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And the lattice distance expands anomalously with decreasing particle size. Using the model of long-range interaction and its cooperative phenomena altered by particle size, the size-induced cubic-tetragonal phase transition, the anomalous lattice expansion, and the change in chemical bonding characters have been well understood.

采用长程相互作用的晶粒尺寸效应模型,对钛酸钡纳米晶结构相变、晶格间距异常增加、价键性质变化等实验现象给出了合理的统一的解释;并把该模型扩展到解释与钛酸钡晶体具有不同共价性成分的氮化镓等纳米体系的相变以及晶格结构变化现象。

It can be seen that the bulk modulus depends mainly on electrons per atomic volume and mass density, while covalent structure of chemical bonding and N content make more contribution to theoretical hardness, and appropriate content N—N covalent bonding in the same direction tends to increase the shear modulus of nitrides.

说明在Tc的氮化物中,其体弹模量与材料的晶体结构、平均每个原子上的电荷密度和材料的质量密度有关;化学键的共价性结构和氮元素的含量对理论计算硬度有正作用;而剪切模量的极大值则与其层状结构及体系中一定量的方向基本一致的N—N键相关。

The purpose of this study is to covalently modify adenoviral capsid with chitosan, a cationic and natural polymer.

本篇研究,我们利用一个正电性的天然高分子几丁聚醣来对腺病毒外壳进行共价性的修饰。

UV and fluorescence spectrometry,〓H-NOESY charactered the non-covalent interaction between cinchonine and CDs in solution. The results indicated that the possible stoichiometry of complex formation is 1: 1 (guest: host ratio) and 2: 1 inclusion complexes coexistence simultaneously in solution.

用紫外光谱、荧光光谱、二维核磁共振等手段研究了辛可宁与β,γ-环糊精在溶液中的非共价作用,发现它们之间是以1:1结合以及2:1结合两种方式模式的方式存在的。

In order to reduce the composite probability of Cd and O, simultaneity , to enhance the Cd-N covalent characteristics and improve the hole concentration, it is important to control the proper concentration of Cd and O.

研究表明共掺体系中,适当控制Cd和O的浓度,可以减小Cd和O的复合机率,加强Cd-N的共价特性,对改善AlN的p型特性有重要意义。

In this paper, the thermally reversible crosslinking reaction and the properties of synthesized TPE based on the reactions of chlorine containing polymers such as PVC , chlorined polyethylene , epichlorohydrin rubber and acrylic rubber with salts of dicyclopenladienyl dicarboxylate crosslinking agents were studied.

本研究以环戊二烯二酸盐衍生物作热可逆共价交联剂,通过与聚氯乙烯、氯化聚乙烯、氯醚橡胶和丙烯酸酯橡胶等含氯聚合物的脱MX酯化反应来实现共价关联,并制取相应的新型TPE。

Potassium salt of dicyclopentadienyl dicarboxylate DCPD(COOK2 was applied to CPE as crosslinking agent and a crosslinked product with 81.79% gel content was obtained in solution reaction.

以溶液反应法研究了CPE与DCPD:的交联反应,制得了凝胶量在80%以上的共价交联CPE,考察了不同牌号CPE、催化剂及其用量、反应温度、反应时间及其交联剂用量对CPE凝胶形成量的影响;通过对比实验和IR谱图证明了该凝胶确由CPE与DCPD:经双端醋化反应生成;通过反应溶解性实验验证了共价交联CPE的热可逆转化特性。

The pegylated polylactide-poly glycolide nanoparticle, whose surface was co-modified withmaleimide-polyethylene glycol and methoxy-polyethylene glycol, was made by double-emulsion and solvent evaporation method andcovalently conjugated with thiolated lactoferrin via its maleimide functionalgroup.

第一章首先由复乳/溶媒蒸发法制备马来酰亚胺—聚乙二醇(Maleimide-PEG,MAL-PEG)和甲氧基聚乙二醇表面共修饰的聚乳酸-聚羟基乙酸纳米粒,然后通过其表面MAL-PEG与巯基化Lf共价连接而制备Lf-NP_。

In terms of the obtained values of parameters, it is demonstrated that the covalency of the bonding between Mn〓 and ligands in SrTiO〓: Mn〓 is stronger than the one of the bonding between Cr〓 and ligands in SrTiO〓: Cr〓.

通过分析得到的常压参量值,揭示了在SrTiO〓:Mn〓中Mn〓与配位体之间的共价作用比SrTiO〓:Cr〓中Cr〓与配位体之间的共价作用更强。

In addition,the spectra and the g factor of GaP∶Co2+ crystal also are analyzed,the results show that,for the strongly covalent of GaP∶Co2+ crystal,it is not reasonable to neglect the covalency and the contribution due to the s.o.coupling of the ligand ion.

本文结果表明,由于GaP∶Co2+晶体共价性很强,再忽略共价性及配体旋轨耦合的贡献是不合理的。

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