluted in the second peak. The major pollen allergen of Carvota mitis was eluted in the forth and fifth peak.

结果 长穗鱼尾葵花粉有30余条蛋白带，其中主要条带有18条，12000和14000 Mr为长穗鱼尾葵花粉特异性变应原；短穗鱼尾葵花粉有30余条蛋白带，其中主要条带有9条，26000、1200和14000 Mr为短穗鱼尾葵花粉特异性变应原，其中14000 Mr为主要变应原；通过离子交换层析方法纯化出长穗鱼尾葵花粉相对分子质量为12000和14000的变应原主要分布在Ⅱ峰中，短穗鱼尾葵花粉相对分子质量为14000阳的主要变应原分布在Ⅴ峰和Ⅵ峰中。

A surface-modified adsorbent is a support bearing at the surface of a chemically bonded "monomolecular" layer of adsorbing groups, which provides fast kinetics of the recovery and elution of the molecules and ions under study.5–9 SPE by use of alkyl-bonded silica gels has been widely applied in the environmental analysis of polyaromatic hydrocarbons, pesticides, substances of biochemical origin and other organic compounds.

表面改性吸附剂是一种载体，它负载在一层化学键合的单分子吸附性官能团的表层，为所研究的分子和离子的回收和洗脱提供了快速动力。使用含烷基的硅胶的SPE技术已经被广泛应用到芳烃聚合物、农药、生物成因物质以及其他有机化合物的环境分析中。

In complex 1,Cucan be described as a four-coordinated square planar geometry.Compound 8 is the sodium salt of plumbagin and exists as ionic compound.Compounds 9-16 are the rare earth complexes of plumbagin with La,Y,Dy,Sm,Gd,Nd,Erand Eu.Compound 17 is binuclear Y complex.18 is mononuclear Ycomplex with plumbagin and another ligand from Plumbago Zeylanica.Compounds 19-21 are the ternary complexes with plumbagin and 2,2\'-bpy and phen as assistant ligand.In 19, the geometry of Cucan be described as five-coordinated distorted square pyramid that exists in a dimer through the weak bonding,and 1-D chain structure is formed by intermolecular hydrogen bonds.

化合物1的单晶结构分析表明1具有四配位平面四边形结构，化合物8是白花丹素的Na盐，以离子化合物形式存在；化合物9～16为白花丹素的La，Y，Dy，Sm，Gd，Nd，Er，Eu的稀土金属配合物；化合物17是白花丹素的双核钇结构；化合物18为白花丹素的单核钇结构，该配合物除了含白花丹素外，还有来自白花丹植物中的另一个单体化合物也参与配位；化合物19～21是以2，2\'-联吡啶和邻菲咯啉等含N配体为辅助配体，具有白花丹素—含N配体—金属离子的三元配合物，化合物19是白花丹素和2，2\'-联吡啶与Cu的配合物，具有五配位的四方锥构型，通过Cu…O弱的成键作用形成二聚体，再通过分子间的氢键作用进一步形成一维链状结构，化合物20和化合物21是白花丹素分别与2，2\'-联吡啶和邻菲咯啉的Zn配合物，都具有六配位八面体构型的双核锌配合物，呈一维链状结构，化合物20中链与链之间的大量氢键将一维链扩展成二维层，分子间的π-π堆积作用进一步形成三维结构。

A compromise between the implicit and explicit models, known as discrete-continuum, cluster-continuum, semicontinuum, orsupermolecule-continuum model, is to include several solvent molecules around the solute into the QM part, but the rest bulk solvent is treated with the continuum theory.

结果表明：(1)，离散—连续组合模型既在从头算水平考虑了溶质分子和第一溶剂化层中溶剂分子间的短程作用，又包含了溶剂效应的长程静电作用；既包括了量子力学的精确性，又利用了连续场的高效性。

Because we found that silane are easy to pile up in course of micro-contact printing.

这是因为矽烷分子在微触印刷过程中容易堆积成多层分子膜。

Based on the introduction of quantum numbers and bonding parameters,a novel molecular topological index ~A~was suggested.

通过引入量子数、键参数，认为分子的性质与其中各原子的电负性、价电子数、成键电子数、价层主量子数及各化学键的键长有关，提出了一种新的分子拓扑指数mAY。

Such one-dimensional chains interconnect via hydrogen bonding and π-π interaction to form an extended undulated sheet-like structure.

经配体桥联的两个金属离子的距离是6.703〓。这样的一维链通过配体的NH部分〓Cl及溶剂分子甲醇相互之间形成的氢键连接扩展成二维波浪状结构。甲醇分子被包容在层间。

On the basis of molecular design, urushiol and tyrosine, with unique chemical structure, were selected as units to fabricate five kinds of stable and functional multilayer films via layer-by-layer self-assembly method.

本论文在对自组装膜的发展历史、自组装技术进行综述的基础上，从分子设计的思想出发，选用具有独特结构和性能的功能分子——漆酚和酪氨酸作为组装基元，以层层自组装技术制备了五种新型的，具有高稳定性的功能多层膜。

The inner reorganization energy and the exothermicity of the reaction are then determined. Closed shell HF SCF calculations have been carried out for the systems Tryptophy1-Tyrosine and Tyrosyl-Tryptophan for different values of R, and the Koopmans^,theorem is invoked to estimate the energy level splitting A.From the obtained A~m~i~n, the values of electron transfer matrix element V~D~A are determined to be 0.96kJ. mol^-^1 and 0.87kJ.mol^-^1 for Tryptophyl-Tyrosine and Tyrosyl- Tryptophan, respectively.

对色氨酰酪氨酸和酪氨酰色氨酸体系进行闭壳层HF自洽场计算，按Koopmans定理计算体系分子轨道分裂能值A，在R约为0处发现了A的极小值，从而获得色氨酰酪氨酸及酪氨酰色氨酸体系分子内电子转移的电子转移矩阵元V~D~A分别为0.96kJ.mol^-^1和0.87kJ.mol^-^1。

Of the eons of geological periods recorded in the stratifications of the earth: of the myriad minute entomological organic existences concealed in cavities of the earth, beneath removable stones, in hives and mounds, of microbes, germs, bacteria, bacilli, spermatozoa: of the incalculable trillions of billions of millions of imperceptible molecules contained by cohesion of molecular affinity in a single pinhead: of the universe of human serum constellated with red and white bodies, themselves universes of void space constellated with other bodies, each, in continuity, its universe of divisible component bodies of which each was again divisible in divisions of redivisible component bodies, dividends and divisors ever diminishing without actual division till, if the progress were carried far enough, nought nowhere was never reached.

349在地球的层理留下记录的太古以来的地质时代。隐藏在大地的洞穴里和能移动的石头底下、蜂巢和土墩子中那无数微小的昆虫类的有机生物：微生物、病菌、细菌、杆菌、精子；凭着分子的亲和之凝聚力而粘在一根针尖上那几万几亿几兆个多不胜数、肉眼看不到的微小颗粒；人类的血浆是一个宇宙，群集着白血球和红血球，每个血球又各自形成一个空虚的宇宙空间，群集着其他球体；各个球体连续性地也是由可分割的构成体形成的宇宙，各个构成体又可以分割成为几个能够进一步分割的构成体。就这样，分子与分母实际上在并未分割的情况下就不断地减少了。如果这个过程延续到一定时候，就永远在任何地方也不会达到零。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。