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内铵盐

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The absorption of root system was the main sources of nitrogen in the plant.The effects of matrix ventilation on the abaorption,transportion and metabolism of nitrogen in the root system of cucmber were discussed deeply.The results showed that contents of ammonium,nitrate,free amino acids and soluble protein in cucumber roots were higher in G1 treatment.Contents of ammonium,nitrate and free amino acids in cucumber roots were the trend of the dropping after the first rising in F1 treatment,but contents of soluble protein was lower11.03%than that of the control.

根系吸收是植物体内氮素的主要来源,本研究深入探讨了基质通气状况对黄瓜根系氮素吸收、运输和氮代谢的影响,结果表明G1通气处理根系的铵盐、硝酸盐、游离氨基酸和可溶性蛋白含量均较高;非通气处理(F1处理)根系内铵盐、硝酸盐和游离氨基酸含量呈先升高后降低的趋势,而可溶性蛋白含量始终较低,比对照降低11.03%。G1处理根系硝酸还原酶、亚硝酸还原酶、谷草转氨酶、谷丙转氨酶、谷氨酰胺合成酶活性均较高;而F1处理的酶活性在处理末期显著降低,其中谷氨酰胺合成酶活性比对照降低33.33%。

Gather a sour buffer liquid of the sugar adoption lemon to carry on taking out to lift to the sweet dew in the beer leaven, separate many sugar from ferment a liquid, is precipitate with cold methyl alcohol, get a white thick lift a thing, use the 铵 salt and boric acid of the quarter again with many sugar the formation match with a thing, adding ether to precipitate, getting white and refined sample, average each 50 gs the wet leaven cell can get such refined sweet dew to gather the sugar 0.6 gs, computing with the this kind method withdraw of produce a rate for 1.2%.

对啤酒酵母内的甘露聚糖采用柠檬酸缓冲液进行抽提,从发酵液中分离多糖,以冷甲醇沉淀,得白色粗提物,再用季铵盐和硼酸与多糖形成配合物,加乙醇沉淀,得到白色精制样品,平均每50g湿酵母细胞可得到这样的精制甘露聚糖0.6g,计算出以此种方法提取的产率为1.2%。

The enhancement of the reaction activity is attributed to the phasetransfer capability of the built-in quaternary ammonium and pyridinium salts of theMn catalyst.

分子内季铵盐和吡啶盐具有相转移能力,对于取代色烯不对称环氧化的作用与外加的吡啶盐和卤化铵的作用相似,使Mn催化剂催化取代色烯环氧化反应的活性明显提高。

TheMn complexes with internal quaternary ammonium and/or pyridinium salt, either formed in-situ or isolated, displayedsignificantly higher activities than analogous complexes and Jacobsens catalyst in theaforementioned reaction.

通过研究发现,含有分子内季铵盐和/或吡啶盐的手性吡咯烷Mn配合物,无论是原位生成的还是分离的,都比类似的配合物以及Jacobsen催化剂的活性明显高。

The enhancement of the reaction activity is attributed to the phasetransfer capability of the built-in quaternary ammonium and pyridinium salts of theMn catalyst. The effect of the internal quaternary ammonium and/or pyridiniumsalt on the epoxidation of substituted chromenes is similar to that of the externalpyridinium salts and ammonium halides.

分子内季铵盐和吡啶盐具有相转移能力,对于取代色烯不对称环氧化的作用与外加的吡啶盐和卤化铵的作用相似,使Mn催化剂催化取代色烯环氧化反应的活性明显提高。

Phenothiazines were also oxidized byiodine and 2, 2, 6, 6- tetramethyl - 4 - acetyloxypiperidineoxoammonium hexachloroantimonate to radical cations in the cavityof β-cyclodextrins in aqueous solution.

以吩噻嗪衍生物为底物,2,2,6,6-四甲基-4-乙酰氧基哌啶氧铵六氯锑酸盐、碘为氧化剂,二者在水相中β-环糊精腔内发生了单电子转移反应,产生了吩噻嗪衍生物正离子自由基。

The present invention adopts ammonium salt solution as leach, and adopts the liquid-phase oxidation activating agent formed from surfactant sodium ligno-sulfonate or sodium dodecyl sulfonate, liquir phase oxidation catalyst Cu(2+) and sulfur-extracting agent tetrachloroethylene to implement quick leaching process of sulkfide mineral in gas-liquid-solid three-phase reactor, all the sulfurs contained sulfide in mineral powder can be converted into elementary sulfur and sulfuric acid radical, the contained zinc, copper, nickel, cobalt, lead, cadmium and silver can be changed into soluble salt, and fed into leach or remained in the leaching out slag.

本发明涉及的有色金属硫化矿的铵盐液相氧化直接浸出方法,其特征在于:采用铵盐溶液作浸出剂,采用由表面活化剂木质磺酸钠或十二烷基磺酸钠,液相氧化催化剂Cu2+、萃硫剂四氯乙烯组成的液相氧化活化剂,在气液固三相反应器内,实现硫化矿的快速浸出过程,矿粉中各种硫化物所含的硫转变为单质硫和硫酸根,所含的锌、铜、镍、钴、铅、镉、银等变成可溶性盐类进入浸出液中或留在浸出渣中,消除传统流程中二氧化硫,硫化氢,氮氧化物及含砷含汞含铅等有毒烟气的排放。

Optimum conditions are as follows: DMF is used as solvent, compound quaternary ammonium salt as catalyst, n(p-nitrochloro benzene):n=1: 1.2, m:m(p-nitrochloro benzene)=4%, m:m(p-nitrochloro benzene)1:1, and reacted under 155~160℃ for 18 h; reduction reaction is carried out in methanol with Raney nickel, which is used as catalyst; the raw product is added an antioxidant, and distilled simply under reduced pressure to obtain 4-fluoroaniline with excellence quality, purity is over 99.5%, total yield is 89.3%.

实验结果表明,氟化反应的最佳条件为:二甲基甲酰胺为溶剂、复合季铵盐为催化剂,n:n=1:1.2,m(催化剂:m=4%,m:m=1:1,于155~160℃下反应18h;还原反应在甲醇中进行,以阮内镍为催化剂;粗产品加入抗氧剂,减压条件下简单蒸馏得高品位的对氟苯胺。

In an acetate buffer of pH 6.0,and in the presence of CTMAB,a stable complex,having the mole ratio of 1 to 3,was formed between cobalt ion and nitroso R salt,which was concentrated on C18 solid phase extraction column,achieving a concentration multiplication of 100 times.

研究了用亚硝基R盐离子对固相萃取光度法测定钴,在pH 6.0的HOAc-NH4OAc缓冲介质中,溴化十六烷基三甲基铵存在下,亚硝基R盐与钴反应生成3∶1稳定络合物,该络合物可用C18固相萃取小柱富集,富集倍数达100倍,小柱上富集的络合物用乙醇洗脱后用光度法测定,钴的质量浓度在0.05~5.0 mg.L-1内符合比耳定律。

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