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Using solid-state 29Si cross-polarization magic-angle spinningNMR spectra, we confirmed that APS moieties are bonded on the LDHs covalently, forming the oxane bonds M-O- Si (M=Zn and Cr in LDH.

采用固态29Si交叉极化魔角旋转 NMR谱,我们证实,黄芪多糖基在债役对水滑石共价,最终形成了oxane债券。

Depending on the amino acid sequence, the length of the ∝-helical portio are held together by hydrogen bonds formed between r grou , by salt linkages, by hydrophobic interactio , and by covalent disulfide(-s-s-0 linkages.

根据氨基酸顺序的不同,此α-螺旋段的长度也不同,并赋予独特的三级结构,这些折叠部分是靠R基团之间所形成的氢键,靠盐键、疏水相互作用以及共价二硫键而结合在一起的。

The method of activating hydroxyls of fullerenols using 2-fluoro-l-methylpyridinium p-tolu- ene sulphonate to covalently linking with bovine serum albumin and further its effect on BSA was studied.

考察了2-氟-1-甲基吡啶对甲苯磺酸盐对富勒醇羟基的活化方法,以便将富勒醇通过共价交联的方法与牛血清白蛋白连接,进而研究富勒醇修饰对BSA所造成的影响。

SUMO has been shown to covalently modify a large number of proteins, reversible modification by SUMO regulates nucleocytoplasmic translocalization, protein-DNA binding activity, protein-protein interaction, transcriptional regulation, DNA repair, and genome organization.

SUMO与靶蛋白之间这种可逆的共价连接,在核质运输、DNA 与蛋白质结合活性、蛋白质之间相互作用、转录调控、DNA 修复以及维持基因组稳定等方面均发挥着重要的调节作用。

Can cause significant increase of UDS, indicating the appearance of DNA damage.

化学致癌剂被肝微粒体细胞色素P-450酶系代谢活化后形成亲电性的活性终致癌物,后者与细胞核DNA的特异性靶点呈共价结合,导致DNA损伤。

According to Johnson's Rule and IR spectra, their possible structures are suggested. The bonding parameters of those complexes are calculated by ESR parameters. And the crystal field parameters are calculated by using electronic spectral data. It can be seen that the vanadyl complexes in the solution are ionic complexes and that the α〓 values of those complexes decrease following the increasing of the N donor replacing the O donor of water on the equatorial plane in those complexes. This means that the covalent bonding between vanadium and ligand increases as Ser, Phen or Bipy replace water ligands. The results show the competitive coordinate law that the coordination reactivity of Phen and Bipy is much stronger than that of Ser. The simulation program of ESR is compiled by the theory of ESR in the present work.

测定了VO-丝氨酸二元体系、VO-丝氨酸-邻菲咯啉三元体系和VO-丝氨酸联吡啶三元体系在不同酸度下(pH=1.0~14.0)的乙二醇/水(V/V=1:1)溶液低温ESR谱,发现不同pH下,溶液中具有不同组成的配合物,根据不同pH下ESR谱的变化,利用Johnson的加合规则并结合红外光谱,推测了它们在溶液中的可能结构;利用波谱参数计算了配合物键参数;利用电子光谱数据计算了配合物的晶体场参数,讨沦了它们的成配特性,结果表明:VO配合物属离子型配合物,随取代水分子的配体(Ser、Phen或Bipy)数目增加,键参数减小,配合物共价性增强,同时得出这些体系中,生物配体竞争配位规律:Phen和Bipy与VO的配位能力比Ser强。

MPO forms reactive chlorinating species capable of inflicting oxidative stress and altering protein function by covalent modification.

MPO生成反应性氯化物,这些氯化物损害氧化应激并通过共价耦联改变蛋白功能。

The specific inhibitor of DNA methylation that is available currently is 5-Aza-2'-deoxycytidine (5Aza-dc), which forms a covalent bond with the DNA methyltransferase, thus, limiting the number of free DMT molecules for methylating DNA and then decreasing its biology activity.

目前研究较多的甲基化抑制剂是胞苷类似物5-氮杂-2'-脱氧胞苷(5-Aza-2'-deoxycytidine, 5Aza-dc)。5Aza-dc的作用机制是与DNA甲基转移酶共价结合,降低酶的生物活性。

The high polarizing power polarizes all but the smallest anions producing covalent character

高极化能力极化所有但最小的那些负离子产生共价特性。

Overview Glycogen degradation and glycogen synthesis are controlled both by allosteric regulation and by hormonal control.

变构控制和共价修饰磷酸化酶存在有磷酸化的活性 a 型河渠磷酸化的正常情况下无活性的 b 型。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。