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It was found that copolymerization of selected acetylenes with different polarity by using palladium acetylide complex catalysts is an effective method for improving solubility of polymers, especially doped polymers, which makes the above mentioned polymers and doped ones a new type of π-conjugated sensing material for preparation of thin film humidity sensor.

研究发现,以新型过渡金属钯-炔配合物为催化剂,通过选择具有不同极性的取代乙炔单体进行共聚,可有效地提高聚合物的溶解性,尤其掺杂聚合物的溶解性,实现可溶酸掺杂,继而开发出上述系列新的π-共轭型聚炔湿敏材料,用以制备薄膜型湿敏元件。

We show that Jordan multiplicative bijective maps on prime operator algebrasmust be additive. As its application, we show that every Jordan * multiplicative bijec-tive map on every factor C~* algebra is a C~* isomorphism or a conjugate C~* isomorphism,in the special case of B, it must be a *-isomorphism or a conjugate *-isomorphism.We also prove the additivity of Jordan multiplicative bijective maps on nest algebras.

证明了素算子代数上Jordan可乘双射的可加性,利用这一结论刻画了因子C~*代数上的Jordan*可乘双射,我们的结果表明这样的映射一定是C~*同构或共轭C~*同构;证明了套代数上的Jordan可乘双射的可加性。

The results also show the sensitivity is enhanced for the pigments with a larger anilide ring. It is important to note that the photosensitivity is greatly increased when the coupler component changed ftom a 2-hydroxy-3-naphthanilide to a 2-hydroxy-11H-benzocarbazole-3-naphthanilide coupler. Clearly, conjugation effects favours to enhance the photosensitivity.

偶合基部分共轭环的扩大使蒽醌偶氮染料的光敏性增加,特别是偶合基萘环上扩大了一个咔唑环后,其吸收光谱大幅红移,光敏性提高了几十倍,这一结果对红外偶氮光导染料的设计合成具有重要参考价值。

The electron- withdrawing groups in the anilide ring of the coupler moiety enhance the photosensitivity. Remarkable increase of photosensitivity was observed with Azo9, suggesting that conjugation effects drastically influence the photoconductive properties.

值得注意的是萘环上扩大一个咔唑环(Azo9,使偶氮染料的光敏性提高了几十倍,表明在萘环上扩大共轭环是提高偶氮染料光敏性的一个良好途径。

The Cardo structure could increase the solubility and thermal stability of the resultant polyimide.

通过在聚酰亚胺的主链中引入庞大侧基(9,9-二苯基芴)形成轴状聚酰亚胺,同时提高聚酰亚胺的溶解性和热稳定性;庞大的侧基又能阻止链的堆砌,避免生色团荧光链间淬灭;通过加入第二种二酐单体合成三元缩聚型聚酰亚胺,调控荧光性二酐在聚酰亚胺中的含量,降低生色团在聚酰亚胺中的浓度,来避免生色团荧光浓度淬灭,增加聚酰亚胺的固态荧光量子效率;通过使用热稳定性好的稠环生色团苝和吖啶来避免共轭类生色团(如含双键或三键的生色团)在高温下热交联及氧和水的破坏。

Characteristics of conflict are analyzed, using divergent, expansive, correlative and implicative natures of matter element and conjugate analysis in extenics, conflict analysis method and policies generation method for conflict settlement are presented.

分析了不正常航班中冲突的特点,利用可拓学中的共轭分析理论和物元的发散性、可扩性、相关性、蕴含性关系,对解决旅客纠纷提供了一种有效的分析手段和策略生成方法。

By weakening the premise of the convexity of the objective function required in paper[7], we prove the sufficient desent property and the global convergence with the strong Wolfe line search.

在第二章中,我们参照文献[7]中的方法,提出了一类与HS算法相关的共轭梯度算法,并减弱了文[7]中要求目标函数二阶连续可微且为凸的前提条件,采用强Wolfe线搜索,在较弱的条件下证明了这一类算法具有充分下降性和全局收敛性。

Since most of the large molecules containing phosphorus element have double bonds, it is necessary to consider the special structures of double bonds in order to deal with these large systems more accurately. So, based on density functional theory and electronegativity equalization principle, applying a general atom-bond electronegativity equalization method , using separated program, through regression and least-squares optimization , the parameters of atoms and bonds in molecules are determined . By these parameters , the charge distributions and the energy of some molecules containing phosphorus element, especial the fragment of DNA, RNA, are calculated . The results are quite good.

由于这些含磷生物大分子体系都含有双键,为了明确的处理双键,进而更准确的解释带有双键和共轭双键的含磷生物大分子结构与性质的关系,我们以密度泛函理论~([1-4])和电负性均衡原理~([5-9])为基础,应用和开发原子-键电负性均衡方法中的σπ模型,利用最小二乘法,拟合确定了一些分子(含碳、氮、氧、氢以及磷等原子)的各种类型原子及化学键区域的参数,并利用上述参数计算了一些多聚核苷酸的电荷分布以及分子的总能量,进行了讨论,得到的结果可以和从头算相媲美。

On the base of the good convergence of FR, and in view of the descend property of the paper presents a new conjugate gradient method, and studies the global convergence with two kinds of Armijo-type linear search.

基于FR方法好的收敛性并考虑到d的下降性,提出了一类新的共轭梯度法,并在两种Armijo型搜索下,研究了新方法的全局收敛性。

The results indicate that series A have better planarity, longer conjugated bridge and larger βtot value than series B.

结果表明:A类分子的共面性好,共轭链长,β值均比B类分子的大。14个化合物中前线分子轨道能级差越小的化合物,其βtot值越大。

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