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Notably, compounds 12–14 can be described as a 3D open–framework with nano–channels, compound 15 can be described as a 3D open–framework with double helical channels, while compound 16 can be described as a 3D heterochiral coordination polymer with double helical channels, which can be obtained by spontaneous resolution from the racemic phosphonic acid.X–ray powder diffraction analysis shows that compound 16 is a pure phase. Surface photovoltage spectroscopy of compound 16 indicates that it possesses positive SPV response in the range of 300–600 nm and shows p–type semiconductor characteristic.

值得注意的是,化合物12-14为具有一维纳米孔道结构的三维开放骨架结构,化合物15是具有双螺旋孔道的三维开放骨架结构,而化合物16是外消旋的有机膦酸配体通过自发拆分而形成的具有双螺旋孔道的多手性三维开放骨架结构。X-射线粉末衍射分析表明化合物16为纯相;化合物16的表面光电压光谱分析中,在300-600nm范围内有3个正的光(来源:ABC论文12网www.abclunwen.com)伏响应带,表明它具有p型半导体的特征;化合物16的诱导表面光电压谱进一步确定它的p型半导体的特征;磁性研究表明,化合物16中两Mn原子之间存在弱的反铁磁相互作用。

The orogenic strata have following characteristics: During the subduction and intracontinental orogeny, the strata experienced dramatic tectonic migration and mixing, resulting in various tectonic features. A short sequence usually composed of tectonic slices of various origins, times, deformations and metamorphisms, and scales. The original sequence was badly destroyed. The extant fragments of orogenic belt usually took form as melanges, especially the accretion complex wedge generated in subduction zone, which is contrary to the Law of Superposition. The original location of the accretion is also contradicted with the Law of Original Horizonality, because the accretion is oblique with high degree. Marine rocks, volcanic rocks of continental margin and metamorphic rocks were well-developed in the orogenic belt, especially ultra-basic, basic rocks were wide spread and were intensely metamorphosed, accompanied by metamorphic slices returned from hundred kilometers underground with ultra-high pressure and magma movements during syn-orogeny and post-orogeny, thus formed the colorful landscapes.

造山带非史密斯地层构成具如下独特性和复杂性:造山带在俯冲碰撞和陆内造山阶段,发生过强烈的构造搬运和构造混杂,构造形迹多样化,垂直不长的地层体往往是众多不同来源、不同时代,不同变形变质程度,不同大小的各种构造岩片拼贴体,地层原始层序被严重肢解、破坏;尤以产于俯冲带的俯冲增生杂岩楔的原始形成方式与史密斯地层学的&层序叠覆律&老下新上的顺序正好相反,其混杂岩增生方式是老的&片体&在上,新的&片体&阶段性拼贴在老的&增生片体&的斜下方,这种增生片体的原始位置亦与&原始水平律&相悖,即增生片体一般保持较高角度倾斜;在岩石类型和变质程度上,造山带海相和古陆缘火山岩以及变质岩普遍发育,尤其是超基性、基性岩系分布广泛,变质作用较强,伴有从百余公里以下深部超高压变质岩片的折返和同造山期与造山后期岩浆活动,构成极为复杂的地质景观。

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The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了,排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意,我建议我们在价格上大家各让一半。

After an hour and no pup, look for continued contractions and arching of the back with no pup as a sign of trouble.

一个小时后,并没有任何的PUP ,寻找继续收缩和拱的背面没有任何的PUP作为一个注册的麻烦。