分子层

The experimental results show that:(1) LB films are uniform and solid, but it is easy to collapse at higher film pressure,(2) Multilayer LB films process sandwich structure and longspace orderliness, and the phenomenon of crystallization in the process of forming 〓 LB films,(3) The thickness of 〓 monolayer is about 50～60〓,(4) During the formation of 〓 multilayers, molecular arrangement is inclinable to the substrate, the angle is about 25°～30°.

采用小角X-射线散射对多层LB膜的结构进行了表征，发现LB膜具有层状结构的特点和长程有序特征，并对多层LB膜中分子排列的取向状态进行了初步推测，与AFM得到的结果一致。

The monosaccharides in LBP-4 identified by GC were xylose , galactose , mannose , Rhamnose , glucose and arabinose with the molar ratio of 4. 45: 1. 20: 1. 0: 0.98: 0.90: 0.85. The content of calcium, magnesium, zinc and iron in LBP-4a were 127. 9070mg·g〓, 32. 3953mg·g〓, 0.3845mg·g〓 and 0.2930mg·g〓, respectively. The content of galacturnic acid in LBP-4a was 55. 45% while the content of protein is 3. 80%. According to IR spectra, it contains -COOH group,-NH- roup,-OH group,-NH〓 group and β-D-glucose. The backbone of sugar residues chain in LBP-4a were contained 1→6 indican bond according to periodate oxidation and the results of β-elimination reaction indicated that the chain of polysaccharides and protein were connected by O-linked chemical bond. The photograph of LBP-4a got by laser scanning confocal microscope and scanning electron microscope showed that the LBP-4a combined both with each other and with itself in its crystalloid. The crystalloid was flake and anisotropic.

由LBP-4a的红外光谱图知：LBP-4a中含有-COOH、-OH和-NH〓或-NH-基团，糖链中含有β-D-吡喃葡萄糖；高碘酸氧化实验知LBP-4a糖链中不具有连二羟基和连三羟基结构的单糖残基：具有连二羟基结构的单糖残基：具有连三羟基结构的单糖残基=57.0：16.2：1，六碳糖残基的连接中含有1→6连接的糖苷键；通过β消去反应证明LBP-4a中多糖链和氨基酸间为-O-型连接；由激光扫描共聚焦显微镜和扫描电镜对LBP-4a结晶观察结果推测：LBP-4a结晶中同时存在分子间和分子内结合的现象，LBP-4a分子相互结合时，并不是无规则的相互缠绕形成无规线团结构，而是形成片层结构，并且LBP-4a结晶可能具有各向异性的性质。

The 28S rDNA molecular phylogenetic trees showed: 1 entoprocts and phylactolaemate ectoprocts constituted a sister group, strenghthening the opinion that entoprocts should be reunited into phylum Bryozoa; 2 the cheilostome gymnolaemates was obviously non-monophyletic; 3 bryozoans itself was polyphyletic beyond any doubt, its main lineages were scattered in different positions of the lophotrochozoan trees; 4 to our great interests, the phylogenetic position of cheilostomes was between the diploblastic and the triploblastic, indicating they may play an important role during the evolution route from the diplobastic to the triploblastic animals.

28S rDNA分子系统树显示，内肛动物和被唇类外肛动物聚在一起并互为姐妹群，支持将内肛动物重新归入苔藓动物门的结论；唇口目裸唇类外肛动物绝非单系发生；苔藓动物本身也不是单系发生的，其主要类群分别位于触手冠担轮动物系统树的不同位置，特别是，唇口目苔藓动物的系统地位介于二胚层动物和其它三胚层动物之间，可能是二胚层动物向三胚层动物演化过程中的一个关键类群。

The Langmuir Blodgett technique was employed to modify the PVC liquid membrane, the LB film of trioctylcetyl ammonium chloroauric acid was deposited on the surface of PVC liquid membrane, and the gold selective electrode with such modification has been fabricated.

