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凝胶剂

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Hybrid mesoporous molecular sieve materials with hexagonal mesoporous structure and covalent bonded polyoxometalates were synthesized based on tetraethoxysilane anti lacunary polyoxometalate, SiW11, via sol-gel method in the presence of triblock copolymers P123 as the structure-directing agent. The influences of molar ratio of inorganic precursors and aging temperature on the structure and the loadings of SiW11 in the hybrid materials were investigated. Some reaction details in the synthesis were revealed.

用嵌段共聚物P123为模板剂,正硅酸乙酯和缺位结构的多金属氧酸盐SiW11为无机前驱体,由溶胶-凝胶法合成了具有六方结构和SiW11共价键联的介孔分子筛杂化材料SiW11/SBA-15,着重考察了无机前驱的配比和老化温度对杂化材料结构及SiW11负载量的影响。

GPC analysesand particle size results indicated that using PFAMA macro-CTA as the first block wasbetter than using the PBMA RAFT agent with respect to the colloidal stability and thenarrow molecular weight distribution of the F-copolymers latices.

改变合成顺序,首先在本体中合成PFAMA大分子链转移剂,然后在细乳液体系中进行BMA的聚合,凝胶渗透色谱和粒径分析表明:可以得到稳定的细乳液和分子量分布窄的含氟嵌段共聚物PFAMA-b-PBMA。

The phenomenon can see from the SEM that,after the exciting of acid,steel slag process to secondary hydration together with cement clinker,combining to a great deal of meshy gelatin.

从SEM照片看出,钢渣在酸性激发剂作用下,与熟料水化产物发生二次水化,相互联结在一起,形成大量的网状结构的絮状凝胶。

The isonucleus-allocytoplasmic materials ms-Xinong 1376,-Xinong 1376, and ms-Xinong 1376 were used to investigate the protein expression profile in mononucleated anaphase anthers of wheat (Triticum aestivum L.) after silver staining and analysis by PDQuest software. About 320 to 350 distinct protein spots were detected reproducibly.

为了研究小麦雄性不育蛋白表达机制,以具有异质同核的3个亲本:即遗传型不育系ms-西农1376、对应的保持系-西农1376和生理型(化学杀雄剂SQ-1诱导)雄性不育系ms-西农1376为材料,利用IEF/SDS-PAGE凝胶电泳技术,对发育到单核后期的花药全蛋白特异性进行了比较分析,得到320~350个清晰的蛋白点。

The discovery that Fomblin HC Classic perfluoropolyethers form extremely fine and stable dispersions in glycerin11,12,13 represents a major step in simplifying their incorporation into creams and lotions; in obtaining more stable monophase translucent gels and shampoos; and in the preparation of multiple emulsions.

当Fomblin HC Classic全氟聚醚在甘油中越均匀稳定地分散时,越有利于它们与乳霜和洗剂混合;越有利于得到稳定均相的透明凝胶和洗发液;越有利于制备复合乳液。

Soil conditioning agent; utilization of black liquor; modified lignin; aluminum toxicity; ligand; sulfonated lignin; alkaline -oxygen treated lignin; gel filtration chromatography; muconic structure.

农业科技,农业基础科学,土壤学土壤改良剂;黑液利用;改性木素;磺化木素;氧碱处理木素;铝毒;螯合剂;凝胶过滤色谱;己二烯二酸结构

The in-situ epoxidation and in-situ grafting of unstaturated rubber,in-situ synthetic poly-unstaturated carboxylate,surface in-situ chemical treating of rubber filler,montmorillonite in-situ plugging plyer/peeling,in-situ preparing SiO2 by sol-gel technology were presented.The modification method and effect of rubber were addressed,and the practic application possibility of modificated rubber to rubber goods was researched.

