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The invention provides a method for homopolymerizing conjugated dialkene or co-polymerizing conjugated dialkene and monovinyl aromatic hydrocarbon. The method comprises the following steps: the conjugated dialkene is homopolymerized or the conjugated dialkene and the monvinyl aromatic hydrocarbon are co-polymerized randomly. The method is characterized in that at least one alkali metal alkoxide compound expressed by the formula is used as a structure regulator; in the formula, R is linear chain or branched chain alkylidene radical having 1 to 10 carbon atoms; M is alkali metal selected from Li, Na, K, Rb and Cs.

本发明提供了一种使轭二烯烃均聚或者使轭二烯烃与单乙烯基芳烃聚的方法,包括在阴离子聚合条件下使轭二烯烃进行均聚或者使轭二烯烃与单乙烯基芳烃进行无规聚,其特征在于采用至少一种式所示的碱金属醇盐化合物作为结构调节剂,其中R为具有1-10碳原子的直链或支链亚烷基;以及M为选自Li、Na、K、Rb和Cs的碱金属。

By using constructive methods and complicated techniques of matrices, necessary and sufficient conditions for the existence of selfconjugate solution, perselfconjugate solution, centrosymmetric solution, bisymmetric solution, skewselfconjugate solution, skewperselfconjugate solution, skewcentrosymmetric solution, skewbisymmetric solution and various interlaced solutions over a finite central algebra Ω to systems of generalized Sylvester matrix equations overΩ are presented.

利用构造方法和复杂的矩阵技巧,研究了有限维中心代数上的多项式环Ω上的广义Sylvester矩阵方程组在Ω上有自轭解,斜自轭解,广自轭解,斜广自轭解,中心对称解,斜中心对称解,双对称解,斜双对称解及其各种交错解的充要条件。

From the influnce of pH change in water on the copolymerization, the copolymerization mechanism was provided. The copolymerization mechanism is that there is hydrogen bond, which can enhance the copolymerization, between acrylic acid and crotonaldehyde at low pH and there is"Charge Transfer Complex", which gives the more crotonaldehyde in P (acrylic acid-crotonaldehyde), between acrylic acid and crotonaldehyde at high pH.

根据聚合反应介质pH值变化对丙烯酸-丁烯醛聚合反应的影响,提出了丙烯酸-丁烯醛聚合反应机理,即在低pH值时,丙烯酸、丁烯醛之间可形成氢键,从而使聚合体系具有较高的聚合反应速率和转化率;在较高pH值时,丙烯酸、丁烯醛之间则有电荷转移络合物形成,从而使聚物中含有更多的丁烯醛链段。

A new organic compound, trans-2--5-dimesitylborylthiophene (abbreviated as DMASBT, 5) with dimesitylboryl, dimethylamino and styryl-thiophene as electron acceptor, electron donor and conjugate bridge respectively, was synthesized. Its crystal structure determined by X-ray diffraction method indicates that the B-C bond between B atom and it bridge is obviously shorter than those of between B atom and mesityl groups. This remarkably strengthened B-C bonding can be regarded as an evidence of additional p-7t conjugation between the B atom and n bridge.

合成了以含硼基团为电子受体,以二甲胺基为电子给体,以苯乙烯基噻吩为轭桥的新化合物2-[(4'-N,N-二甲胺基)苯乙烯基]-5-二米基硼-噻吩 trans-2-[(4'-N, N-dimethylamino) styryl]-5-dimesitylboryl-thiophene(简写为DMASBT,5)。X射线衍射方法测定其单晶结构表明,硼原子与π轭桥之间的硼碳键相对于其它的硼碳键明显缩短,硼与π轭桥之间存在除了σ键之外的p-π轭作用。

The thermal stability, Raman spectra, and upconversion luminescence spectra of lead halide-modified Tm~3+/Yb~3+-codoped tellurite glasses have been investigated, and the upconversion luminescence mechanism of Tm~3+/Yb~3+-codoped oxyhalide tellurite glasses were analyzed.

研究了卤化铅调整Tm3+/Yb3+掺碲酸盐玻璃的热稳定性能、Raman光谱和上转换发光光谱,分析了Tm3+/Yb3+掺氧卤碲酸盐玻璃的上转换发光机理。结果发现:混合卤化铅调整Tm3+/Yb3+掺碲酸盐玻璃具有好的热稳定性能、低的声子能量、强的上转换蓝光。这表明混合卤化铅调整Tm3+/Yb3+掺碲酸盐玻璃是一种上转换蓝光激光器的潜在基质材料

From the photophysical behaviors of 1, 3, 4-triaryl-2pyrazoline compound (TPP16) at low temperature, it can be considered that the twisted configuration between pyrazoline ring and the non-substituted phenyl group on the position 1 is the fluorescence configuration of conjugated system Ⅰ, and the twisted configuration between pyrazoline ring and P-nitrobenzene group is fluorescence configuration of conjugated system Ⅱ.

