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Starting from 3-benzoyl-5-formyl-indolizine, 3-benzoyl-5-(2'2'-diacetylethenyl)-indolizines and analogs were obtained by the 〓mediated aldol condensation or Wittig reaction. These compounds,promoted by low-valent titanium, gave highly functionlizedcycl[3,2,2]azine derivatives. The coupling reaction proceeded betweenthe carbonyl group and the carbon-carbon double bond, a rare example inMcMurry reaction.

我们以3-苯甲酰基-5-甲酰基中氮茚为原料,通过三碘化钐促进的aldol反应和Wittig反应制备了3-羰基-5-羰基乙烯基中氮茚,随后经低价钛还原偶联,没有生成正常的分子内羰基-羰基偶联产物,而是得到反常的羰基与α,β-不饱羰基的双键偶联产物,较高收率地得到了含多官能团的CycI[3,2,2]azine衍生物。

The centralized interconnection rail switch concentrates in the station signal tower inside control,common has the mechanical interlocking interconnection,all-electric interlocking interconnection and so on.

集中联锁道岔集中在车站信号楼内操纵,常见的有机械集中联锁、电气集中联锁等。

Aim: To determine whether activation of κ-opioid receptor with U50,4 88 H, a selective κ-opioid receptor agonist, produces any changes in electrical u ncoupling during prolonged ischemia and whether these changes in electrical unco upling is associated with the cardioprotection induced by κ-opioid receptor ac tivation, and to explore the possible mechanism.

测量指标:以分光光度计在490nm波长下测定氯化三苯基四氯唑与活细胞反应的产物formazan含量的方法测定心肌细胞活性、测定冠脉流出液中乳酸脱氢酶的含量以及心室内压;②全心停灌70min,应用四电极法观察不同浓度U50,488H、nor-BNI和5-HD对缺血期间心肌整体阻抗和电脱耦联参数(电脱耦联时间、平台时间、电脱耦联最大速率和阻抗倍数)的影响。

Due to great amount of double bond on rubber chain,a lot of intramolecular reaction occurred in the system,which made the uncontrolled cross-linked system into a controlled cross-linked copolymerization,resulting in chain growth can't go illimitably in cross-linking process.

苯乙烯和二乙烯苯共聚体系是典型的不可控制的交联聚合体系,加入天然橡胶后,通过阳离子聚合方法,生成三元共聚物线团,由于橡胶分子链上含有大量的双键,聚合体系中能进行分子内反应,使不可控的交联聚合体系成为可控的交联聚合体系,其链增长不能无限制进行,从而可以合成可溶解的交联的聚苯乙烯-二乙烯苯-天然橡胶聚合物。

The geometry model formular is used to deduce the length of yarns, the oridentation angle of the nodulated yarns and the fiber volume content on some typical 2.5-D woven composites, such as shallow curve-linking structures, shallow straight-linking ones, and depp angle-linking ones, and tensile strength and compress strength of the composites are forecated.

借助模型推导出纱线在几种典型结构(浅交弯联、浅交直联、深角联)的单元体结构内的纱线长度、接结经的取向角和纤维体积分数,并对材料进行拉伸、压缩性能预测。

PAA/PVA IPN hydrogels were prepared by a sequential method by which acrylic acid firstly. polymerizes and cross-links in PVA/water solution with UV irradiation,then PVA physical cross-linked hydrogels are formed in cross-linked PAA networksby freezing-thawing. The orthogonal test design method was used to optimize theexperimental conditions based on the mechanical and swelling properties of thehydrogels. The effect of the PAA and crosslinking agent contents on the microscopicmorphology of the PAA/PVA IPN xerogel was investigated by transmission electronmicroscopy, and on the mechanical properties of the hydogels was studied bymeasurements of mechanical properties.

针对水凝胶强度、生物相容性和刺激响应性的需要,选择了以PVA和PAA为复合水凝胶的基本分子结构;采用顺序IPN方法制备PAA/PVA IPN水凝胶,即将单体丙烯酸与PVA溶液共混,AA经紫外光辐射聚合交联在PVA溶液中形成PAA化学交联网络,再经冰冻—解冻循环过程在PAA网络内形成PVA物理交联网络。

Then the surface of the star polymer was intramolecularly crosslinked using octa(3-azidopropyl)polyhedral oligomeric silsesquioxane, POSS-(N_3)_8,as the inorganic multifunctional crosslinker at high dilution concentration via click chemistry,forming a novel POSS/polymer hybrid nanostructure.Thermogravimetric analysis shows that after surface crosslinking, the thermostability of the core crosslinked PS can be remarkably improved.In the second work,we synthesized of a novel polymer with quatrefoil-shaped topology.

接着,我们合成了一种结构规整的含八个叠氮功能团的无机分子—多面低聚倍半硅氧烷,以其为交联剂,我们通过Click反应在即稀浓度下实现了前驱体星型聚合物的分子内表面交联,得到了外层为无机分子交联,内层为有机高分子的星状高分子,这种新型的星状聚合物表现出了优良的热稳定性能。

All-electric interlocking interconnection operates in the station through the signal tower in control bench the light signal and the electrically operated railroad switch realizes the interconnection and the inspector general train movement.

电气集中联锁通过信号楼内的控制台操纵车站内的色灯信号机和电动转辙机实现联锁和监督列车运行。

Mounted coupling: first in the motor shaft mounted on the head ring, mounted on coupling half, and then in the shaft coupling client and loaded block chute and Plum wrench tightening bolts (lifting shaft 3 ~ 5 mm and to provide mechanical seal prestressed); and then loaded up the other half on the coupling screw Hexagon screw must be tightened.

装联轴器:先在电机轴头上装上挡圈,装上一半联轴器,再在泵轴端和联轴器槽内装上挡块并用梅花扳手拧紧螺栓(吊起泵轴3~5毫米并提供机械密封预应力);再装上另一半联轴器拧上内六角螺钉必须拧紧。

Mounted coupling: first in the motor shaft fitted with ring head, fitted with coupling half, and then end in the shaft and the coupling block bed fitted with Plum wrench tightening bolts (lifting shaft 3 ~ 5 mm and pre-stressed mechanical seal); and then loaded onto the other half of the coupling screw Hexagon screw must be tightened.

装联轴器:先在电机轴头上装上挡圈,装上一半联轴器,再在泵轴端和联轴器槽内装上挡块并用梅花扳手拧紧螺栓(吊起泵轴3~5毫米并提供机械密封预应力);再装上另一半联轴器拧上内六角螺钉必须拧紧。

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On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面,更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值,分为几个相等的区间作为横轴,并将各区间内所测定值依所出现的次数累积而成的面积,用柱子排起来的图形,也叫做柱状图。

You rap, you know we are not so good at rapping, huh?

你唱吧,你也知道我们并不那么擅长说唱,对吧?