介绍了不饱和橡胶的原位环氧化和原位接枝、原位合成聚不饱和羧酸盐、橡胶填充剂表面原位化学处理、蒙脱土原位插层/剥离、溶胶-凝胶法原位生成SiO2等原位反应合成技术在橡胶加工和改性方面的应用研究工作,讨论了各种改性橡胶方法的特点以及改性效果,并探讨了改性橡胶材料在各种橡胶制品行业实际应用的可能性。

The objective in this study is to reduce the aggregate phenomenon of SiO2-sol and improve the storage/release thermal properties of the composite phase change materials. Silicane coupling agent was used to modify the SiO2sol during preparing CPCMs by sol-gel method.

为改善溶胶-凝胶法复合相变材料过程中硅溶胶易团聚的问题,采用硅烷偶联剂对SiO2溶胶进行改性,提升复合相变材料的热储、放性能。

The mian works are as follows:(1)By coprecipitation technique and coprecipitation- gel technique the nano zirconia powder was produced, factors affecting the properties of nano zirconia powder such as pH and the content of stabilizator are analyzed;(2)By the new pressless sintering process, the nano zirconia ceramic was produced, factors which can affecting the properties of nano zirconia sinter body such as moulding press and the sinter temperature are analyzed;(3)By the microtherm pressless sintering process, the nano copper added functional zirconia ceramic composite was produced, microscopic dimensionality and electric properties of such sinter body and the factors affecting such sinter body are analyzed;(4)By the self-invented "external albumen coating" technique the zirconia powder was successfully coated by carbon in the corresponding sinter body, which can help solve the traditional aggregation problem to some degree;(5)Based on analyze the characteristics in the nano powder sinter process, the "three-ball sinter model" was proposed, for the relationship between the relative density and porosity of sinter body, by mathematical fitting, such model was successfully verified.

本研究比较系统地研究了纳米氧化锆陶瓷的合成与成型机理,特别是讨论了纳米氧化锆陶瓷的稳定性,为防止纳米颗粒在外场作用下的团聚和长大提供了理论基础和实验数据,具体工作有以下几方面:(1)采用共沉淀法和共沉淀-凝胶法制备了纳米氧化锆粉体,并分析了pH值和稳定剂含量对粉体性能的影响;(2)采用新型无压烧结工艺制备了纳米氧化锆陶瓷,并分析了成型压力和烧结温度对烧结体性能的影响;(3)采用低温无压烧结工艺制备出添加纳米铜的功能性纳米氧化锆复合陶瓷,并分析了烧结体的微观尺度和电学性能的变化以及影响因素;(4)通过自创的&鸡蛋清外敷法&在真空镀膜台上对纳米氧化锆粉体进行包敷碳颗粒的表面处理,并采用真空烧结工艺制得相应烧结体,初步开始解决陶瓷烧结过程中团聚长大这一传统难题;(5)通过分析纳米颗粒在制备烧结体过程中的实际特点,提出了&三球烧结数学模型&,通过引入坯体相对密度和孔隙率的相对关系分析并通过自行编写的数学拟合软件,验证了这一数学模型。

A series of tri-block copolymers of styrene/tetradecyl methyl acrylate/3-methacryloxyl-propyl thimethoxyl silane was synthesized by atom transfer radical polymerization. The structures of those copolymers were characterized by means of gel permeation chromatography, infrared spectrum, and nuclear magnetic resonance (1H-NMR). Effect of tri-block copolymers on the mechanical properties of glass fiber/polypropylene composites was also investigated.

采用原子转移自由基聚合法合成了一系列新的三嵌段共聚物大分子偶联剂聚苯乙烯-b-聚甲基丙烯酸十四酯-b-聚3-甲基丙烯酰氧基丙基三甲氧基硅烷,通过凝胶渗透色谱、红外光谱和核磁共振(1H-NMR)证实了其结构,并研究了其对玻璃纤维/聚丙烯复合材料力学性能的影响。

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It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发,分析对称连杆曲线上鲍尔点的产生条件,提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品,年生产总值3000万美元,产品价廉物美、选料上乘、质量保证,深受国内外客户的青睐

The eˉtiology of hemospermia is complicate,but almost of hemospermia are benign.

血精的原因很,以良性病变为主。