六胺

In the fifth chapter, six compounds formed between nitrogen-containing ligands such as 2, 2'-bipyridyl, isonicotinamide and 1, 4, 8, 11-tetraazacyclotetradecane and the solution cadmium sulfonates such as 1, 5-naphthalenedisulfonate, 2, 6-naphthalenedisulfonate, 4, 4'-bipenyldisulfonate and 4, 4'-penyletherdisulfonate have been synthesized and structurally characterized. Besides, another compound has been synthesized with cadmium carbonate reacting with 1, 5-naphthalenedisulfonate acid.

第五章以2，2'-联吡啶、异烟酰胺和1，4，8，11-四氮杂环十四癸烷与含有Cd〓和1，5-萘二磺酸根离子、2，6-萘二磺酸根离子、4，4'-联苯二磺酸根离子和4，4'-苯醚二磺酸根离子的水溶液反应，合成了六个化合物，另外以1，5-萘二磺酸与碳酸镉反应合成出一个化合物。

They are derived from the condensation of salicylaldehyde with naphthalidine, 2-cyano-4-chloroaniline, o-Toluidine, N-aminoethylmorpholine, benylamine, butylamine, cyclopentylamine and 3-carboxysalicylidene with N-aminoethylmorpholine, benylamine, 2-hydroxyaminoethylamine, ethylenediamine, respectively.

得到了HL1、HL2和HL3配体的单晶；培养出了HL3～HL6、H2L11的Cu配合物，HL7～H2L11的Co配合物和H2L11的Ni配合物的单晶。此外，以5-溴水杨酸(5-bsa)、2-氨基苯甲酸(2-aba)、六次甲基四胺等为原料，合成了3种过渡金属Ag配合物，并培养出了其单晶。

Using cetyl trimethyl ammoniunm bromide as templating agent, the mesoporous TiO_2 with special performance was synthesized by a tartaric acid sol-gel method. The UV irradiation was used in this process.

以十六烷基三甲基溴化胺为模板剂，采用溶胶-凝胶法，在溶胶-凝胶制备过程中引入紫外光照辐射，制备出具有一定特殊性能的中孔TiO2材料。

The result makes clear, with anhydrous chloridize zinc, sulfur acting acetyl amine is raw material, it is OK to use chemical method the ZnS Na Mijing that preparation bead diameter controls in 10 Nm, earning sample is α- construction of mine of ZnS fine zinc, 6 brilliant are, form appearance is globose or close globose.

结果表明，以无水氯化锌、硫代乙酰胺为原料，采用声化学法可以制备粒径在10 nm左右的ZnS纳米晶，所得样品为α-ZnS纤锌矿结构，六方晶系，形貌为球形或近球形。

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能，共由以下六部分组成：1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应；2、亚甲基环丙烷类化合物开环产物的偶联反应；3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应；4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应；5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应；6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1，3-偶极环加成反应。

In this chapter, A〓 is divinyl sulfone, B〓 organic molecules with two secondary-amino groups, BB'〓 organic molecules with one secondary-amino group and one primary-amino group.

提出了一种由已商品化的A〓、B〓和BB'〓型单体合成高度支化共聚物的新方法，并合成了六种新型高度支化共聚砜胺。

Using pentaerythritol as initiator, boron trifluoride diethyl etherate as catalyst.dichloroethane as dispersion agent, the chloride polyether polyol is synthesized based on the mechanism of cationic ring-opening polymerization of epiclilnrohyclrin.The azide polyether polyol is synthesized, in DMF through A and sodium azide, and the non-reported azide energetic curing agent is synthesized through the adduction of B and IIDI.

以季戊四醇为起始剂，三氟化硼乙醚为催化剂，1，2—二氯乙烷为分散剂，环氧氯丙烷经阳离子开环聚合反应制成氯化聚醚多元醇，A在N，N—二甲基甲酰胺中与叠氮化钠反应制得叠氮聚醚多元醇，B与六亚甲基二异氰酸酯加成反应制得未见文献报道的叠氮固化剂。

The structure consists of discrete adamantylammonium cations lying on crystallographic mirror planes and hexa- fluoridogermanate anions disordered about sites of 2/m point symmetry.

它的结构中包含位于晶体学对称面上的离散的金刚烷胺阳离子，而无序的六氟锗酸盐阴离子位于2/m对称点。

In the system droplets in microns are first formed by emulsifying an organic phase consisting of a core material (n- hexadecane) and an oil- soluble reactive monomer,toluene- 2,4- diisocyanate,in an aqueous phase.By adding water- soluble reactive monomer,diamine,monomers TDI and diamine react with each other at the interface of micelles to become a shell.

在含乳化剂的水溶液中，将溶有芯材正十六烷的有机相乳化成微米级油性液滴，随后加入的水溶性单体二胺与甲苯 2， 4-二异氰酸酯在胶束界面相互反应形成囊壁。

In this experiment,three kinds of sizes of CdSe nanocrystals were obtained by changing the amount of hexadecyl amine in the system.

通过改变配体十六烷基胺在反应体系中的含量，合成了 3种不同粒径的 Cd Se纳米晶。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。