再碳化

Novel sulfonic acid and carbon chains of mixed-mode packing materials were synthesized through sulfonating polymer-encapsulated zirconia covered by a porous copolymer of olefinic hydrocarbon and divinylbenzene on its surface.

通过共聚交联方法将长链碳烯-苯乙烯包覆到锆胶表面上，得到聚合物包覆固定相，再对该填料进行磺化引入离子官能团到聚合物表面，得到混合型固定相。

All compounds are synthesized starting from the acylation reaction of gallic acid with L-glutamine to form the basic scaffold, followed by the cyclic reaction in acetic anhydride and the key intermediate cyclic anhydride (compound 4) was obtained. The intermediate compound is condensed with different amino acids or primary amines, and produces the target compounds.

本研究以L－谷氨酸为基本骨架，与甲醚化保护的没食子酸缩合后，经过酰化、环合反应得到关键中间体环状酸酐（化合物4），再经胺解反应合成目标化合物，其化学结构经过红外光谱、电喷雾质谱和核磁共振谱（氢谱、碳谱、碳氢异核多键相关谱）确证。

The carbon molecules combine to form an equilateral triangle, the most ideal and stable type of structure.

这电离罩是利用高电压使碳分子电离化，再用分子工程技术加压降温，重整碳晶体的结构。

Dihydrojasmone was synthesized from2-hexyl-5-methyl-1,2-oxaborolane,prepared frommethyl vinyl ketone and hexene,via the homologationwith 〓 followed by PCC oxidation and intra-molecular condensation.In stead of the oxidation ofthe C-B bond of 1,2-oxaborolane,fluoride inducedhalogenation of 2-alkoxy-1,2-oxaborolane was found togive 3-halopropanol.

硼氢化甲基乙烯基酮和已烯得到的2-已基-5-甲基-1，2-氧硼杂环戊烷与〓反应，再经PCC氧化，分子内缩合得到二氢茉莉酮。1，2-氧硼杂环戊烷的C-B键除氧化断裂之外，也能够在〓或KF作用下卤化断裂成碳卤键。

Tetrachloroterephthalic acid was prepared by chlorinating terephthalic acid, oleumsolvent and iodine catalyst. Tetrachloroterephthalic acid was acylated by sulphurous oxychloride in the presence of DMF to form tetrachloroterephthaloyl chloride. The acyl chloride product was fluorinated by potassium fluoride and esterified by methanol to synthesize dimethyl tetrafluoroterephthalate. The ester was reduced with potassium borohydride and lithium chloride to give tetrafluoroterephthalyl alcohol. The above product was bromated in the hydrobromic acid to obtain 4-bromomethyl-2,3,5,6-tetrafluoro-benzene methanol. 4-Methyl-2,3,5,-6-tetrafluorobenzene ethanol was obtained by reducing the bromide with magnesium. In the exist of DCC and DMAP, tefluthrin was got by the condensation reaction between 4-methyl-2,3,5,6-tetrafluoro-benzene methanol and-(1RS,3RS)- 3-(2- chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropanecar-boxylate acid.

对苯二甲酸与氯气在碘存在下以发烟硫酸为溶剂进行氯化制备四氯对苯二甲酸；再以DMF为催化剂与二氯亚砜反应生成四氯对苯二甲酰氯；以氟化钾为氟化剂，环丁砜为溶剂置换氟化，再与甲醇酯化得到四氟对苯二甲酸甲酯；以KBH4-LiCl为还原剂二甲醚为溶剂反应制得四氟对苯二甲基苄醇；以氯苯为溶剂在溴化氢溶液中溴化得到溴化产物；在乙醇溶液中经镁粉还原得到4-甲基-2，3，5，6-四氟苄醇；甲基苄醇与功夫酸在催化剂二环己基碳二亚胺和4-二甲氨基吡啶作用下缩合得到七氟菊酯，总收率达43.6%。

On the other hand, reaction of lactol derived from D-mannose and D-glucose with Grinard reagent of propargyl bromide also proceed both withanti stereoselectivity and with high anti-specificity.

链增长及目标分子中的碳碳双键是由一步Wittig反应和一步末端炔的烷基化再部分氢化而获得，双键构型-选择性可达到95％以上。

Chiral centers of C5 and C8 are directly constructed in the key step of the diastereoselective propargylation from D--tartrate. The methylation and subsequent methoxycarbonylation result in desymmetrization of the terminal dialkynes. The α,β-unsaturated δ-lactone is synthesized after partial hydrogenation and lactonization.

由非天然酒石酸出发，利用双向非对映选择性的炔丙基化反应，在一步反应中同时构建C5和C8手性中心；然后通过末端炔基的甲基化、甲酯基化，延长碳链并对分子去对称化；内酯化得到关键中间体α，β-不饱和六元内酯，再经多步反应转化得到8-epi--Boronolide。

CNTs were first pre-treated using acid solution (HNO3) to obtain CNTs functionalized with carboxylic groups. Subsequently, the stearyl alcohol was grafted onto CNT with the assistance of dehydrating agent, N,N'-dicyclohexyl-carbodiimide. Excellent dispersion in organic solvents such as acetone, THF, and chloroform was found for the modified CNTs (CNT-C18). In addition, the PBS/CNTs nanocomposites were then prepared through simple melt-blending. Mechanical properties, thermal behavior, conductivity of resultant polymer/CNT composites were investigated. The results show that excellent dispersion of nanotubes in the PBS matrices was achieved.

为了增加多壁奈米碳管在复合材料中的分散性，将碳管表面进行化学修饰，首先将多壁奈米碳管浸入HNO3溶液中，进行酸化，使碳管表面带有羧酸的官能基，然后再加入十八烷醇，在温和的条件下，藉由N，N'-二环己基碳二亚胺(N，N'-dicyclohexyl- carbodiimide，DCC)脱水剂脱水，使碳管和十八烷醇之间产生酯基的化学键结，改质后的碳管可以分散在acetone、THF、chloroform…等有机溶剂中，结果显示成功的利用DCC脱水剂完成碳管的改质。

The present invention features that one kind of aerobiota is first used to ferment glucose, saccharified starch liquid, enzymolyzed cellulose liquid and other carbohydrate to produce glycerin, and one other kind of anerobic microbe is then used to convert glycerin into propylene glycol.

本发明的特征在于首先使用一种好氧微生物菌种发酵如葡萄糖、淀粉糖化液、纤维素酶解液等碳水化合物产生甘油，进而再通过另一种厌氧微生物菌种将甘油转化为1，3－丙二醇，其中第一步发酵所得到的发酵液可离心或过滤除去菌体，清液可直接进入第二步发酵或者经浓缩后作为第二步发酵的批式流加液，部分菌体可在连续发酵时循环使用；第一步发酵液也可不离心经灭菌后再进行第二步发酵。

This novel reagent was treated with LDA to produce polystyrene-supported a-seleno carbanions, which reacted with alkyl halides and epoxides, followed by stereospecific selenoxide syn-elimination to give olefins and allylic alcohols respectively.

它与LDA反应形成α—硒基稳定的碳负离子，再与卤代烃或环氧化合物发生α—烷基化反应，烷基化后的树脂可以在30%的双氧水中进行氧化-消除，以良好产率和较高纯度合成了取代烯烃或烯丙基醇。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新