分子团

It consists of a chromophore and an apoprotein, and the former has the activity to attack DNA, whereas the latter plays the role in protecting chromophore.

其分子由一个酸性的辅基蛋白和一个发色团结合而成，发色团是LDM的主要活性部分，起着直接断裂DNA的作用，而辅基蛋白的主要作用是保护发色团。

The establishment and relaxation processes of the transient gratings, which are formed by two recording 514nm beams with different polarization directions, SS, PP, SP and ±45℃, are investigated. Using the weak absorption of the chromophores at 632. 8nm and the positive dichroism of the chromophores molecules, a kind of bi-photonic transient gratings, owing to the periodic distribution of Trans and Cis isomers, is established first time in azo-dye doped polymeric bulk sample.

实验考察了两束514nm的写入光在不同偏振情况下（SS，PP，SP和±45），在样品中形成的瞬态栅的建立和弛豫情况；利用偶氮生色团在632.8nm波段的微弱吸收和生色团分子的正二向色性，首次在块状偶氮聚合物材料中形成一种基于生色团反式和顺式异构体密度分布的双色光瞬态栅；利用瞬态栅的快速建立和弛豫，考察了其在衍射型全光开关方面的潜在应用。

Many multi chromophoric organic dyes with covalent linkage between the chromophores, one of which can act as a triplet acceptor of the excess energy, have been synthesized and studied.

本文综述近几年多发色团染料分子内能量传递领域的研究概况，重点介绍了分子内能量传递对组装型多发色团有机染料光稳定性影响的研究进展。

Absorption spectra indicate that there is little or no interaction between chromphores in the ground state. However, the fluorescence emission of oxadiazole and triphenylamine moieties are almost quenched, which shows that in the excited ground state there exists very effective intramolecular singlet-singlet energy transfer .

研究发现，这些多发色团化合物在基态发色团之间没有作用或作用很小，而其中噁二唑和三苯基胺单元的荧光被严重的猝灭，这说明在激发态下，萘酰亚胺发色团与噁二唑、三苯胺功能团之间发生了分子内单线态—单线态能量转移。

Absorption spectra indicate that there is little or no interaction between chromphores in the ground state. However, the fluorescence emission of oxadiazole and triphenylamine moieties are almost quenched, which shows that in the excited ground state there exists very effective intermolecular singlet-singlet energy transfer.

研究发现，这些多发色团化合物在基态发色团之间没有作用或作用很小，而其中恶二唑和三苯基胺单元的荧光被严重的猝灭，这说明在激发态下，萘酰亚胺发色团与恶二唑、三苯胺功能团之间发生了分子内单线态－单线态能量转移。

Considering the low morphological stability of dye-doped polymer thin film and based on the above multi-chromophoric organic small molecules, six novel copolymers have been synthesized by the co-polymerization, in which there are three functions: 1, 8-naphthalimide as emitting moiety, oxadiazole as electron transporting moiety, and N-vinyl carbazole as hole transporting moiety.

考虑到有机小分子掺杂到聚合物膜中低的形态稳定性，我们在上面多发色团有机小分子研究的基础上，通过自由基引发共聚合成了六个新型的共聚物。在该类共聚物的侧链上含有三个功能团：1，8-萘酰亚胺单元、噁二唑单元和N-乙烯基咔唑单元。

The shape and size of the cluster can be adjusted.πconjugate aryl alkynyl thio ethers containing thiomethyl in the end are important compounds. We can use such compounds to get some functional molecules that have good assemblied effect, especially in controlling the shape and the size of the cluster.

设计并合成一些形态多样的π共轭系多-SCH_3功能基的芳炔硫醚类分子对获得一些具有良好组装效果，尤其是能够控制团簇形态或控制团簇尺度有用的功能分子有着重要的理论和实际意义。

As protein of bacteria and fungi is with negative charge. The antibacterial functional mass, grafted by assembling chemical method, is positive electric polarity. Thus, the antibacterial functional mass is absorbed to the cell of microorganism by the principle of unlike charges attracting. This will influence the normal breath and metabolism of the cell and causes the cell membrane to rupture. In this way, its product realizes the function of being antibacterial, antiviral, and mildew-proof

分子组装抗菌技术主要是通过化学接枝的方法，将精选的抗菌功能团组装到基体树脂的分子链上，利用抗菌功能团的正电性与细菌的带负电蛋白质的异性相吸原理，将微生物细胞吸附，并影响细胞的正常呼吸和代谢功能，造成细胞的破裂，达到抗菌的目的，从而使产品达到了真正意义上的持久抗菌。

Series of crosslinked polymers containing POSS were synthesized in this thesis. The main contents include three parts as follows:(1) The preparation of different POSS molecules containing multiple functionalgroups and the development of crosslinked polymers containing POSS were reviewed in detail.

2合成了一种多功能团的POSS分子(T_8H_8)及四种不同长度的双烯功能团有机小分子，这些有机小分子可以通过硅氢化反应与POSS形成交联聚合物，在聚合物中作为连接链将POSS分子连接起来。

BY molecular dynamic simulation on the self-diffusion properties of Cu nanoclusters, we found the diffusion coefficients of copper nanoclusters Nc8949 increase with the increasing temperature and increase with reciprocals of their radii approximately at

本文通过分子动力学模拟研究了纳米铜团簇的自扩散性质，结果表明Nc8949铜团簇自扩散系数随温度的升高而增大，在温度为1000K时纳米铜团簇的扩散系数随团簇半径的倒数基本呈线性增加。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。