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In this paper the system with intermolecular reaction and intramolecular reaction was designed.

设计了含有分子内反应和分子间反应的聚合体系,这是一对竞争反应,竞争的结果可达到一定的平衡,使无法控制的凝胶化过程得以控制,从而合成了具有交联结构的大分子。

The phase data of different rare earth complexes are different, which is directly relative to the intramolecular relaxation processes.

在此波段内不同稀土DBM配合物的位相不同,位相的差别与它们的分子内弛豫过程直接相关。

This is a reasonable method to investigate real polymer systems. The semiflexible model can capture the main features of aPS, and can semi-quantitatively describe the intermolecular correlation function, intramolecular correlation function, solubility parameters and x-ray scattering intensity for real aPS melt.

该模型能够抓住复杂的无规聚苯乙烯熔体的主要结构信息,可以半定量的描述各种条件下无规聚苯乙烯熔体的分子间相关函数、分子内相关函数、溶解度参数和x-光散射强度等结构和热力学性质,并得到了MD数据和实验数据的支持。

The members of the same genus and family were grouped together. The polyogenetic relationships of 8 families were Pyrgomorphidae →Chrotogonidae→Pamphagidae→Oedipodidae→Acrididae→Arcypteridae→Gomphoceridae→Cantantopidae.Pygomorphidae had closer relationships with Chrotogonidae as well as being the most ancestral group. Arcypteridae and Gomphoceridae were the sister groups and had closer relationships with most evolutionary Catantopidae. Tridactylidae was divided firstly as a suborder,which differs from the recent taxonomy distinctly. Haglidae and Gryllidae were grouped into suborder Ensifera, Tetrigidae and 8 families of Acridoidea were grouped into suborder Caelifera, as same as recent taxonomy.

分子系统树表明:科内的属和属内的种均优先聚在一起;蝗总科8科的起源关系为:锥头蝗科→瘤锥蝗科→癞蝗科→斑翅蝗科→剑角蝗科→网翅蝗科和槌角蝗科→斑腿蝗科;锥头蝗科与瘤锥蝗科关系较近,是蝗总科内最原始的类群;槌角蝗科和网翅蝗科互为姐妹群,与最进化的斑腿蝗科关系较近;蚤蝼科为独立的一支,最先分出,似为一个亚目,与现用的分类系统有明显差别;哈螽科和蟋蟀科聚在一起为剑瓣亚目,蚱科和蝗总科的8科组成短瓣亚目,同现用的分类系统。

FT-Raman, normal Raman spectra of artemisinin in solid state and surface-enhanced Raman scattering spectra of 1 ?10-5 mol/L artemisinin aqueous solution were recorded. 1756 Cm-1 hexat. lactonic ring vibration which was shown strong in FT-Raman and normal Raman spectra disappeared in SERS spectra. This phenomenon appeared to result from the broken of lactonic ring.

本文对固态青蒿素的FT-Raman光谱和普通Raman光谱以及低浓度(1×10^-^5mol/L)青蒿素水溶液的表面增强Raman散射光谱进行了检测,着重观察了1756cm^-^1六元内酯环振动谱带,发现其在FT-Raman和普通Raman光谱中表现为强振动,而在SERS光谱中此振动谱带消失,说明分子内酯环发生了破裂。

Recent single-molecular experiments have shown that it is different from other myosins, it\'s an efficient processive motor.

非传统的肌球蛋白Ⅴ是具有运动功能的蛋白,这种马达负责细胞内的小器官和小囊泡的输运,分子实验已表明肌球蛋白Ⅴ不同于其它肌球蛋白,是一种有效的进行性分子马达,它异常小却异常强大,能输运比自己重千倍的物质。

Accordingly, aromatic compounds can be divided into three groups and a delocalized π system itself is always destabilized, the dependence of aromatic ring current upon the CT was reveled, and ring rigidity has been defined as a new aromatic index.

据此,我们提出了芳环化合物新的分类准则,揭示了芳香环流起因的必要条件,定义环的刚度为芳香性一个新判据。发现,分子内基团间的局部作用同它们对分子整体性能的影响是完全相反的。

Cellulose acetate butyrate,which is widely applied as coatings additive, is synthesized in the heterogeneous system. The activation is required because of the strong hydrogen intramolecular and intermolecular bondings and the regulation of the crystalline region in cellulose microfibrils.

中文摘要纤维素醋酸丁酸酯(Cellulose acetate butyrate是一种广泛应用于涂料工业的添加剂,由于纤维素具有分子内与分子间强氢键作用以及纤维素纤维的局部规整的结晶序列等特征,一般纤维素在酯化反应前都需要进行预活化处理,工业上纤维素醋酸丁酸酯的合成方法一般都在非均相体系中进行的。

The activation energy of B ring elementary reaction is between 16~20kJ/mol.

从IRC结果以及对过渡态结构的电子密度拓扑学分析结果可以确定,羟基自由基在反应过程之中抽取了黄酮类化合物A环上未参与分子内氢键结构的酚羟基上的氢原子形成水分子及稳定性更高的半醌式大环自由基,在整个过程之中羟基自由基从反应物一侧进攻并逐渐发生扭转,直至形成一个进平面结构的过渡态结构,这与上一章关于黄酮类化合物B环的研究结果基本一致。

In chapter four, the REMPI-TOF-MS of Carbon disulfide is investigated in the range of 283-289nm.

第四章主要报道了二硫化碳分子在283-289nm波长范围内的共振增强多光子电离-解离过程的实验研究结果和分析结果,主要内容有:(1)实验测定了二硫化碳分子的共振增强多光子电离的TOF质一谱和分质量的REMpl谱。

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