1引百 LB膜技术〔''是近年来超分子组装化学中应用最多和相对最成功的分子装配技术，因能较好地在许多固体表面按设计方式组装空间有序的超分子体系，特别是其器件研制最基本的实验手段之一卿，由于LB膜修饰层有序，高密，超薄，能从根本上改进电极体系及其反应过程的性质和行为

In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions（0-D chain）; complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物，并用X-射线单晶结构分析方法确定了晶体结构，分别为： [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构；配合物2借助水分子形成一维链状结构；配合物3、4、5、6是以H4btc为第一配体、phen为第二配体，通过水热法合成的配合物，其中，Co2+、Ni2+、Cu2+为中心离子；配合物3中的二价钴离子具有相同的配位环境，不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境，在配合物4中，一维链通过H4btc上的羧基形成一个二维层结构；配合物5、6是借助H4btc上的羧基形成的一维链状结构；配合物7、8属于异质同晶结构，它们的分子通过分子间氢键形成三维网状结构，H4btc上的羧基失去2个质子，作为一个二价负离子起到电荷平衡作用。

The research of polymer/layered silicate nanocomposite was introduced detailedly, including the classify, property and the latest research advance. On the basis of consulting the document and the exploratory experiment, the experimental method which first creative preparing poly (acrylonitrile-vinyl acetate)/raontmorillonite nanocomposite by emulsion intercalation copolymerization was established; the structure and property of polyacrylonitrle different molecule weight with inorganic mineral super fine nanocomposite was reseached. The reaction principle of PMMA by photo-initution was explored. The mixture principle with productor condition, property of PE/Clay nanocomposite milt insert was seal prived. By PS/Clay nanocomposite munufacture, the monomer ins-polymerization and polymerial solution was proved.

在查阅文献和探索性实验的基础上，确定采用乳液原位插层聚合方法首先创制了聚/蒙脱土纳米复合材料，利用正交实验得出了最佳实验条件，通过X射线衍射和红外光谱对纳米复合材料的结构进行表征，研究了复合材料的溶解性能，并测定了其溶液的绝对粘度；研究了不同相对分子质量的聚丙烯腈与不同的无机矿物超细粉复合材料的结构与性能；探讨了在蒙脱土中光引发聚甲基丙烯酸甲酯的反应机理；通过聚乙烯与粘土的纳米复合材料制备，探讨了热塑性树脂熔融插层复合机理与最佳工艺条件和复合材料性能关系；通过聚苯乙烯与蒙脱土纳米复合材料制备，验证了单体原位聚合插层和聚合物溶液插层机理。

Comparing with general composite materials, intercalation composite material is formed by intercalating one or more layers either organic molecules or polymers into inorganic materials with stratum shape, its mechanical properties could be modified markedly.

插层复合材料不同于传统的材料，它是由一层或多层有机分子或聚合物插入层状无机物形成的，复合后不仅可以提高力学性能还能获得许多功能特性。

This kind of general structural intercalation complex materials have three obvious characteristics: i Conditions of intercalation reaction are wild in room temperature, water or ethanol solution usually, ii we can process molecule design of host for increasing selectivity to guest molecules in order to prepare general structural intercalation complex materials, iii we can obtain all kinds of applied purpose complex materials by intercalating different functional guests.

这类特殊结构的复合材料具有三个显著特点：第1，制备条件温和，通常在室温、水或醇等溶液中进行；第2，通过对主体分子的设计，提高对客体分子的选择性，可以得到预先设计分子结构的复合材料；第3，通过对一些功能性客体分子进行插层组装，可以得到具有光、电、磁等结构新颖的复合材料。

Then the surface of the star polymer was intramolecularly crosslinked using octa(3-azidopropyl)polyhedral oligomeric silsesquioxane, POSS-(N_3)_8,as the inorganic multifunctional crosslinker at high dilution concentration via click chemistry,forming a novel POSS/polymer hybrid nanostructure.Thermogravimetric analysis shows that after surface crosslinking, the thermostability of the core crosslinked PS can be remarkably improved.In the second work,we synthesized of a novel polymer with quatrefoil-shaped topology.

接着，我们合成了一种结构规整的含八个叠氮功能团的无机分子—多面低聚倍半硅氧烷，以其为交联剂，我们通过Click反应在即稀浓度下实现了前驱体星型聚合物的分子内表面交联，得到了外层为无机分子交联，内层为有机高分子的星状高分子，这种新型的星状聚合物表现出了优良的热稳定性能。

Results indicate that the observed salt fluxes under the two wind conditions show a marginal difference. Under the steady wind condition, a DBL with a constant thickness of 3.5 cm is observed right above the deposited sediment. The molecular diffusion is found to be the dominant mechanism for salt transport within the DBL. The latter can suppress the hydrodynamic enhancement on the exchange of substances between deposited sediments and overlying water.

研究结果表明，在稳定风场条件下，沉积物－水界面处存在厚度约3.5cm的扩散边界层，有风条件下的界面盐分交换通量略大于无风时的通量；分子扩散是边界层内盐分运移的主要机制，扩散边界层对沉积物盐分释放具有阻滞作用，并且边界层越厚，阻滞效应越显著。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失