共轭类

In the first part,two methods calculating the coefficients of nilpotentclass normal forms are proposed.one is the iteration search method based onrepresentation theory of Li-algebra,and another is a new matrixrepresentation method based on the adjoint operator concepts,both are ableto be used to analyse the normal form problems with high orders and largedimensions efficiently.

在第一部分工作中，对于幂零类规范形的系数计算，分别提出了基于李代数表示论的迭代搜索的理论和方法以及基于共轭算子概念的新的矩阵表示的理论和方法，从而有效地解决了维数和阶数较高时的计算问题。

Among the large number of nonlinear absorbers, the material applied most extensively is phthalocyanine reverse saturable absorption compound which is organic large molecule with central symmetry two-dimensional π-electron conjugate system. In the off-resonance condition, its absorption coefficient will raise along with the increasing of incoming light intensity, which shows its reverse saturable absorption properties.

在非线性光学材料中目前最具应用价值的是酞菁类的反饱和吸收材料，这是一类具有中心对称二维π电子共轭体系的有机大分子，在非共振激发条件下，吸收系数往往会随入射光强的增加而增加，体现反饱和吸收。

Finally, the numerical results show this class of conjugate gradient methods is very efficient.

然后证明三种新算法在强Wolfe线搜索下的全局收敛性，数值验证表明这类共轭梯度法是比较有效的。

Second, using DBU as the base for enolization of propargylic esters of unsaturated acids 18e-k, we developed a tandem Ireland-Claisen rearrangement /isomerization reactions. It has been shown that the reaction sequence affords triene molecules 42a-b and 43a-b in moderated to high yields. Interestingly, with allyl hexa-3,5-dienoates 18i-j as the substrate, the rearranged products underwent further aromatization to give uniquely substituted benzyl acids 44a-b.

其次，以含有活泼质子的烯酸炔丙酯18e-k为底物，在DBU为烯醇化碱、TMSCl为硅试剂的条件下，底物18e-h发生了Ireland-Claisen重排/异构化串联反应，得到完全共轭的三烯类化合物42a-b及43a-b；而以己二烯酸炔丙基酯18i-j为底物时，重排/异构化后的产物进一步发生电环化等反应最终得到芳构化产物——取代苯甲酸类化合物44a-b。

The structure and stability of all possible isomers of C50X(X=SiH2, PH, S) were investigated by ab initio HF/3-21G calculations. The calculation results indicate that the preferred position for cycloaddition of SiH2, PH, and S on C50 is consistent, i.e. on the C3-C4 and C4-C4 sites of C50, and the resultant most stable cycloaddition isomers are [5,6]-closed and [5,5]-closed structures. The main driving force governing the stability of the C50X(X=SiH2, PH, S) isomers is the strain, or the conjugative effect, or the combination of strain and conjugative effect, depending on the addition positions and the types of the attacked C-C bonds.

用从头算HF/3-21G方法研究了C50的环加成衍生物C50X(X=SiH2， PH， S)所有可能的异构体的结构与稳定性，计算结果表明，SiH2基团、PH基团与S原子在C50上环加成的优先加成位置相同，都为C3-C4类键和C4-C4类键，并且相应形成[5，6]-闭环和[5，5]-闭环结构的最稳定异构体；决定C50X(X=SiH2，PH，S)各异构体稳定性的主要因素，因加成位置以及发生加成反应的C-C键的单双键类型的不同，可能是张力、共轭效应或者二者的共同作用。

Exceptionally large nonlinear optical response in C60 had been reported, and diacetylene complexes have the large NLO suspceptibilities, so the novel idea of introducing diacetylene to C60 to improve the NLO suspceptibilities was supposed.