研究了1,3,4-三芳基-2-吡唑啉化合物TPP16在低温时的发光情况,发现:在低温77K下,轭体系Ⅰ(苯基-N1-N2=C3-苯基)在非极性溶剂中不发荧光,在极性溶剂中有较强荧光发射;而轭体系Ⅱ(N1-N2=C3-C4=对硝基苄叉)在非极性溶剂或极性溶剂中均有荧光发射,表明N1所联取代基与吡唑啉环相扭曲的构象是轭体系Ⅰ的发光构象,而对硝基苄叉与吡唑啉环相扭曲的构象是轭体系Ⅱ的发光构象。

Effect of polymerization conditions including charging weight ratio of polystyrene macromer, amount of initiator and temperature of copolymerization on grafting efficiency were studied. PBA-g-PS was used as compatibilizer in the blends of PS/ACR Effects of composition of the blends, amount of the graft copolymer, and composition of the graft copolymer on mechanical properties were studied.

研究了聚合反应条件:聚苯乙烯大单体的投料质量分数,引发剂用量,反应温度对接枝效率的影响;PBA-g-PS可以作为ACR/PS体系的混增容剂,研究混物的组成,接枝物的用量,接枝物的组成对混物物理机械性能的影响。

There were 15 pediatric ALL patients, which had received 50 times of chemotherapy with HD-MTX. The records about blood concentration of MTX and clinical conditions for 50 times chemotherapy were divided into two groups. Group I: contained 25 records of stand-risk patients, administering MTX 3.0g/m2; Group II: contained 25 records of mid and high-risk patients, administering 5.0g/m2. Continuous intravenous dripped MTX for 24th in both two groups, while implemented hydrating and alkalizing for 4 days. All patients were rescued 6 times through leucovorin, 15mg/m~2, since 12th after the end of MTX dripping. Then examined the blood concentration of MTX by fluorescence polarization immunoassay approach at 24h, 44h, 68h, at the same time inspected liver function, blood routine examination, the occurrence time and degree of toxicological reactions.

观察15例ALL住院患儿,接受大剂量MTX50例次,按ALL危险度分2组,低危治疗组接受MTX剂量为3.0g/m2为I组;中高危治疗组接受MTX剂量为5.0g/m2为II组,连续静脉点滴MTX24小时,同时给予水化碱化治疗,4天,全部病例均在MTX滴注结束后12小时开始静脉推注四氢叶酸钙(leucovorin,LV)解救,15mg/m2/次,6次,采用免疫偏振荧光法检测药物滴注24、44、68小时MTX血药浓度,同时检测两组病例的肝功、血常规,观察临床出现MTX毒副反应的时间及程度,观察每个病例毒副反应出现程度与MTX血药浓度关系,两组毒副反应程度比较,进行统计学分析。

In this article, the factors that affect molecular weight and solubility of polyacrylamide are studied and suitable initiator system is selected. The optimum parameters of copolymerizing process are obtained as follows: the molar proportion of acrylamide and sodium acrylate is 7:3, the monomer concentration is 30%, pH value of solution is 12, the oxidizer (K2S2O8) concentration is 0.1%, the reducing agent (NH2CONH2) concentration is 1%, the chain-transfer agent concentration is 0.4%. The initial reaction temperature is 35℃.

讨论了影响聚丙烯酰胺分子量和溶解性能的因素,选取了合适的氧化-还原引发体系,确定了制备超高分子量速溶型部分水解聚丙烯酰胺的优化聚合工艺参数:起始聚合反应温度为35℃,保持在密闭条件下的聚合反应2.5h后,再将聚合反应温度升高到55℃,继续反应2h,反应结束;反应溶液单体总浓度:30%,聚合反应溶液pH值:12,氧化剂K_2S_2O_8:0.1%,还原剂NH_2CONH_2:1%,聚合反应中两种单体的投料比:丙烯酰胺:丙烯酸钠=7:3,异丙醇链转移剂:0.4%。

In order to determine the load-bearing capacity, the bearing steel GCr15 was treated by ferritic and composite nitrocarburizing techniques.

为考察氮碳渗层的承载能力,对GCr15轴承钢进行了铁素体氮碳渗及其与氧化+抛光+氧化相结合的复合氮碳渗工艺,首次对铝质材料实施了氮碳渗处理,研究了表面处理层的摩擦学特性。

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However, as the name(read-only memory)implies, CD disks cannot be written onorchanged in any way.

然而,正如其名字所指出的那样,CD盘不能写,也不能用任何方式改变其内容。

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