再制备

There are two kinds of synthetic pathway for KIP, the first route is to isomerize α-isophorone into a β-isophorone, and then oxidize β-isophorone into the product; the second route is direct oxidation of α-iso-Isophorone into the product.

目前有两种合成途径，第一条路线为α-异佛尔酮异构化为β-异佛尔酮，然后再氧化β-异佛尔酮制得KIP；第二条路线为直接氧化α-异佛尔酮制备。

In the second section, with ketone and hydroxylamine hydrochloride as the starting materials, 3-aminopropanol is prepared via three steps including reaction of ketone and hydroxylamine hydrochloride , condensation of ketoxime and acrylonitrile, and hydrogenation cracking of condensation product.

第二是3-氨基丙醇的制备，由酮肟丙烯睛缩合物催化氢化裂解制得：即先以酮、盐酸羟胺为起始原料在碱性条件下合成酮肟，再与丙烯腈反应生成酮肟丙烯腈缩合物后经催化氢化裂解制得3-氨基丙醇。

To avoid the low yield in direct hydrosilylation addition of allyamine, 1, 1, 1, 3, 3, 3-hexamethyldisilazane is used to protect the amino groups, and the protective groups are removed easily after hydrosilylation addition, then the high yield of ladderlike copolymethyl-aminpropylsilsesquioxane was obtained.

为了克服将烯丙基胺直接与聚氢基甲基倍半硅氧烷进行硅氢加成反应接枝效率低的缺点，探索用六甲基二硅氮烷对烯丙基胺预保护，硅氢加成反应后再脱保护，从而以较高产率制备了含胺丙基、甲基的反应性梯形共聚倍半硅氧烷。

Methods: The string inserting method according to Longa＇s report was used to induce the model of rats with focal cerebral ischemia/reperfusion.

采用Longa报道的线栓法制备大鼠局灶性脑缺血-再灌注模型。

Schiff base derived from p-hydroxybenzaldehyde and p-aminobenzoic acid was prepared by solid-state reaction at supersonic speed airflow and low-heating. Lophophora shape Cu complexes was prepared from the Schiff base and copper acetate and through adding sodium dodecyl sulfate. The structural composition of complexes was confirmed by FTIR and elemental analysis.

利用超音速气流低热固相法合成了对羟基苯甲醛缩对氨基苯甲酸Schiff碱配体，再以该配体和乙酸铜为原料，通过添加十二烷基硫酸钠的方式制备出了晶形规整的仙人球型配合物，利用元素分析和红外等现代测试手段确定了配合物的结构组成。

A series of maleopimaric acid polyester amino resins were made from maleo￣pimaric acid polyesters crosslinked by etherified melamine formaldehyde resins.

以马来海松酸和线性小分子二醇为原料，合成马来海松酸聚酯多元醇，再用氨基树脂交联，制备马来海松酸聚酯氨基树脂。

By combining resolution and protection of DBSPINOL with menthyl chloroformate, the enantiopure SPINOL and other 4,4'-derivatives have been synthesized effectively via (1S)--4,4'-dibromo-l,r-spirobiindane-7,7'-diyl bis-menthyl carbonate with n-BuLi following reacting with electrophiles of I2, MeI, CO2 and water.

在制备其它衍生物反应中，薄荷醇碳酸酯成为羟基的保护基，DBSPINOL碳酸酯用正丁基锂处理后，再和亲电试剂作用合成了其它4，4'位二碘代、二甲基取代和二羧基取代SPINOL新化合物。

Using the chemical reaction route selection method proposed by the authors, a reaction route of using commercial methylglyoxal as the starting material to produce Furaneol was chosen.

今采用作者提出的化学反应路径选择因子对呋喃酮的合成方法进行计算比较，确定了以丙酮醛为原料，通过偶联反应合成中间体苏式3，4-二羟基-2，5-己二酮，再由成环反应制备产物呋喃酮的合成路线。

Results showed that the kinetics of photocatalytic degradation of ethylene by TiO2/ACF desoposited Pt in the simulated cold storage environment for horticultural products could be described using the pseudo first-order equation. The prepared TiO2/ACF-Pt, in the process of which Pt was initially deposited on the surface of ACF and then TiO2 was coated, would promote the activity of ethylene decomposing. When ion sputtering time was 60 seconds (Pt/Ti atomic concentration ratio was 0.112), the apparent rate constant of the reaction of TiO2/ACF-Pt was 1.16 times as much as that of TiO2/ACF. The micrographic structure of ACF was not damaged and an excessive porous structure, which was contributive to absorbing the diluted ethylene, was obtained by the way of ion sputtering Pt.

结果表明：在模拟园艺产品冷藏环境中，TiO2 /ACF-Pt光催化降解乙烯的动力学可用表观一级速率方程来描述；ACF表面先溅射沉积Pt，再进行TiO2附着方案，能提高降解乙烯的能力，当溅射时间为60 s（Pt/Ti原子浓度比为0.112）时，表观一级速率常数是未溅射Pt的1.16倍；TiO2/ACF-Pt的制备方法，对ACF形貌结构没有破坏，并能得到有利于对微量乙烯的吸附的多孔结构。

According to the characteristic of silver nanoparticles, their uniform dispersion in reaction media was obtained by surface modification, ultrasonic radiation and the select of emulsion, and then emulsion polymerization system were formed by combination with reactive monomer and initiator. Nano-Ag/Polystyrene core-shell particles were prepared by emulsion polymerization and their microstructure were characterized by TEM, FTIR, XPS, AFM and TG/DTA. The experimental results showed that silver nanoparticles were coated by polymer and the composite particles had typical core/shell structure, and the microlevel combination was realized. Meantime, the form mechanism of nano-Ag/polystyrene core-shell particles was tentatively researched. The conclusion is that the perfect coating was able to obtained by the control of reaction condition.

根据纳米银粒子的特性，借助于表面处理、超声辐照以及乳化剂的选择，使其均匀分散在反应介质中，再与反应单体、引发剂等形成乳液聚合体系；采用乳液聚合方法、包裹聚合方式，制备出纳米银/聚苯乙烯核壳复合粒子，并借助于TEM、FTIR、 XPS、AFM、TG/DTA等分析手段对复合粒子微观结构进行了表征；结果表明：纳米银粒子表面被聚合物层包覆，复合粒子呈明显的核壳结构，实现了微观尺度上的复合；同时，初步探讨了纳米银/聚苯乙烯核壳复合粒子的形成机理，指出：通过控制反应条件，可以使形成纳米银/聚苯乙烯核壳复合粒子的聚合反应方式占主导地位，实现最大限度地包覆。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