富勒烯具有优良的非线性光学性能，共轭双炔类有机分子有较大非线性光学系数，将C60与双炔类化合物结合在一起设计非线性光学材料是一个有意义的设想。

Specifically, itcontains 8 chapters.In chapter 1, the formation, structures, properties and the futureprospect of liposome were thoroughly reviewed;In chapter 2, the stibility and permeability of phopholipid -eleostericacid liposome were studied together with the effect of polymerizationof eleostearic acid. This membrane system was very sensitive to 〓,the effect of 〓 was clarified to increase the aggregation/fusion ofliposomes and made the permeability of mixed liposomes much higher;In chapter 3, two polymerizable conjugated diyne bolaamphiphiles were synthesized. They could form very stable mixed liposome, andthe diyne could be polymerized by UV light in bilayer liposomes, as aresult, the stability of mixed liposome against solvent or surfactantafter polymerization were enhanced. In chapter 4, two kinds of amphiphilic amino acids were synthesized andstable liposomes were formed therefrom After the condensationpolymerization of amino acid in bilayer liposomes, stable polypeptide liposomes were obtained, which had lower phase transition temperatureand higher permeability.In chapter 5, four kinds of glycolipids were synthesized and theiraggregation behavior in water was comparied. When incorporated intophospholipid bilayer membranes, they could increase the phase transitiontemperatures and inhibit the aggregation and fusion of mixedliposomesat lower temperature.In chapter 6 and 7, three kinds of steroidal bolaamphiphiles withdifferent chain lengths were synthesized. Incorporation of steroidalmoiety to the center of lipid bilayer membrane obviously increased themobility of lipid membrane and shifted Tc to lower temperature side incomparasion with cholesterol. The bolaamphiphile which was shorter thanthe hosted lipid bilayer membrane thickness influenced the lipid packingmore obviously.

全文共分8章：第一章对脂质体的形成、结构、性质及展望进行了较为详细的文献综述；第二章研究了磷脂-桐酸脂质体的稳定性，通透能力及桐酸的聚合对这些性质的影响；磷脂-桐酸混合脂质体为一类对〓灵敏的脂质体，〓的作用首先是使脂质体集聚然后使脂质体融合，并加速内包荧光物的释放；第三章通过合成两种可聚合共轭双炔双极性双亲分子DDCA，DDOL，研究了共双炔分子在双分子层脂质体膜上的聚合及对脂质体性质的影响，聚合可以提高脂质体相对于溶剂及表面活性剂的稳定性；第四章合成了两类氨基酸为极性基团的双亲分子，它们均可以在超声下形成稳定的脂质体结构；氨基酸基团可以在脂质体上进行缩聚反应，若聚合后脂质体表面仍有足够的亲水能力，则可得到稳定的多肽型脂质体；聚合后脂质体的相变温度降低，通透能力增加；第五章合成了四种亲水基团为单糖基的双亲分子GL-l，GL-2，GL-3， GL-4，研究了它们在水中的分散情况、集合体形态与分子结构的关系；在DMPC双分子层膜中加入糖脂分子可以使脂质体的相变温度提高，阻止脂质体在低温放置时的集聚与融合；第六章-第七章合成了三种不同碳链长度的双极性含胆甾环双亲分子 CL-1，CL-2，CL-3；它们可以象胆固醇一样与磷脂混合形成稳定脂质体，胆甾环基团位于脂质体双分子层膜的中间；与胆固醇的作用相反，它们可以增加磷脂双分子层膜的流动性，降低混合脂质体的相变温度；三种分子的作用与其碳链长度和磷脂双分子层膜的厚度有关，比膜厚度短的分子影响最大。

The two-photon absorption cross-sections of these styryl derivatives were determined by Z-scan technique, and the benzothiazolium derivatives exhibited the largest TPA cross-sections (10〓s·cm〓/photon) and the best power limiting ability at high operable incident intensity. The results show that the benzothiazolium derivatives are promising organic compounds as two-photon absorption optical limiting materials. 2. Several organic dyes active to 800nm femtosecond laser with D-π-A structure were designed and synthesized.

研究了它们的上转换荧光、上转换激射和光限幅行为，通过改变染料分子共轭体系的大小，首次实现了在576nm-635nm范围内的双光子上转换激光波长的调节，其中噻唑啉碘盐类二苯乙烯化合物的双光子上转换激射峰（576nm）是迄今在1064nm皮秒激光作用下能够得到的最短波长的激光；阴离子显著改变上转换激射效率，但对上转换荧光峰和激射峰的位置影响很小；增加溶液的浓度，上转换荧光光谱和激射光谱红移，并在一定的浓度范围内，能够有效的提高上转换激射效率；利用Z-扫描技术测定了染料分子的双光子吸收截面，发现苯并噻唑类染料分子的双光子吸收截面高达10〓s·cm〓／photon，而且在较大的入射光强范围内，这类染料分子具有较大的光限幅能力，是一类作为双光子吸收光限幅材料很有潜力的染料分子。

Polyaniline and Poly-phenylene vinylene are organic polymers with π^-conjugated structure.

聚苯胺类和聚对苯撑乙烯类材料都为线性共轭高分子有机聚合物。

Understand the chemistry of alkenes and alkynes: nomenclature, electronic structures, sequence rule, cis-trans isomers, electrophilic addition reactions and mechanism, Markonikov's rule, conjugated dienes, rules of resonance forms.

A2 E3 了解烯类及炔类的化学性质：命名、电子结构，顺反异构物，亲电子加成反应及机制，马克尼可夫规则，共轭双键及共振式。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。