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共价键

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Study on the Crystallization Process of Labeled GL-7-ACA Acylase CA130 Complex 7β-bromoacetyl amino cephalosporanic acid (BA-7-ACA), an analog of glutaryl-7-amino cephalosporanic acid (GL-7-ACA), can inhibit and specifically alkylate GL-7-ACA acylase (CA130) from Pseudomonas sp. 130, forming a carbon-carbon bond between BA-7-ACA and the C-2 on indole ring of Trp-β4 residue of CA130.Here we reported that BA-7-ACA labeled CA130 (BA-C130) could self-catalyze the hydrolysis of BA-7-ACA during crystallization process. The hydrolysis was confirmed to be a reaction analogous to the one of GL-7-ACA by comparative MALDI-TOF (matrix-assisted laser desorption/ionization-time of flight) spectrometry analysis.

二、GL-7-AcA酰化酶CA130标记复合物的结晶过程研究溴乙酰氨基头孢烷酸(7β-bromoacetyl amino cephalosporanic acid,BA-7-ACA)作为戊二酰-7-氨基头孢烷酸(GL-7-ACA)的类似物,不仅能够抑制GL-7-ACA酰化酶CA130的活力,而且能通过在BA-7-ACA和CA130的β亚基第四位色氨酸吲哚环二位碳原子之间形成碳-碳共价键而将CA130特异的烷基化。

Synthesis of Arylenealkyne Conjugated Macrocycles Containing Long Alkylene Bridge;2. Rigid,planar structures have been modified through incorporation of new additional groups to generate sharp-persistent imine macrocycles in very high yields.

我们设计并合成了一类氢键诱导下构象受限的芳酰胺寡聚体,以此模块作为前体,利用动态共价键的方法,高产率(80%-89%)地合成了一系列新的亚胺大环。

The nonlinear optical properties of two novel covalently bonded azobenzene polymers are studied.

研究了两种新的共价键联型含偶氮聚合物材料的二阶非线性光学性质。

The studies presented here provided the antifungal lead compounds. Because the affinity of the lead molecules for CYP51 was mainly attributed to their nonbonding interaction with the apoprotein, which was different from the azole antifungal agents.

先导分子通过与靶酶活性腔氨基酸残基的非共价键结合产生抗真菌作用,避免与血红素辅基Fe原子发生配位结合,为一类具有新作用机理的非氮唑类抗真菌先导化合物。

Shuenn is a covalent bond uniform crack more energy, so you have selected the use of UV-radiation energy raises the line as an energy raises one of the main form.

顺为共价键均均裂需要较大的能量,所以选择了采用紫外光线的辐射能引发作为能量引发的主要形式之一。

We assume that the special interaction between amino and carboxyl is responsible for the reversible connection between subunits.

我们假定端胺基和端羧基间的非共价键作用连接不同的次级单元。

The basic structure of chromogen in PFBs remains the same, so PFBs have fluorescent properties of traditional FBs. Covalent bonds between chromogen and macromolecule chains enhance their photochemical stability, increase their whitening performance and fluorescence quantum yield.

聚合型荧光增白剂中基本发色团的结构不变,具有传统荧光增白剂的光学性能;发色团与高分子链间的共价键使其光化学稳定性大大增强,增白性能和荧光量子产率显著提高。

The group were divided in their sympathies. See Usage Note at collective noun

指化合物中以共价键与其他组分相结合的原子集团,如羟基,—OH。

The test results showed that the amount of this kind of function material to conjugate proteins were larger than 1.5ig/mm2and its one time adsorption rate was larger than 80% and can satisfy the requirements for solid-phase radioimmunoassay. Test results showed that this polymer-NHS-ester can connect with proteins through covalent bounds under mild conditions This technical method will supply a type of new material for solid-phase radioimmunoassay.

实验证实,这类聚合物NHS酯可在温和条件下与蛋白反应,使蛋白以共价键结合方式固定在聚合物上,这种功能材料对蛋白的结合量大于1.5μ/mm~2,对蛋白的一次吸附率大于80%,能满足固相放免分析的要求,将为固相放免分析提供一种新材料。

The results indicated that hydrogen bond and covalence bond were formed between PVA and TEOS through the sol-gel reaction.

结果表明PVA与无机相发生溶胶-凝胶反应生成氢键和共价键Si-O-Si,形成交联有机聚合物/无机杂化体系,使杂化膜的结晶度减少,控制了膜的溶胀,提高膜的溶解选择性能,但膜的溶胀减少会使通量有所下降。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。