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And the lattice distance expands anomalously with decreasing particle size. Using the model of long-range interaction and its cooperative phenomena altered by particle size, the size-induced cubic-tetragonal phase transition, the anomalous lattice expansion, and the change in chemical bonding characters have been well understood.

采用长程相互作用的晶粒尺寸效应模型,对钛酸钡纳米晶结构相变、晶格间距异常增加、价键性质变化等实验现象给出了合理的统一的解释;并把该模型扩展到解释与钛酸钡晶体具有不同共价性成分的氮化镓等纳米体系的相变以及晶格结构变化现象。

A cofactor that is covalently attached to the enzyme is called a prosthetic group.

与酶共价结合的辅助因子成为辅基。

In order to reduce the composite probability of Cd and O, simultaneity , to enhance the Cd-N covalent characteristics and improve the hole concentration, it is important to control the proper concentration of Cd and O.

研究表明共掺体系中,适当控制Cd和O的浓度,可以减小Cd和O的复合机率,加强Cd-N的共价特性,对改善AlN的p型特性有重要意义。

Transition metal nitrides belong to a class of interstitial compounds, have the properties of covalence compound, ion crystal and transitional metals.

过渡金属氮化物是一类金属间充型化合物,兼具有共价化合物、离子晶体和过渡金属的性质。

Furthermore, though Nt and Ne are the two different covalent factors belonging to different wave functions, their difference in numerical values should be small, because Racah electrostatic parameter A plays a great role in the calculation of energy levels when the covalence effect is considered.

Nt和Ne虽然是属于两个不同轨道的不同的共价因子,但在数值上不能有大的差别,因为考虑进共价效应后,拉卡静电参量A对能级计算有极大的影响。

The crocic acid is used for living creature analysis realm, is the near red and outside fluorescence dyestuff that combines with the living creature member covalence at present.

现今克酮酸被用于生物分析领域,是与生物分子共价结合的近红外荧光染料。

Major content of this work includes five aspects as follows:(1). Oxygen sensitive materials had been prepared by carrier covalence method, and the preparation mechanism of the materials had been investigated by FI-IR, SEM, and the detection experiment of oxygen. Then through the detection of oxygen, the sensitivity and stability had been estimated, and it was studied that the properties of materials would be affected by the various factors.(2). Oxygen sensitive materials had been prepared by carrier covalence-cross linking method, and the preparation mechanism of the materials had been investigated by FI-IR, SEM, and the detection experiment of oxygen. Then through the detection of oxygen and spectrophotometer, the sensitivity and stability had been estimated, and it was studied that the properties of materials would be affected by the various factors.(3). For the detection of gaseous oxygen, the fiber optical sensor on basis of oxygen sensitive materials had a respond time of 10s, detection limit of 5ppmand detection precision of 0.5%. The sensor had good repeatability and stability, a less delay and at least 1 year life-span.

本论文主要包括以下五个方面的内容:(1)载体共价法制备氧敏感材料:通过红外光谱、扫描电镜图谱和氧测试实验探讨该氧敏感材料的制备机理,通过氧测试实验评价该氧敏感材料的氧敏感性和稳定性,同时研究了各种因素对该氧敏感材料性能的影响(2)载体共价—交联法制备氧敏感材料:通过红外光谱、扫描电镜图谱和氧测试实验探讨该氧敏感材料的制备机理,通过氧测试实验和分光光度计评价该氧敏感材料的氧敏感性和稳定性,同时研究了各种因素对该氧敏感材料性能的影响(3)氧敏感材料在光纤气态氧传感器中的应用:该传感器的响应时间为10s,检测下限为5ppm,检测精度为0.5%,具有较好的重复性和稳定性,迟滞较小,使用寿命至少为1年,适合各种环境下气态氧浓度的检测。

Potassium salt of dicyclopentadienyl dicarboxylate DCPD(COOK2 was applied to CPE as crosslinking agent and a crosslinked product with 81.79% gel content was obtained in solution reaction.

以溶液反应法研究了CPE与DCPD:的交联反应,制得了凝胶量在80%以上的共价交联CPE,考察了不同牌号CPE、催化剂及其用量、反应温度、反应时间及其交联剂用量对CPE凝胶形成量的影响;通过对比实验和IR谱图证明了该凝胶确由CPE与DCPD:经双端醋化反应生成;通过反应溶解性实验验证了共价交联CPE的热可逆转化特性。

The pegylated polylactide-poly glycolide nanoparticle, whose surface was co-modified withmaleimide-polyethylene glycol and methoxy-polyethylene glycol, was made by double-emulsion and solvent evaporation method andcovalently conjugated with thiolated lactoferrin via its maleimide functionalgroup.

第一章首先由复乳/溶媒蒸发法制备马来酰亚胺—聚乙二醇(Maleimide-PEG,MAL-PEG)和甲氧基聚乙二醇表面共修饰的聚乳酸-聚羟基乙酸纳米粒,然后通过其表面MAL-PEG与巯基化Lf共价连接而制备Lf-NP_。

In terms of the obtained values of parameters, it is demonstrated that the covalency of the bonding between Mn〓 and ligands in SrTiO〓: Mn〓 is stronger than the one of the bonding between Cr〓 and ligands in SrTiO〓: Cr〓.

通过分析得到的常压参量值,揭示了在SrTiO〓:Mn〓中Mn〓与配位体之间的共价作用比SrTiO〓:Cr〓中Cr〓与配位体之间的共价作用更强。

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